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1.发明授权Palladium catalyst and its use in the preparation of a mixture of optionally substituted cyclohexylamine and optionally substituted dicyclohexylamine 失效钯催化剂及其在制备任选取代的环己胺和任选取代的二环己胺的混合物中的用途
公开(公告)号：US5386060A
公开(公告)日：1995-01-31
申请号：US966127
申请日：1992-10-23
IPC分类号： B01J23/656 , C07C209/72 , G02B26/12 , G06K7/10 , C07C209/60 , C07C209/64
CPC分类号： B01J23/6562 , C07C209/72 , G02B26/125 , G06K7/10594 , G06K7/10702 , G06K2207/1011
摘要： A Pd catalyst in which an .alpha.- or .gamma.-Al.sub.2 O.sub.3 as support is first treated with at least one compound of the rare earth metals and with at least one compound of manganese and then with at least one palladium compound is suitable for the preparation of a mixture of optionally substituted cyclohexylamine and optionally substituted dicyclohexylamine by hydrogenation of a correspondingly substituted aniline.
摘要翻译： 首先用至少一种稀土金属化合物和至少一种锰化合物，然后与至少一种钯化合物一起处理作为载体的α或γ-Al 2 O 3的Pd催化剂适用于制备 任选取代的环己胺和任选取代的二环己胺的混合物通过相应取代的苯胺的氢化。
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2.发明授权Process for the preparation of a mixture of cyclohexylamine and dicyclohexylamine using a supported noble metal catalyst 失效使用负载型贵金属催化剂制备环己胺和二环己基胺的混合物的方法
公开(公告)号：US5322965A
公开(公告)日：1994-06-21
申请号：US113581
申请日：1993-08-27
IPC分类号： B01J23/40 , B01J23/46 , B01J23/648 , C07C209/26 , C07C209/72
CPC分类号： B01J23/40 , B01J23/462 , B01J23/648 , C07C209/26 , C07C209/72 , C07C2101/14
摘要： Optionally substituted cyclohexylamine and optionally substituted dicyclohexylamine can be obtained by catalytic hydrogenation of optionally substituted aniline, a catalyst being employed which contains ruthenium, palladium or a mixture of both metals, which are applied to a support of niobic acid or tantalic acid or a mixture of both. The catalyst contains the noble metal(s) in a total amount from 0.05 to 5% by weight, relative to the total weight of the catalyst. In the case of the use of both noble metals, their weight ratio to one another is 1:9-9:1.
摘要翻译： 任选取代的环己胺和任选取代的二环己胺可以通过任选取代的苯胺的催化氢化获得，使用的催化剂包含钌，钯或两种金属的混合物，其被施用于铌酸或钽酸的载体或 都。 催化剂含有相对于催化剂总重量为0.05-5重量％的贵金属。 在使用贵金属的情况下，它们彼此的重量比为1:9-9:1。
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3.发明授权Process for the production of di-(4-aminocyclohexyl)-methane containing 15 to 25% by weight of the trans-trans isomer 失效制备含有15至25重量％反式异构体的二（4-氨基环己基）甲烷的方法
公开(公告)号：US5245082A
公开(公告)日：1993-09-14
申请号：US4382
申请日：1993-01-14
IPC分类号： B01J23/46 , C07C209/72
CPC分类号： B01J23/462 , C07C209/72 , C07C2101/14
摘要： Di-(4-aminocyclohexyl)-methane containing 15 to 25% by weight of the trans-trans isomer can be obtained by the catalytic hydrogenation of di-(4-aminophenyl)-methane at elevated temperature and elevated hydrogen pressure in the presence of a ruthenium-containing supported catalyst containing 0.05 to 5% by weight ruthenium on an Al.sub.2 O.sub.3 support which has been treated with compounds of rare earth metals and manganese.
摘要翻译： 含有15-25％（重量）反式异构体的二 - （4-氨基环己基） - 甲烷可以通过二 - （4-氨基苯基） - 甲烷在升高的温度下催化氢化和升高氢气压力 含有0.05〜5重量％钌的含钌载体的Al 2 O 3载体上已经用稀土金属和锰化合物处理。
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公开(公告)号：US5196592A
公开(公告)日：1993-03-23
申请号：US805441
申请日：1991-12-11
IPC分类号： B01J27/055 , B01J23/46 , B01J23/58 , C07B61/00 , C07C209/52 , C07C209/68 , C07C211/54 , C07C211/55 , C07C213/02 , C07C215/76 , C07C217/84 , C07C217/90 , C07D521/00
CPC分类号： C07C209/68
摘要： Diphenylamine, which can be substituted by lower alkyl and/or lower alkoxy, is obtained from the corresponding N-cyclohexylidene-aniline by catalytic dehydrogenation, a rhodium-containing catalyst being employed.
摘要翻译： 可以由低级烷基和/或低级烷氧基取代的二苯胺通过催化脱氢从相应的N-亚环己基苯胺获得，使用含铑催化剂。
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公开(公告)号：US5304525A
公开(公告)日：1994-04-19
申请号：US50752
申请日：1993-04-21
申请人： Otto Immel , Helmut Waldmann , Rudolf Braden , Christian Frohlich , Gerhard Friedhofen , Wilfried Niemeier
发明人： Otto Immel , Helmut Waldmann , Rudolf Braden , Christian Frohlich , Gerhard Friedhofen , Wilfried Niemeier
IPC分类号： B01J23/44 , B01J23/46 , C07B61/00 , C07C209/30 , C07C209/36 , C07C211/46 , B01J21/18 , B01J23/40
CPC分类号： C07C209/36 , C07C209/30
摘要： A process for the preparation of aniline by hydrogenation of nitrobenzene in the gas phase in the presence of a catalyst containing a noble metal is described. The process can be carried out in an improved manner if the catalyst employed is palladium on graphite or petrol coke, as the support, containing 0.001-1% by weight of Pd, based on the total weight of the catalyst, it being possible for the catalyst also to contain, in addition to the Pd, 0.001-0.5% by weight of Ir and/or 0.001-0.3% by weight of Rh, all figures being based on the total weight of the catalyst.
摘要翻译： 描述了在含有贵金属的催化剂存在下，在气相中硝基苯氢化制备苯胺的方法。 如果所使用的催化剂是石墨或石油焦炭作为载体，基于催化剂的总重量，可以以改进的方式进行该方法，该催化剂含有0.001-1重量％的Pd，对于 催化剂除了Pd之外还含有0.001-0.5重量％的Ir和/或0.001-0.3重量％的Rh，所有数据都是基于催化剂的总重量。
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公开(公告)号：US5434310A
公开(公告)日：1995-07-18
申请号：US180516
申请日：1994-01-12
申请人： Helmut Waldmann , Manfred Hajek , Otto Immel , Lothar Puppe , Rudolf Braden
发明人： Helmut Waldmann , Manfred Hajek , Otto Immel , Lothar Puppe , Rudolf Braden
IPC分类号： B01J29/76 , B01J29/70 , B01J29/78 , B01J29/86 , B01J29/87 , B01J29/88 , C07B61/00 , C07C45/46 , C07C49/76 , C07C49/78 , C07C49/786 , C07C45/45
CPC分类号： C07C45/46
摘要： Acylbenzenes of the formula ##STR1## can be prepared by reaction of benzene with carboxylic acids of the formulaHOOC--R.sup.1 (II)where R.sup.1 has the meaning given in the text, using a molar ratio of benzene:carboxylic acid=1-50:1 at a temperature of 200.degree.-400.degree. C., a zeolite of the Pentasil type having an SiO.sub.2 /M.sup.2 O.sub.2 ratio of 15-500:1 being used as acid catalyst; in the latter formula, M.sup.2 is one element or more from the group comprising Al, B, Ga, In, Fe, Cr, V, As and Sb.
摘要翻译： 式（I）的酰基苯可以通过苯与式HOOC-R1（II）的羧酸反应来制备，其中R 1具有本文给出的含义，使用苯：羧酸的摩尔比= 1 -50：1，温度为200-400℃，使用SiO 2 / M 2 O 2比为15-500:1的Pentasil型沸石作为酸催化剂; 在后一公式中，M2是由Al，B，Ga，In，Fe，Cr，V，As和Sb组成的组中的一种以上。
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公开(公告)号：US5166440A
公开(公告)日：1992-11-24
申请号：US626343
申请日：1990-12-12
申请人： Otto Immel , Helmut Waldmann , Rudolf Braden
发明人： Otto Immel , Helmut Waldmann , Rudolf Braden
IPC分类号： B01J23/20 , C07B61/00 , C07C209/18 , C07C209/60 , C07C209/68 , C07C211/48
CPC分类号： C07C209/18
摘要： Aromatic amines, alkylated on the N-atom, can be prepared by catalytic alkylation of aromatic amines with alcohols or the corresponding ethers or by transalkylation with aromatic amines alkylated on the N-atom, whereby niobic acid or tantalic acid is used as the catalyst.
摘要翻译： 在N-原子上烷基化的芳族胺可以通过芳族胺与醇或相应的醚的催化烷基化或通过在N-原子上烷基化的芳族胺进行烷基转移来制备，由此使用铌酸或钽酸盐作为催化剂。
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公开(公告)号：US5801285A
公开(公告)日：1998-09-01
申请号：US961675
申请日：1997-10-31
申请人： Helmut Waldmann , Jurgen Dahmer , Anatoly Bazanov , Alexandre Timofeev , Natalja Zubritskaya , Gennady Terechtchenko
发明人： Helmut Waldmann , Jurgen Dahmer , Anatoly Bazanov , Alexandre Timofeev , Natalja Zubritskaya , Gennady Terechtchenko
IPC分类号： C07C209/26 , C07C209/62 , C07C211/09 , C07C211/11 , C07D239/06
CPC分类号： C07D239/06 , C07C209/62
摘要： The present invention relates to a process for preparing 2-methyl-2,4-diaminopentane by introducing acetone, ammonia and hydrogen into a two-zone reactor at a temperature of 20.degree. to 130.degree. C. and a pressure of 30 to 250 bar, wherein the first zone contains a cationic exchange resin containing NH.sub.4.sup..sym. groups or an aluminum oxide and/or silicon oxide catalyst and the second zone contains a hydrogenation catalyst containing nickel.
摘要翻译： 本发明涉及一种通过将丙酮，氨和氢气在20℃至130℃的温度和30至250巴的压力下引入双区反应器中制备2-甲基-2,4-二氨基戊烷的方法 ，其中所述第一区含有含有NH 4（+）基团的阳离子交换树脂或氧化铝和/或氧化硅催化剂，所述第二区含有含镍的氢化催化剂。
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公开(公告)号：US5552549A
公开(公告)日：1996-09-03
申请号：US315001
申请日：1994-09-29
IPC分类号： A62D3/32 , A62D101/22 , C07B35/06 , C07B61/00 , C07C1/26 , C07C15/04 , C07C17/23 , C07C25/02 , C07D213/06 , C07D213/61 , C07D215/18 , C07D217/22 , C07D319/24 , C07D217/00 , C07C1/20 , C07C22/00 , C07D309/00
CPC分类号： A62D3/32 , A62D2101/22
摘要： Chlorinated aromatic compounds are dechlorinated in a simple and inexpensive manner by heating them to 300.degree. to 450.degree. C. in a salt melt in the presence of water and/or water vapor and carbon.
摘要翻译： 氯化芳族化合物以简单且便宜的方式通过在水和/或水蒸气和碳的存在下在盐熔体中加热至300-450℃进行脱氯。
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公开(公告)号：US5369947A
公开(公告)日：1994-12-06
申请号：US120630
申请日：1993-09-13
IPC分类号： B01D53/34 , C08J11/12 , C10B53/00 , C10B53/07 , C10J3/46 , F01K23/10 , F01K27/02 , F02C3/20 , F02C3/28 , F02C6/18 , F23G5/027 , H02K44/28 , H02N11/00 , F02C3/26
CPC分类号： F02C6/18 , C10B53/07 , C10J3/482 , F02C3/28 , C10J2200/12 , C10J2200/158 , C10J2300/1238 , C10J2300/165 , C10J2300/1675 , Y02E20/12 , Y02E20/14 , Y02E20/16 , Y02E50/11 , Y02E50/12 , Y02P20/123 , Y02P20/124 , Y02P20/129 , Y02P20/143
摘要： The plastic waste is reacted in a plasma reactor 3 under reducing conditions in a plasma containing substoichiometric oxygen at temperatures above 1200.degree. C. to form a plasma pyrolysis gas consisting of low molecular weight carbon fragments which is then cooled to temperatures below 1500.degree. C. The cooled plasma pyrolysis gas is then delivered in compressed form as a fuel of high calorific value and high temperature to a gas turbine 10 for generating power. The waste heat of this gas turbine is used to generate steam which is fed into a steam turbine 12 for generating more power. The process is suitable for plastic waste of any composition and leads to complete conversion into a gas of high calorific value so that a high exergetic efficiency level is achieved.
摘要翻译： 塑料废料在等离子体反应器3中在还原条件下在含有亚化学计量氧的等离子体中在高于1200℃的温度下反应，以形成由低分子量碳片段组成的等离子体热解气体，然后冷却至低于1500℃的温度。 然后将冷却的等离子体热解气体作为高热值和高温的燃料以压缩形式输送到用于发电的燃气轮机10。 该燃气轮机的废热用于产生蒸汽，其被馈送到蒸汽涡轮机12中以产生更多的功率。 该方法适用于任何组合物的塑料废料，并导致完全转化为高热值气体，从而达到高的高效率水平。
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