公开(公告)号：US20170335130A1

公开(公告)日：2017-11-23

申请号：US15665831

申请日：2017-08-01

Applicant: Wisconsin Alumni Research Foundation

Inventor： Padma Gopalan ,  William L. Murphy ,  Samantha Kelly Schmitt

IPC: C09D133/14 ,  C08F220/28 ,  C12N5/00

CPC classification number: C09D133/14 ,  C08F220/28 ,  C12N5/0068 ,  C12N2533/40 ,  C12N2537/10 ,  C08F2220/286 ,  C08F2220/325 ,  C08F226/06

Abstract: Random copolymers, crosslinked thin films of the random copolymers and cell culture substrates comprising the crosslinked thin films are provided. Also provided are methods of making and using the copolymers, thin films and substrates. The copolymers are polymerized from glycidyl methacrylate monomers and vinyl azlactone monomers. The crosslinked thin films are substrate independent, in that they need not be covalently bound to a substrate to form a stable film on the substrate surface.

公开(公告)号：US09786853B2

公开(公告)日：2017-10-10

申请号：US15118058

申请日：2015-02-11

Applicant: Wisconsin Alumni Research Foundation

Inventor： Michael Scott Arnold ,  Padma Gopalan ,  Gerald Joseph Brady ,  Yongho Joo ,  Harold T. Evensen

IPC: H01L29/06 ,  H01L29/08 ,  H01L51/05 ,  H01L51/00 ,  C01B31/02

CPC classification number: H01L51/0558 ,  C01B32/168 ,  C01B2202/02 ,  H01L51/0003 ,  H01L51/0039 ,  H01L51/0048 ,  H01L51/0049

Abstract: High density films of semiconducting single-walled carbon nanotubes having a high degree of nanotube alignment are provided. Also provided are methods of making the films and field effect transistors (FETs) that incorporate the films as conducting channel materials. The single-walled carbon nanotubes are deposited from a thin layer of organic solvent containing solubilized single-walled carbon nanotubes that is spread over the surface of an aqueous medium, inducing evaporative self-assembly upon contacting a solid substrate.

公开(公告)号：US20170121555A1

公开(公告)日：2017-05-04

申请号：US15404775

申请日：2017-01-12

Applicant: Wisconsin Alumni Research Foundation

Inventor： Padma Gopalan ,  Daniel Patrick Sweat ,  Xiang Yu ,  Myungwoong Kim

IPC: C09D153/00 ,  G03F7/00 ,  C09D153/02 ,  C08F297/02 ,  C08F297/04

CPC classification number: C09D153/00 ,  C08F12/22 ,  C08F12/32 ,  C08F297/02 ,  C08F297/026 ,  C08F297/046 ,  C09D153/02 ,  G03F7/0002 ,  Y10T428/268

Abstract: Block copolymers for use in block copolymer lithography, self-assembled films of the block copolymers and methods for polymerizing the block copolymers are provided. The block copolymers are characterized by high Flory-Huggins interaction parameters (χ). The block copolymers can be polymerized from protected hydroxystyrene monomers or from tert-butyl styrene and 2-vinylpyridine monomers.

公开(公告)号：US09425405B1

公开(公告)日：2016-08-23

申请号：US14619465

申请日：2015-02-11

Applicant: Wisconsin Alumni Research Foundation

Inventor： Michael Scott Arnold ,  Harold T. Evensen ,  Gerald Joseph Brady ,  Padma Gopalan ,  Yongho Joo

IPC: H01L51/00 ,  C01B31/02 ,  C09D11/52 ,  C09D11/106 ,  B05D1/18 ,  H01L29/06 ,  H01L29/78

CPC classification number: H01L51/0039 ,  B05D1/18 ,  B05D1/202 ,  C01B32/16 ,  C01B32/174 ,  C01B2202/02 ,  C09D11/037 ,  C09D11/106 ,  C09D11/52 ,  H01L51/0007 ,  H01L51/0043 ,  H01L51/0048 ,  H01L51/0558 ,  H01L51/0566

Abstract: High density films of semiconducting single-walled carbon nanotubes having a high degree of nanotube alignment are provided. Also provided are methods of making the films and field effect transistors (FETs) that incorporate the films as conducting channel materials. The single-walled carbon nanotubes are deposited from a thin layer of organic solvent containing solubilized single-walled carbon nanotubes that is continuously supplied to the surface of an aqueous medium, inducing evaporative self-assembly upon contacting a solid substrate.

Abstract translation: 提供具有高度纳米管取向度的半导体单壁碳纳米管的高密度膜。 还提供了制造将膜和场效应晶体管（FET）合并为导电沟道材料的方法。 单壁碳纳米管是从含有溶解的单壁碳纳米管的有机溶剂的薄层沉积的，所述单壁碳纳米管连续地供应到水性介质的表面，在接触固体基质时引起蒸发自组装。

公开(公告)号：US09327979B1

公开(公告)日：2016-05-03

申请号：US14588513

申请日：2015-01-02

Applicant: Wisconsin Alumni Research Foundation

Inventor： Padma Gopalan ,  Michael Scott Arnold ,  Yongho Joo ,  Gerald Joseph Brady ,  Matthew Shea

IPC: C01B31/02 ,  B82Y40/00 ,  B82Y30/00

CPC classification number: C01B31/0253 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/168 ,  C01B32/172 ,  C01B2202/02 ,  C01B2202/22 ,  C01B2202/36 ,  Y10S977/751 ,  Y10S977/847

Abstract: Methods for removing polymer coatings from the surfaces of single-walled carbon nanotubes are provided. The methods remove polymer coatings that are used to selectively wrap and sort semiconducting single-walled carbon nanotubes from metallic single-walled carbon nanotubes. The methods are based on a process of detaching a polymer coatings by binding transition metal complexes to bi-pyridine repeat units within the polymer backbone.

Abstract translation: 提供了从单壁碳纳米管表面去除聚合物涂层的方法。 该方法去除用于从金属单壁碳纳米管选择性包裹和分选半导体单壁碳纳米管的聚合物涂层。 该方法基于通过将过渡金属络合物结合到聚合物主链内的双 - 吡啶重复单元来分离聚合物涂层的方法。