摘要:
A grease composition is provided containing (a) a base oil; (b) a urea-based thickening agent; (c) at least one compound selected from the group of (i) a molybdenum dithiocarbamate, (ii) a zinc dithiocarbamate, (iii) a molybdenum dithiophosphate, and/or (iv) a zinc dithiophosphate; and (d) a metal salt of a fatty acid.
摘要:
This invention relates to improved antioxidant antiwear/extreme pressure compositions consisting of (a) methylenebis(di-n-butyldithiocarbamate) and (b) a diphenylamine derivative of tolutriazole or benzotriazole wherein the (a):(b) mass precent ratio ranges from above about 4:1 to about 50:1 and lubricating compositions containing same.
摘要:
A lubricating oil for improving the fuel economy of internal combustion engines is disclosed comprising a major amount of a lubricating oil base stock and a minor amount of an additive package which comprises in combination a molybdenum dithiocarbamate friction modifier, a mixture of calcium and magnesium salicylate and magnesium sulfonate detergent, and alkylated (alkoxy) amine. In addition the engine lubricant can include other typical engine oil lubricant additives including dispersants, anti-foaming agents, anti-oxidants, anti-wear additives, demulsifiers, etc.
摘要:
Dithiocarbamyl carboxylic acids, useful as multifunctional additives for lubricating oils, possess the general formula: ##STR1## wherein R.sup.1 and R.sup.2 each independently is a hydrocarbyl group of from 1 to about 60 carbon atoms and R.sup.3 is a divalent alkylene group of from 1 to about 20 carbon atoms.
摘要:
The present invention is directed to a method for improving the performance of a sooted diesel oil and controlling soot induced viscosity increase by adding to a major amount of a diesel oil a minor amount of a composition comprising at least one compound having the formula Mo.sub.3 S.sub.k L.sub.n Q.sub.z and mixtures thereof wherein the L are independently selected ligands having organo groups with a sufficient number of carbon atoms to render the compound soluble or dispersible in the oil, n is from 1 to 4, k varies from 4 through 10, Q is selected from the group of neutral electron donating compounds such as water, amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5 and includes nonstoichiometric values.
摘要:
This invention relates to compositions for improving fuel efficiency in internal combustion engines. The composition comprises a lubricant having an oil of lubricating viscosity and (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced fuel efficiency properties.
摘要:
Providing a lubricating oil composition for internal combustion engines which has high resistance to oxidation by nitrogen oxides, excellent friction characteristics that is maintained for a prolonged period, and reduces the fuel consumption for a prolonged period. A lubricating oil composition for internal combustion engines is provided consisting of a base oil principally consisting of a hydrocarbon oil which has a dynamic viscosity of 2-20 mm.sup.2 /s at 100.degree. C. and contains 3 wt % or less aromatic components in total, 45 wt% or more one- and two-ring naphthenes in total, 50 wt ppm or less sulfur and 50 wt ppm or less nitrogen, to which are added, with respect to the total weight of the composition, 0.02-0.2 wt % as molybdenum of molybdenum dithiocarbamate, 0.02-0.15 wt % as phosphorus of zinc dithiophosphate, and 0.05-3 wt % of phenol-based antioxidant. The lubricating oil composition according to the invention has a low friction coefficient, which is maintained for a prolonged period even after oxidation by nitrogen oxides.
摘要:
A composition comprisinga) a lubricant or a hydraulic fluid andb) at least one compound of the general formula I ##STR1## in which x=1 or 2 and,if x=1,R is as defined for R.sup.1 or R.sup.3 --O-- or,if x=2,R is as defined for R.sup.8, andR.sup.1 and R.sup.3 are, for example, alkyl, cycloalkyl, alkenyl, phenyl, naphthyl, aralkyl or alkaryl, or alkyl, cycloalkyl, alkenyl, phenyl, naphthyl, aralkyl or alkaryl, which are monosubstituted or polysubstituted by groups from the series comprising halogen, cyano, nitro, e.g. --OCH.sub.3 or e.g. --COOCH.sub.3, or alkyl, cycloalkyl, alkenyl, aralkyl or alkaryl which are interrupted by one or more groups from the series comprising --O--, --S--, --NH--, ##STR2## or alkyl, cycloalkyl, alkenyl, aralkyl or alkaryl which are monosubstituted or polysubstituted by groups from the series comprising halogen, cyano, nitro, e.g. --OCH.sub.3 or e.g. --COOCH.sub.3 and interrupted by one or more groups from the series comprising --O--, --S--, --NH--, ##STR3## and R.sup.2 is NR.sup.4 R.sup.5, --OR.sup.6 or --SR.sup.7, andR.sup.4 and R.sup.5 are identical or different and are, for example, --H, alkyl, phenyl, naphthyl, aralkyl or alkaryl, orR.sup.4 and R.sup.5, together with the N atom linking them, form, for example, a piperidine or morpholine radical, andR.sup.6 and R.sup.7 can be alkyl which may be interrupted by one or more groups from the series comprising --O--, --S--, --NH--, ##STR4## or are, for example, phenyl, naphthyl, alkaryl or aralkyl, and R.sup.8 can be alkylene which may be interrupted by at least one --O-- group or alkylidene which may be interrupted by at least one --O-- group. Some of the compounds of the formula I are novel. The compositions show an improved stability towards oxidative degradation, confer protection under extreme pressures and reduce frictional wear.
摘要:
An additive for improving the antioxidation properties of lubricating oil is made by reacting a sulfur halide selected from sulfur monochloride or sulfur dichloride with an aliphatic monoolefin (e.g. isobutene) to form an adduct, reacting the adduct thus formed with an alkali metal salt of an organocarbamodithioic acid in an aqueous alkanol medium and recovering the reaction product.When added to lubricating oil, the additive products of the invention improve the antioxidation properties of the lubricating oil.
摘要:
A lubricant-fuel mixture containing an amine salt and/or amide of a thiobenzoic acid derivative is effective in reducing the smoke emitted during operation of a two-cycle internal combustion engine. A preferred thiobenzoic acid derivative is 4-hydroxy-3,5-ditert-dibutyldithiobenzoate.