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    Dyeing composition containing halogenated 2-nitroanilines
    61.
    发明授权
    Dyeing composition containing halogenated 2-nitroanilines 失效
    含有卤代2-硝基苯胺的染色组合物

    公开(公告)号：US4845293A

    公开(公告)日：1989-07-04

    申请号：US15033

    申请日：1987-02-17

    Applicant: Alex Junino ,  Gerard Lang ,  Nicole Jehanno ,  Jean J. Vandenbosche

    Inventor： Alex Junino ,  Gerard Lang ,  Nicole Jehanno ,  Jean J. Vandenbosche

    IPC: A61K8/00 ,  A61K8/34 ,  A61K8/35 ,  A61K8/40 ,  A61K8/41 ,  A61K8/49 ,  A61Q5/06 ,  A61Q5/10 ,  C07C211/52 ,  C07C215/16 ,  C07C217/52 ,  C09B51/00 ,  C09B67/20 ,  D06P3/04

    CPC classification number: A61K8/418 ,  A61Q5/065 ,  A61Q5/10 ,  C09B51/00

    Abstract: A dyeing composition for keratinous fibres comprising a solvent and at least one dye which is a halogenated 2-nitro-aniline of formula: ##STR1## in which Y is a halogen and Z is a NHR.sub.2 group or Y is hydrogen and Z is a halogen and R.sub.1 and R.sub.2, which may be identical or different, are each hydrogen, an alkyl group, a mono- or polyhydroxylated alkyl group, an alkyl group substituted with an alkoxy or hydroxyalkoxy group, or an aminoalkyl group, the amino group of which is optionally substituted with one or two alkyl or hydroxyalkyl groups, and it being possible for the nitrogen atom of the aminoalkyl group to form part of a heterocycle, all the abve alkyl groups or moieties containing from 1 to 6 carbon atoms,or, if the compound of formula (I) contains an amine group which can be salified, a cosmetically acceptable salt thereof.

    Abstract translation: 一种用于角质纤维的染色组合物，其包含溶剂和至少一种染料，其是下式的其中的卤化2-硝基 - 苯胺：其中Y是卤素，Z是NHR 2基团或Y是氢，Z是卤素 和可以相同或不同的R 1和R 2各自为氢，烷基，单或多羟基化烷基，被烷氧基或羟基烷氧基取代的烷基或氨基烷基，其氨基为 任选地被一个或两个烷基或羟烷基取代，并且氨基烷基的氮原子可以形成杂环的一部分，所有的亚烷基或含有1至6个碳原子的部分，或者如果化合物 式（I）的化合物含有可以盐化的胺基，其化学上可接受的盐。

    Aromatic benzopyranyl and benzopyranyl compounds; their preparation; and their use in cosmetic compositions and human and veterinary medicine
    62.
    发明授权
    Aromatic benzopyranyl and benzopyranyl compounds; their preparation; and their use in cosmetic compositions and human and veterinary medicine 失效
    芳香族苯并吡喃基和苯并吡喃基化合物; 他们的准备 以及它们在化妆品组合物和人兽药中的应用

    公开(公告)号：US4829080A

    公开(公告)日：1989-05-09

    申请号：US025200

    申请日：1987-03-12

    Applicant: Jean Maignan ,  Gerard Lang ,  Gerard Malle ,  Serge Restle ,  Braham Shroot

    Inventor： Jean Maignan ,  Gerard Lang ,  Gerard Malle ,  Serge Restle ,  Braham Shroot

    IPC: A61K8/00 ,  A61K8/36 ,  A61K8/41 ,  A61K8/49 ,  A61K31/35 ,  A61K31/352 ,  A61K31/38 ,  A61K31/382 ,  A61P11/00 ,  A61P17/00 ,  A61P27/02 ,  A61P31/00 ,  A61P35/02 ,  A61P37/00 ,  A61Q5/00 ,  C07D311/04 ,  C07D311/58 ,  C07D335/06

    CPC classification number: C07D335/06 ,  C07D311/58

    Abstract: An aromatic benzopyranyl or benzothiopyranyl compound of the formula ##STR1## wherein n is 0 or 1,X represents ##STR2## R' represents H, OH, acyloxy or NH.sub.2, R" represents H or alkoxy orR' and R" taken together form an oxo, methano or hydroxyimino radical,R.sub.8 represents H, ##STR3## R.sub.9 represents H, alkyl, mono or polyhydroxyalkyl, aryl, aralkyl, a residue of a sugar or ##STR4## p equals 1, 2 or 3, r' and r" represent H, alkyl, monohydroxyalkyl, polyhydroxyalkyl, aryl, benzyl, the residue of an amino acid or an aminated sugar, or together form a heterocycle,R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents H or lower alkyl,R.sub.5, R.sub.6 and R.sub.7 represent H or methyl or when n=1, R.sub.5 and R.sub.7 taken together form with the benzene ring a naphthalene ring (R.sub.5 -R.sub.7 .dbd.--CH.dbd.CH--), andthe salts of said compounds as well as their geometric and optical isomers.These compounds are useful in pharmaceutical and cosmetic compositions.

    Abstract translation: 式（I）的芳香族苯并吡喃基或苯并硫代吡喃基化合物，其中n为0或1，X代表R'表示H，OH，酰氧基或NH 2，R“表示H或烷氧基或R'和R “一起形成氧代，亚甲基或羟基亚氨基，R8表示H，R 9表示H，烷基，单或多羟基烷基，芳基，芳烷基，糖残基或p等于1,2或3 ，r'和r“表示H，烷基，单羟基烷基，多羟基烷基，芳基，苄基，氨基酸或胺化糖的残基，或一起形成杂环，R 1，R 2，R 3和R 4表示H或低级烷基， R5，R6和R7表示H或甲基，或当n = 1时，R5和R7与苯环一起形成萘环（R5-R7 = -CH = CH-），所述化合物的盐以及它们的 几何和光学异构体。 这些化合物可用于药物和化妆品组合物。

    Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds
    63.
    发明授权
    Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds 失效
    基于吲哚衍生物的角质纤维染色组合物和新化合物

    公开(公告)号：US4822375A

    公开(公告)日：1989-04-18

    申请号：US21932

    申请日：1987-03-05

    Applicant: Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    Inventor： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    IPC: A61K8/00 ,  A61K8/34 ,  A61K8/37 ,  A61K8/41 ,  A61K8/49 ,  A61K8/92 ,  A61Q5/10 ,  C07D209/08 ,  C07D209/12 ,  C07D209/42 ,  C07D491/04 ,  C07D491/056 ,  C07F7/18 ,  C07F9/572 ,  C09B53/00 ,  C09B53/02 ,  C09B57/00 ,  C09B69/00 ,  D06P3/08 ,  A61K7/13 ,  C07D209/30 ,  C07F9/12

    CPC classification number: C07D491/04 ,  A61K8/492 ,  A61Q5/10 ,  C07D209/08 ,  C07F7/1856 ,  C07F9/5728 ,  C09B69/007 ,  C09B69/008

    Abstract: Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds.Dyeing composition for keratinous fibres, and especially human hair, characterized in that it contains, in a cosmetically acceptable medium suitable for dyeing these fibres, at least one dye corresponding to the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a lower alkyl group or a group --SiR.sub.9 R.sub.10 R.sub.11 ;R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group or a group -COOSiR.sub.9 - R.sub.10 R.sub.11 ; and R.sub.5, which may be identical or different, denote at least one linear or branched C.sub.1 -C.sub.20 alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O)(OR.sub.6).sub.2 or a group R.sub.6 OSO.sub.2 --, the other group R.sub.4 or R.sub.5 being able to be a hydrogen atom, R.sub.4 and R.sub.5 are not simultaneously acetyl, or alternatively R.sub.4 and R.sub.5, together with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group, a thiocarbonyl group, a group>P(O)OR.sub.6 or>CR.sub.7 R.sub.8 ;R.sub.6 denoting a hydrogen atom or a lower alkyl group, R.sub.7 denoting a hydrogen atom or a lower alkyl group, and R.sub.8 denotes a lower alkoxy group or a mono- or dialkylamino group, R.sub.9, R.sub.10 and R.sub.11, which may be identical or different, denoting linear or branched lower alkyl groups, and the cosmetically acceptable salts of alkali metals, alkaline earth metal metals, ammonia or amines.

    Abstract translation: 基于吲哚衍生物的角质纤维染色组合物和新化合物。 用于角质纤维，特别是人类头发的染色组合物，其特征在于，其在适合于染色这些纤维的化妆品可接受的培养基中含有至少一种对应于下式的染料：其中R 1表示氢原子 或低级烷基或-SiR 9 R 10 R 11基团; R2和R3可以相同或不同，表示氢原子，低级烷基，羧基，低级烷氧基羰基或基团-COOSiR9-R10R11; 和R 5可以相同或不同，表示至少一个直链或支链C 1 -C 20烷基，甲酰基，直链或支链C 2 -C 20酰基，直链或支链C 3 -C 20链烯酰基， SiR 9 R 10 R 11，基团-P（O）（OR 6）2或基团R 6 OSO 2 - ，另一基团R 4或R 5可以是氢原子，R 4和R 5不同时为乙酰基，或者R4和R5连同 形成任选地含有羰基，硫代羰基，基团> P（O）OR 6或> CR 7 R 8的环的氧原子。 R6表示氢原子或低级烷基，R7表示氢原子或低级烷基，R8表示低级烷氧基或一或二烷基氨基，R9，R10和R11可相同或不同， 表示直链或支链的低级烷基，以及碱金属，碱土金属金属，氨或胺的美容上可接受的盐。

    Alcoholic or aqueous-alcoholic compositions containing natural essences and benzylidene-camphor derivatives
    65.
    发明授权
    Alcoholic or aqueous-alcoholic compositions containing natural essences and benzylidene-camphor derivatives 失效
    含有天然香精和亚苄基 - 樟脑衍生物的醇或含水组合物

    公开(公告)号：US4731200A

    公开(公告)日：1988-03-15

    申请号：US885392

    申请日：1986-07-18

    Applicant: Gerard Lang ,  Andre Deflandre ,  Irena Beck

    Inventor： Gerard Lang ,  Andre Deflandre ,  Irena Beck

    IPC: C09K3/00 ,  A61K8/00 ,  A61K8/30 ,  A61K8/34 ,  A61K8/35 ,  A61K8/37 ,  A61K8/41 ,  A61K8/46 ,  A61K8/49 ,  A61K8/92 ,  A61K8/97 ,  A61K31/125 ,  A61K31/37 ,  A61P17/00 ,  A61Q13/00 ,  A61Q17/04 ,  A61Q19/02 ,  A61Q90/00 ,  C11B9/00 ,  A61K7/46

    CPC classification number: A61K8/416 ,  A61K8/35 ,  A61K8/466 ,  A61K8/922 ,  A61Q17/04

    Abstract: The present invention relates to an alcoholic or aqueous-alcoholic composition comprising a natural essence containing a phototoxic dose of furocoumarin, and 0.01 to 2% by weight of at least one benzylidenecamphor derivative filtering out UV-A radiation and chosen from among 3-p-oxybenzylidenebornan-2-ones, 3,3'-terephthalylidenedicamphors optionally sulphonated in the 10-position of the camphor, p-(3-methylidenecamphor)cinnamic acid derivatives, 3,3'-terephthalylidenedicampho-10-sulphonamides or 3,3'-terephthalylidenedicampho-10,10'-disulphonamides. It is also possible to incorporate into the composition a UV-B filter chosen from among benzylidenecamphor, p-methylbenzylidenecamphor, benzylidenecamphor derivatives containing a quaternary ammonium radical on the benzene nucleus in the para position relative to the bornylidene radical, benzylidenecamphor derivatives sulphonated on the methyl radical in the 10-position of the camphor or in the 3'-position or 4'-position on the benzene nucleus, p-methylbenzylidenecamphor derivatives substituted on the p-methyl group, or other 3-benzylidenecamphor derivatives filtering out UV-B radiation.Application: perfumes, toilet waters, eaux de cologne and shaving lotions.

    Abstract translation: 本发明涉及包含含有光毒剂量的呋喃香豆素的天然精华和0.01-2重量％的至少一种亚苄基猝灭衍生物的酒精或含水醇组合物，其过滤掉UV-A辐射并选自3-对 - 对苯二甲酰亚苯基-2-酮，樟脑10位中任选磺化的3,3'-对苯二甲酰基樟脑，对 - （3-甲基亚甲基樟脑）肉桂酸衍生物，3,3'-对苯二甲酰亚苯基二磷杂-10-磺酰胺或3,3'- 对苯二甲酰己二磷-10,10'-二磺酰胺。 在组合物中还可以将选自亚苄基樟脑，对甲基亚苄基樟脑中的UV-B过滤器，在相对于亚生乙酰基的对位的苯核上含有季铵基的亚苄基am or衍生物，在甲基上磺化的亚苄基am or衍生物 在樟脑的10位或苯核上的3'-位或4'-位，在对甲基上取代的对甲基亚苄基脒衍生物或其它过滤出UV-B辐射的3-亚苄基or or衍生物 。 适用范围：香水，马桶水，洗发水及洗发水。

    Anti-sunburn compositions containing 2-phenyl-indole derivatives
    69.
    发明授权
    Anti-sunburn compositions containing 2-phenyl-indole derivatives 失效
    含有2-苯基 - 吲哚衍生物的防晒组合物

    公开(公告)号：US4522808A

    公开(公告)日：1985-06-11

    申请号：US428755

    申请日：1982-09-30

    Applicant: Bernard Jacquet ,  Gerard Lang ,  Alain Malaval

    Inventor： Bernard Jacquet ,  Gerard Lang ,  Alain Malaval

    IPC: A61K8/49 ,  A61Q17/04 ,  C07D209/08 ,  C07D209/10 ,  C07D209/12 ,  C07D209/18 ,  C07D209/30 ,  A61K7/06 ,  A61K7/021 ,  A61K7/42 ,  A61K9/12

    CPC classification number: C07D209/30 ,  A61K8/492 ,  A61Q17/04 ,  C07D209/08 ,  C07D209/10 ,  C07D209/12 ,  C07D209/18 ,  Y10S424/01 ,  Y10S424/05

    Abstract: Anti-sunburn compositions are provided which comprise, as active ingredient, at least one compound of the general formula: ##STR1## in which: R.sub.1 is selected from hydrogen, alkyl radicals containing 1 to about 12 carbon atoms and optionally branched carboxyalkyl radicals containing 1 to 4 carbon atoms;R.sub.2 is selected from hydrogen, alkoxy radicals containing 1 to 4 carbon atoms, at least one alkyl and carboxyalkyl radical containing 1 to 4 carbon atoms, and halogen atoms.R.sub.3 is selected from hydrogen, carboxyalkyl radicals containing 1 to 4 carbon atoms and --S--R.sub.8 radicals, each of R.sub.4, R.sub.5, R.sub.6 and R.sub.7 is independently selected from hydrogen, and alkyl, carboxyalkyl and alkoxy radicals containing 1 to 4 carbon atoms, provided that if R.sub.3 denotes hydrogen, at least one of the radicals R.sub.1 R.sub.2, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 is not hydrogen, in an amount of at least about 0.05% by weight based on the total weight of the composition. These compounds have good solubility properties enabling a large number of different types of formulation to be prepared, these formulations being adjusted to meet the requirements of the skin to be protected.

    Abstract translation: 提供了防晒组合物，其包含作为活性成分的至少一种下列通式的化合物：其中：R 1选自氢，含有1至约12个碳原子的烷基和任选支化的羧基烷基 含有1至4个碳原子的基团; R2选自氢，含有1至4个碳原子的烷氧基，至少一个含有1至4个碳原子的烷基和羧基烷基以及卤素原子。 R 3选自氢，含有1至4个碳原子的羧基烷基和-S-R 8基团，R 4，R 5，R 6和R 7各自独立地选自氢和含有1至4个碳原子的烷基，羧基烷基和烷氧基， 条件是如果R3表示氢，基团R1R2，R4，R5，R6和R7中的至少一个不是氢，其量为组合物总重量的至少约0.05重量％。 这些化合物具有良好的溶解性，能够制备大量不同类型的制剂，这些制剂被调整以满足待保护皮肤的要求。

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