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    CATALYSTS AND METHOD FOR THE HYDROAMINATION OF OLEFINS
    65.
    发明申请
    CATALYSTS AND METHOD FOR THE HYDROAMINATION OF OLEFINS 有权
    催化剂和烯烃的水解方法

    公开(公告)号：US20120041236A1

    公开(公告)日：2012-02-16

    申请号：US13265457

    申请日：2010-04-19

    申请人： Thomas Heidemann ,  Jens Kehrer

    发明人： Thomas Heidemann ,  Jens Kehrer

    IPC分类号： C07C209/00 ,  B01J29/04 ,  C01B39/00

    CPC分类号： B01J29/7057 ,  B01J29/7007 ,  B01J37/0201 ,  B01J2229/186 ,  C07C209/60 ,  C07C211/07

    摘要： The present invention relates to a hydroamination catalyst comprising boron beta zeolites, wherein the hydroamination catalyst is doped with lithium, and also a process for producing it. The present patent application further relates to a process for preparing amines by reaction of ammonia or primary or secondary amines with olefins at elevated temperatures and pressures in the presence of the hydroamination catalyst of the invention.

    摘要翻译： 本发明涉及包含硼沸石的水解催化剂，其中所述水化催化剂掺杂有锂，并且还涉及其生产方法。 本专利申请还涉及在本发明的水解催化剂存在下，在升高的温度和压力下，通过氨或伯胺或仲胺与烯烃的反应来制备胺的方法。

    PROCESS FOR PREPARING ACETYLENE BY THE SACHSSE-BARTHOLOME PROCESS
    66.
    发明申请
    PROCESS FOR PREPARING ACETYLENE BY THE SACHSSE-BARTHOLOME PROCESS 有权
    通过SACHSSE-BARTHOLOME工艺制备乙烯的方法

    公开(公告)号：US20120022308A1

    公开(公告)日：2012-01-26

    申请号：US13183683

    申请日：2011-07-15

    申请人： Lucia Königsmann ,  Maximilian Vicari ,  Thomas Heidemann ,  Dirk Großschmidt ,  Jürgen Michel

    发明人： Lucia Königsmann ,  Maximilian Vicari ,  Thomas Heidemann ,  Dirk Großschmidt ,  Jürgen Michel

    IPC分类号： C07C4/22

    CPC分类号： C07C2/78 ,  C07C11/24

    摘要： A process is proposed for preparing acetylene by the Sachsse-Bartholomé process by combustion of a natural gas/oxygen mixture in one or more burners to obtain a cracking gas which is cooled in two or more stages in burner columns, each burner having one or more burner columns assigned thereto, and said cracking gas being quenched with pyrolysis oil in the first cooling stage, to obtain a low boiler fraction comprising benzene, toluene and xylene from the one or more burner columns, which is cooled with direct cooling water and separated in a phase separator into an aqueous phase and an organic phase which comprises benzene, toluene and xylene and is fully or partly introduced to the top of the one or more burner columns as a return stream, wherein the organic phase comprising benzene, toluene and xylene from the phase separator, prior to full or partial recycling to the top of the one or more burner columns, is supplied to a selective hydrogenation over a catalyst which comprises at least one platinum group metal on an inorganic metal oxide as support, comprising 0.05 to 5% by weight of platinum group metal, based on the total weight of the catalyst, and wherein the selective hydrogenation is performed at a pressure in the range from 10 to 70 bar gauge and a temperature in the range from 0 to 100° C.

    摘要翻译： 提出了一种通过Sachsse-Bartholomé方法通过在一个或多个燃烧器中燃烧天然气/氧气混合物来制备乙炔的方法，以获得在燃烧器柱中两级或更多级冷却的裂化气体，每个燃烧器具有一个或多个 燃烧器列，并且在第一冷却阶段，所述裂解气体用热解油淬火，以从一个或多个燃烧器柱获得包含苯，甲苯和二甲苯的低沸点馏分，其用直接冷却水冷却并分离 相分离器进入水相和有机相，其包含苯，甲苯和二甲苯，并作为回流完全或部分地引入到一个或多个燃烧器塔的顶部，其中有机相包含苯，甲苯和二甲苯 在完全或部分再循环到一个或多个燃烧器塔的顶部之前，将相分离器供应到催化剂上的选择性氢化，所述催化剂包括在l 在一个无机金属氧化物上的一个铂族金属作为载体，包含0.05-5重量％的铂族金属，基于催化剂的总重量，其中选择性氢化在10〜 70巴规，温度范围为0至100℃。

    PROCESS FOR PREPARING A PRIMARY AMINE WITH A TERTIARY ALPHA CARBON ATOM BY REACTING A TERTIARY ALCOHOL WITH AMMONIA
    69.
    发明申请
    PROCESS FOR PREPARING A PRIMARY AMINE WITH A TERTIARY ALPHA CARBON ATOM BY REACTING A TERTIARY ALCOHOL WITH AMMONIA 有权
    通过反应具有氨基酸的碱性醇来制备具有碱性阿尔法碳原子的主要胺的方法

    公开(公告)号：US20110009671A1

    公开(公告)日：2011-01-13

    申请号：US12739572

    申请日：2008-10-14

    申请人： Marcus Sigl ,  Thomas Heidemann

    发明人： Marcus Sigl ,  Thomas Heidemann

    IPC分类号： C07C209/16

    CPC分类号： C07C209/16 ,  C07C2603/74 ,  C07C211/07 ,  C07C211/38

    摘要： A process for preparing a primary amine with a tertiary alpha-carbon atom by reacting a tertiary alcohol with ammonia in the presence of a heterogeneous catalyst, by performing the reaction in the presence of a non-microporous, non-zeolitic aluminosilicate as a catalyst, where the aluminosilicate has a molar Al/Si ratio in the range from 0.1 to 30.

    摘要翻译： 通过在非均相催化剂的存在下，使叔醇与氨反应，通过在非微孔非沸石硅铝酸盐作为催化剂存在下进行反应来制备具有叔α-碳原子的伯胺的方法， 其中铝硅酸盐具有在0.1至30的范围内的Al / Si摩尔比。

    Oligomerization of alkenes in a plurality of successive heterogeneous catalyst zones
    70.
    发明授权
    Oligomerization of alkenes in a plurality of successive heterogeneous catalyst zones 有权
    烯烃在多个连续的非均相催化剂区域中的低聚

    公开(公告)号：US07291759B2

    公开(公告)日：2007-11-06

    申请号：US10518449

    申请日：2003-06-27

    申请人： Thomas Heidemann ,  Ursula Siebenhaar

    发明人： Thomas Heidemann ,  Ursula Siebenhaar

    IPC分类号： C07C2/02

    CPC分类号： C07C2/08 ,  C07C2523/755 ,  C07C2527/02

    摘要： Process for oligomerizing an alkene stream over a solid catalyst comprising sulfur and nickel, in which the oligomerization is carried out in two or more successive catalyst zones and the molar ratio of sulfur to nickel in the first catalyst zone is less than 0.5 and that in the last catalyst zone is 0.5 or more and, in the case of further catalyst zones between the first and last catalyst zones, the molar ratio of sulfur to nickel in each catalyst zone is not less than that in the immediately preceding catalyst zone, based on the main flow direction of the feed stream.

    摘要翻译： 在包含硫和镍的固体催化剂上使烯烃流低聚的方法，其中低聚反应在两个或更多个连续的催化剂区域中进行，并且第一催化剂区域中硫与镍的摩尔比小于0.5，而在 最后的催化剂区域为0.5以上，在第一催化剂区域和最后一个催化剂区域之间的另外的催化剂区域的情况下，各催化剂区域中的硫与镍的摩尔比不小于紧接在前一个催化剂区域的摩尔比，基于 进料流的主流向。