摘要:
In a rechargeable lithium battery including inter alia a lithium anode, a lithium ion reducible cathode bonded with a polymer, as well as a polymer electrolyte, potassium ions are introduced either in the cathode or in the electrolyte, or in both of them at the same time, so that potassium is distributed in the cathode and the electrolyte when the generator has reached equilibrium. This has the effect of stabilizing the performances of the battery during cycling in terms of energy and power.
摘要:
These additives are represented by the following general formula:L--Y--Sin which L designates a hydrocarbon radical which serves as lubricating segment; S designates an oligomer segment which serves as solvating segment of metallic salts and Y designates a chemical bond which joins the hydrocarbon radical and the oligomer segment. With these additives there is no more need to subsequently wash the surface of laminated lithium.
摘要:
An ionic compound comprising at least one group A.sup.+ X.sup.-, comprising:a cationic group A.sup.+ selected from the group consisting of biaryliodonium, arylsulfonium, arylacylsulfonium, diazonium and organometallic cations comprising a transition metal complexed with at least one unsaturated cyclic compound comprising 4-12 carbon atoms, said cationic group being part of a polymer chain; whereinX.sup.- is an imide anion, [FSO.sub.2 NSO.sub.2 R'.sub.F ].sup.- or [R.sub.F CH.sub.2 OSO.sub.2 NSO.sub.2 R'.sub.F ].sup.- or [(R.sub.F).sub.2 CHOSO.sub.2 NSO.sub.2 R'.sub.F ].sup.-, or a methylide anion [FSO.sub.2 C(Q)SO.sub.2 R'.sub.F ].sup.-, or a [R.sub.F CH.sub.2 OSO.sub.2 C(Q)SO.sub.2 R'.sub.F ].sup.- or [(R.sub.F).sub.2 CHOSO.sub.2 C(Q)SO.sub.2 R'.sub.F ].sup.31 .
摘要翻译:包含至少一种A + X-基团的离子化合物,其包含:选自二芳基碘鎓,芳基锍,芳基酰基锍,重氮鎓和有机金属阳离子的阳离子基团A +,其包含与至少一种不饱和环状化合物络合的过渡金属,所述不饱和环状化合物包含4- 12个碳原子,所述阳离子基团是聚合物链的一部分; 其中X-是酰亚胺阴离子,[FSO 2 NSO 2 R'F] - 或[RFCH 2 OSO 2 R O 2 R'F] - 或[(RF)2 CHOSO 2 NO 2 R'F] - 或甲基化阴离子[FSO 2 C(Q)SO 2 R' RFCH2OSO2C(Q)SO2R'F] - 或[(RF)2CHOSO2C(Q)SO2R'F] 31。
摘要:
An ionically conductive material which contains at least one ionic compound in solution in an aprotic solvent, wherein the ionic compound is selected from the group consisting of compounds of the formulae (1/mM).sup.61 ((ZY)2N).sup..crclbar., (1/mM).sup..sym. ((ZY).sub.3 C).sup..crclbar., or (1/mM).sup..sym. ((ZY).sub.2 CQ).sup..crclbar., wherein M, Z, Y and Q are as defined herein.
摘要:
The invention relates to monomers derived from perhalogenated sultones, to a process for their preparation, to the polymers obtained from the said monomers and to their use for the production of ion-conductive materials.The monomers are compounds corresponding to the formula A--CFX--SO.sub.2 Z in which A denotes one group R.sup.3 --O--CF.sub.2 -- or R.sup.3 -- or R.sup.1 R.sup.2 N--CO--; Z denotes F, Cl, --OSi(CH.sub.3).sub.3 or an ionic group, Z being other than F when A denotes R.sup.3 --O--CF.sub.2 -- or R.sup.3 --; X denotes F, Cl, H or R.sub.F, X being R.sub.F when A denotes R.sup.3 --; the radicals R.sup.1, R.sup.2 and R.sup.3 are chosen from polymerizable nonperfluorinated organic radicals; R.sub.F is chosen from perfluoroalkyl radicals and perfluoroaryl radicals.The polymers obtained from these monomers can be employed for the production of ion-conductive materials.
摘要:
The invention relates to copolymers, a process for preparing them and their use for the production of ionically conductive materials. The copolymers consist of identical or different organic blocks A which cannot be crosslinked by a radical route or by a Diels-Alder reaction, each of which has a valency i such that 1.ltoreq.i.ltoreq.6, and identical or different blocks Z(CH.sub.2).sub.j, in each of which Z denotes an organic radical which has a valency j such that 1.ltoreq.j.ltoreq.6, the radicals Z additionally containing at least one functional group permitting crosslinking by a radical route or by a Diels-Alder reaction; each block being joined to at least one other block by a functional group Y, the functional group Y being an ether functional group or a secondary or tertiary amine functional group. They are obtained by polycondensation of A(YH); monomers and Z(CH.sub.2 X).sub.j monomers, wherein Y is a leaving group. They are useful in the production of ionically conductive materials.
摘要:
The invention relates to copolymers, a process for preparing them and their use for the production of ionically conductive materials.The copolymers consist of identical or different organic blocks A which cannot be crosslinked by a radical route or by a Diels-Alder reaction, each of which has a valency i such that 1.ltoreq.i.ltoreq.6, and identical or different blocks Z(CH.sub.2).sub.j, in each of which Z denotes an organic radical which has a valency j such that 1.ltoreq.j.ltoreq.6, the radicals Z additionally containing at least one functional group permitting crosslinking by a radical route or by a Diels-Alder reaction; each block being joined to at least one other block by a functional group Y, the functional group Y being an ether functional group or a secondary or tertiary amine functional group.They are obtained by polycondensation of HYAYH monomers and Z(CH.sub.2 X).sub.j monomers, wherein Y is a leaving group.They are useful in the production of ionically conductive materials.
摘要:
A hydraulically controlled self-contained multi-functional hand tool including a hydraulic ram portion with a rod that activates two blades or arms. The blades articulate about a common pin and are mounted on a fork joint which is securely fixed to the body of the ram. Opening and closing of the blades is achieved by means of a system of links controlled directly by the rod associated with the hydraulic ram. The movement of the blades is obtained by means of an assembly which is integrated into the body of the tool. Said assembly includes an electric motor powered by a battery; drive means for compressing a fluid contained within a leaktight chamber, and a flexible membrane arranged in the chamber to compensate for fluid volume differences and to prevent formation of a vacuum in the chamber when fluid is moved to activate the tool. The compressed fluid is transferred by a directional control valve and feeder assembly within a reversible circuit which allows the fluid to act on either of two faces of a piston that controls the rod connected to the ram for activating the two blades or arms forming the tool. The assembly thus provided permits operation of the tool in a reversible manner while maintaining the same efficiency in both working directions.
摘要:
Process for producing organic cation radicals using anodic oxidation of an organic molecule in an electrochemical cell containing two electrodes upon which opposite polarity may be established and a liquid electrolyte which is an ion conductive material comprising a salt in solution in a liquid consisting essentially of at least one polar aprotic solvent selected from the group consisting of linear ethers, cyclic ethers, esters, carbonates, lactones, nitrate derivatives, amides, sulfones and sulfolanes, wherein said salt is represented by one of the following formulas: ##STR1## wherein M is an alkaline or alkaline earth metal, a transition metal or a rare earth metal,RF and R'F are identical or different and each represent a perhalogen radical having from 1 to 12 carbon atoms,QF is a perfluorinated bivalent radical having from 2 to 6 carbon atoms.
摘要:
An ionically conductive material useful in electrochemical generators is disclosed. This ionically material comprises a salt in solution in a solvent. The solvent comprises a sulfonated derivative of Formula (I):R.sub.1 R.sub.2 N--SO.sub.2 NR.sub.3 R.sub.4wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently a C.sub.1-10 alkyl group or a C.sub.1-10 oxaalkyl group.