Aqueous suspension of bentonite and its use for coating thermal
insulating molded articles
    72.
    发明授权
    Aqueous suspension of bentonite and its use for coating thermal insulating molded articles 失效
    膨润土的水悬浮液及其用于涂覆绝热模制品的用途

    公开(公告)号:US4670101A

    公开(公告)日:1987-06-02

    申请号:US749480

    申请日:1985-06-27

    IPC分类号: C04B30/02 D21F11/00

    CPC分类号: C04B30/02

    摘要: There is prepared an aqueous suspension which in addition to water, consists of 2 to 50 weight % of a mixture of bentonite and inorganic fibers, with the portion of inorganic fiber being 1 to 30 weight % and the portion of bentonite being 1 to 30 weight % and wherein the total amount of solids does not exceed 50 weight %. With the suspension there is attained an improvement of the mechanical properties of thermal insulating molded objects which are employed for thermal insulation and which for example, contain pyrogenically produced silica as a filler by delivery of this suspension on the thermal insulating plate. The suspension can also be delivered on thermal insulating molded bodies on which there is pressed a fiber net or a fiber felt. After applying the suspension several thermal insulating molded bodies can be joined together where the coating formed consisting of bentonite and inorganic fibers acts as binder. The heat insulating molded article in addition to this layer, can have one or more additional coatings based on organic or inorganic lacquer systems, silicone compositions or low melting glazes.

    摘要翻译: 制备水性悬浮液,除了水之外,由2〜50重量%的膨润土和无机纤维​​的混合物组成,无机纤维的比例为1〜30重量%,膨润土的比例为1〜30重量% %,其中固体的总量不超过50重量%。 通过悬浮液,绝热成型体的机械性能得到改善,其用于隔热,并且例如通过将该悬浮液输送到绝热板上而含有热解法生产的二氧化硅作为填料。 该悬浮液也可以在其上挤压纤维网或纤维毡的隔热成型体上输送。 应用悬浮液后,几个绝热成型体可以结合在一起,其中由膨润土和无机纤维​​组成的涂层作为粘合剂。 除了该层之外,绝热模制品可以具有一种或多种基于有机或无机漆系统,硅酮组合物或低熔点釉料的附加涂层。

    Bis-(silylethyl)-oligosulphides and process for their production
    75.
    发明授权
    Bis-(silylethyl)-oligosulphides and process for their production 失效
    双(甲硅烷基乙基) - 二硫化物及其生产方法

    公开(公告)号:US4444936A

    公开(公告)日:1984-04-24

    申请号:US461432

    申请日:1983-01-27

    摘要: Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH.sub.2 .dbd.CH).sub.m --SiR.sub.n.sup.1 R.sub.4--(m+n) in which R represents chlorine, bromine, iodine, C.sub.1 --C.sub.3 -alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R.sup.1 represents C.sub.1 --C.sub.3 -alkyl, phenyl or C.sub.5 --C.sub.7 -cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100.degree. and 200.degree. C. under pressure of from 1 to 25 bars (total pressure at the reaction) temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.

    摘要翻译: 通过使式(CH2 = CH)m-SiRn1R4-(m + n)的乙烯基硅烷(其中R表示氯,溴,碘,C1-C3-烷氧基,2-甲基苯基) 甲氧基乙氧基,2-乙氧基乙氧基或羟基,R1代表C1-C3-烷基,苯基或C5-C7-环烷基,n是0,1或2,m是1或2,m + n是1,2或3, 以及在给定情况下,在约100至200℃的温度下,乙烯基硅烷与硫的摩尔比为1:2.5至1:10的硫化氢和乙烯基硅烷至硫化氢的摩尔比为1:0至1:5 在1至25巴(反应总压力)温度的压力下,在本身已知的硫化催化剂的存在下,在给定的情况下,随后水解或部分水解反应产物。 双(甲硅烷基乙基) - 二硫化物用作含有硅酸盐填料的交联性橡胶混合物中的增强添加剂(粘合剂),在给定情况下用于炭黑以及在给定情况下硫和其它常规组分。

    Aqueous solution of cationic organosilicon compounds and process for the
production of the solutions
    77.
    发明授权
    Aqueous solution of cationic organosilicon compounds and process for the production of the solutions 失效
    阳离子有机硅化合物的水溶液及其制备方法

    公开(公告)号:US4390712A

    公开(公告)日:1983-06-28

    申请号:US298251

    申请日:1981-08-31

    IPC分类号: B03D1/01 C07F7/18 C07F7/10

    摘要: There are prepared aqueous solutions of cationic organosilicon compounds which are produced by reacting an alkoxysilylalkyl halide of the formula (RO).sub.3-n R.sub.n.sup.1 --Si--R.sup.2 --X (I) where R is C.sub.1 to C.sub.5 alkyl, methoxy, ethoxy, phenyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.1 is C.sub.1 to C.sub.5 alkyl, phenyl, tolyl, benzyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.2 is a divalent ethylenic double bond free hydrocarbon group having 3 to 8 carbon atoms, n is zero, 1 or 2 and X is chlorine, bromine, or iodine with a tertiary amine of the formula R.sup.3 NR.sup.4 R.sup.5 (II) where R.sup.3, R.sup.4, and R.sup.5 are the same or different and each is an alkyl group or benzyl in which the number of carbon atoms of the alkyl group or the alkyl groups together is up to 30 or R.sup.4 and .sup.5 together with the nitrogen atom, as well as in a given case a further hetero atom selected from the group consisting of oxygen, nitrogen, and sulfur is a univalent five to eight membered heterocyclic ring having three to seven --CH.sub.2 -- groups in the heterocyclic ring, or R.sup.5 is a C.sub.3 to C.sub.12 cycloalkyl group in aqueous medium at a temperature from room temperature (e.g. about 20.degree. C.) to 300.degree. C. at a mole ratio of (I) to (II) between 1:0.8 to 1:1,2 and in a given case under pressure.

    摘要翻译: 制备阳离子有机硅化合物的水溶液,其通过使式(RO)3-nRn1-Si-R2-X(I)的烷氧基​​甲硅烷基烷基卤化物反应制备,其中R是C1至C5烷基,甲氧基,乙氧基,苯基或 C5至C8环烷基; R 1是C 1至C 5烷基,苯基,甲苯基,苄基或C 5至C 8环烷基; R2是具有3-8个碳原子的二价烯键式双键无键烃基,n为0,1或2,X为氯,溴或碘,与式R3NR4R5(Ⅱ)的叔胺反应,其中R3,R4和 R5相同或不同,并且各自为烷基或苄基,其中烷基或烷基的碳原子数一起为至多30或R4和5以及氮原子以及在给定的 在另一个选自氧,氮和硫的杂原子的情况下,杂环中具有三至七个-CH 2 - 基的一价五元至八元杂环,或者R5是水性中的C3至C12环烷基 介质在室温(例如约20℃)至300℃的温度下以(I)至(II)的摩尔比为1:0.8至1:1.2,在给定情况下在压力下。

    Zirconium dioxide powder, method of its production and use
    78.
    发明授权
    Zirconium dioxide powder, method of its production and use 失效
    二氧化锆粉末,其生产和使用方法

    公开(公告)号:US06524548B1

    公开(公告)日:2003-02-25

    申请号:US09067915

    申请日:1998-04-29

    IPC分类号: C01G2500

    摘要: Pyrogenically, especially flame-hydrolytically produced zirconium dioxide powder with a specific surface area between 20 and 200 m2/g, a primary particle size between 7 and 100 nm, a tamped density of the deacidified and non-deacidified zirconium dioxide between 40 and 150 g/l with Sears numbers of the deacidified and non-deacidified zirconium dioxide between 1 and 20 ml/2 g and with a chlorine content of the deacidified zirconium dioxide less than 0.6% by weight. These are produced by evaporating zirconium halides, mixing the vapors alone or together with a carrier gas in a burner with air, oxygen, nitrogen and hydrogen, causing the gases to react with each other in a flame in a closed burner chamber, cooling off the waste gases and the zirconium dioxide in a heat exchanger unit, separating the waste gases from the zirconium dioxide and removing any halide remnants adhering to the zirconium dioxide by a heat treatment with moistened air.

    摘要翻译: 热原性地,特别是火焰水解生产的二氧化锆粉末,比表面积为20至200m2 / g,一次粒径在7至100nm之间,脱酸和非脱酸二氧化锆的密度为40-150g / S,数量为1至20ml / 2g之间的脱酸和非脱酸二氧化锆,并且脱酸二氧化锆的氯含量小于0.6重量%。 这些是通过蒸发卤化锆,将蒸气单独或与气体一起携带在具有空气,氧气,氮气和氢气的燃烧器中的气体混合而产生的,导致气体在封闭的燃烧器室中的火焰中彼此反应,冷却 废气和二氧化锆在热交换器单元中分离废气和二氧化锆,并通过用湿润的空气进行热处理除去附着在二氧化锆上的任何卤化物残余物。