摘要:
Catalyst compositions comprising a phosphorous-promoted ZSM-5 component and a silica-containing binder, and methods for making and using same, are disclosed. More specifically, processes for making a catalyst for biomass conversion are provided. The process includes: treating a ZSM-5 zeolite with a phosphorous-containing compound to form a phosphorous-promoted ZSM-5 component; preparing a slurry comprising the phosphorous-promoted ZSM-5 component and a silica-containing binder; and shaping the slurry into shaped bodies. Such catalysts can be used for the thermocatalytic conversion of particulate biomass to liquid products such as bio-oil, resulting in higher bio-oil yields and lower coke than conventional catalysts.
摘要:
The present invention provides new compositions of matter, referred to as quasi-crystalline carboxylates (QCCs), their preparation and use. The materials comprise a quasi-crystalline hydrated magnesium-aluminium hydroxy carboxylate and are characterised by the presence of at least a strong reflection in the powder X-ray diffraction pattern at a basal spacing in the range of 5 to 15 Å. The invention further relates to a process for preparing the QCCs, Mg—Al solid solutions and anionic clays under acidic conditions. The QCC is prepared by aging an acidic mixture of a magnesium carboxylate and an aluminium source. Calcination of the QCC results in a Mg—Al solid solution; rehydration of this solid solution gives an anionic clay.
摘要:
An economical and environment-friendly processes for the synthesis of anionic clays and the products made therefrom. It involves reacting a slurry comprising non-peptized boehmite with a magnesium source. There is no necessity to wash or filter the product. It can be spray dried directly to form microspheres or can be extruded to form shaped bodies. The product can be combined with other ingredients in the manufacture of catalysts, absorbents, pharmaceuticals, cosmetics, detergents, and other commodity products that contain anionic clays.
摘要:
A process for preparing a catalyst is disclosed. The process generally comprises the steps of: (a) preparing a slurry comprising clay, zeolite, a sodium-free silica source, quasi-crystalline boehmite, and micro-crystalline boehmite, provided that the slurry does not comprise peptized quasi-crystalline boehmite; (b) adding a monovalent acid to the slurry; (c) adjusting the pH of the slurry to a value above about 3, and (d) shaping the slurry to form particles. This process results in attrition resistant catalysts with a good accessibility.
摘要:
A process is disclosed for converting biomass to fuels and/or valuable chemicals. The process comprises the steps of a) activating biomass to make it more susceptible to conversion; c) partially converting the biomass to a solubilized material; and d) subjecting the unconverted biomass to a second conversion step. The process optionally comprises a step b) of adding a solvent to the activated biomass. In a preferred embodiment the solubilized biomass obtained in step c) is removed before the unconverted biomass is subjected to step d).
摘要:
A process is disclosed process for converting a solid or highly viscous carbon-based energy carrier material to liquid and gaseous reaction products, said process comprising the steps of: a) contacting the carbon-based energy carrier material with a particulate catalyst material b) converting the carbon-based energy carrier material at a reaction temperature between 200° C. and 450° C., preferably between 250° C. and 350° C., thereby forming reaction products in the vapor phase. In a preferred embodiment the process comprises the additional step of: c) separating the vapor phase reaction products from the particulate catalyst material within 10 seconds after said reaction products are formed. In a further preferred embodiment step c) is followed by: d) quenching the reaction products to a temperature below 200° C.
摘要:
A process is disclosed for mild hydro-conversion of oxygenated hydrocarbon compounds. The oxygenated hydrocarbon compounds are contacted with a hydro-conversion catalyst material at a reaction pressure below 100 bar.Preferred oxygenated hydrocarbon compounds are those obtained by the liquefaction of biomass.In a specific embodiment the process is used for production of normal alkanes by hydrotreating mixtures of triglycerides (or compounds derived-from triglycerides, including free fatty acids) and vacuum gasoil.
摘要:
A process is disclosed for converting a particulate biomass material to a bioliquid. In the process the biomass material is mixed with a heat transfer medium and a catalytic material, and heated to a temperature in the range of from 150 to 600° C. The particle size of the solid biomass may be reduced by abrasion in admixture with inorganic particles under agitation by a gas. The biomass particles of reduced size obtained in the abrasion process may be converted to bioliquid in any of a number of conversion processes.
摘要:
Novel compositions of matter comprising a cationic layered material and a second compound. The second compound has a reflection in its XRD pattern at 18.5 degrees two-theta, and s second reflection at 29 degrees two-theta. The composition of matter may be used in hydrocarbon conversion, purification, and synthesis processes, such as fluid catalytic cracking and hydroprocessing. The materials are especially suitable for the reduction of SOx and NOx emissions and the reduction of the sulfur and nitrogen content in fuels like gasoline and diesel.
摘要:
Process for the preparation of an aluminium phosphate-containing composition wherein an aluminium source is converted partly to aluminium phosphate using a phosphorus-containing compound and partly to (i) an anionic clay and/or a Al-MII mixed metal (hydr)oxide using a divalent metal (MII) source, (ii) an aluminosilicate using a silicon source, and/or (iii) a MII- aluminosilicate using both a divalent metal source and a silicon source.