Methods for Preparation of Graphene Nanoribbons From Carbon Nanotubes and Compositions, Thin Films and Devices Derived Therefrom
    72.
    发明申请
    Methods for Preparation of Graphene Nanoribbons From Carbon Nanotubes and Compositions, Thin Films and Devices Derived Therefrom 有权
    从碳纳米管和组合物制备石墨烯纳米带的方法,衍生自其的薄膜和器件

    公开(公告)号:US20100105834A1

    公开(公告)日:2010-04-29

    申请号:US12544017

    申请日:2009-08-19

    摘要: Methods for producing macroscopic quantities of oxidized graphene nanoribbons are disclosed herein. The methods include providing a plurality of carbon nanotubes and reacting the plurality of carbon nanotubes with at least one oxidant to form oxidized graphene nanoribbons. The at least one oxidant is operable to longitudinally open the carbon nanotubes. In some embodiments, the reacting step takes place in the presence of at least one acid. In some embodiments, the reacting step takes place in the presence of at least one protective agent. Various embodiments of the present disclosure also include methods for producing reduced graphene nanoribbons by reacting oxidized graphene nanoribbons with at least one reducing agent. Oxidized graphene nanoribbons, reduced graphene nanoribbons and compositions and articles derived therefrom are also disclosed herein.

    摘要翻译: 本文公开了生产宏观量的氧化石墨烯纳米带的方法。 所述方法包括提供多个碳纳米管并使多个碳纳米管与至少一种氧化剂反应以形成氧化石墨烯纳米带。 至少一种氧化剂可操作以纵向打开碳纳米管。 在一些实施方案中,反应步骤在至少一种酸的存在下进行。 在一些实施方案中,反应步骤在至少一种保护剂的存在下进行。 本公开的各种实施方案还包括通过使氧化石墨烯纳米带与至少一种还原剂反应来生产还原的石墨烯纳米带的方法。 氧化石墨烯纳米带,还原石墨烯纳米带以及由其衍生的组合物和制品也在本文中公开。

    FUNCTIONALIZED, HYDROGEN-PASSIVATED SILICON SURFACES
    73.
    发明申请
    FUNCTIONALIZED, HYDROGEN-PASSIVATED SILICON SURFACES 失效
    功能化,氢化硅表面

    公开(公告)号:US20090269593A1

    公开(公告)日:2009-10-29

    申请号:US12407471

    申请日:2009-03-19

    IPC分类号: B32B9/04

    摘要: This invention is generally related to a method of making a molecule-surface interface comprising at least one surface comprising at least one material and at least one organic group wherein the organic group is adjoined to the surface and the method comprises contacting at least one organic group precursor with at least one surface wherein the organic group precursor is capable of reacting with the surface in a manner sufficient to adjoin the organic group and the surface.

    摘要翻译: 本发明通常涉及一种制备分子 - 表面界面的方法,该分子 - 表面界面包括至少一个包含至少一种材料和至少一种有机基团的表面,其中有机基团邻接于该表面,并且该方法包括使至少一种有机基团 具有至少一个表面的前体,其中有机基团前体能够以足以邻接有机基团和表面的方式与表面反应。

    SHORT, FUNCTIONALIZED, SOLUBLE CARBON NANOTUBES, METHODS OF MAKING SAME, AND POLYMER COMPOSITES MADE THEREFROM
    74.
    发明申请
    SHORT, FUNCTIONALIZED, SOLUBLE CARBON NANOTUBES, METHODS OF MAKING SAME, AND POLYMER COMPOSITES MADE THEREFROM 有权
    短功能化,可溶性碳纳米管,其制备方法及其制备的聚合物复合材料

    公开(公告)号:US20090215953A1

    公开(公告)日:2009-08-27

    申请号:US12280523

    申请日:2007-02-22

    IPC分类号: C08K3/04 D01F9/12 C09K3/00

    摘要: In some embodiments, the present invention relates to new processes to simultaneously shorten and functionalize raw or purified carbon nanotubes to improve their dispersity and processibility, and the short functionalized nanotubes that may be made by the processes. This present invention also relates to new compositions of matter using short functionalized carbon nanotubes with thermoset, thermoplastic polymers, high temperature polymers, and other materials; the processes for making such composite materials; and the products of said processes.

    摘要翻译: 在一些实施方案中,本发明涉及同时缩短和官能化原始或纯化的碳纳米管以提高其分散性和可加工性的新方法以及可通过该方法制备的短官能化纳米管。 本发明还涉及使用具有热固性,热塑性聚合物,高温聚合物和其它材料的短官能化碳纳米管的物质的新组合物; 制造这种复合材料的方法; 和所述方法的产品。

    Hybrid molecular electronic device for switching, memory, and sensor applications, and method of fabricating same
    75.
    发明申请
    Hybrid molecular electronic device for switching, memory, and sensor applications, and method of fabricating same 审中-公开
    用于开关,存储器和传感器应用的混合分子电子器件及其制造方法

    公开(公告)号:US20080258179A1

    公开(公告)日:2008-10-23

    申请号:US11157391

    申请日:2005-06-21

    IPC分类号: H01L29/78 H01L21/336

    摘要: A hybrid molecular electronic device having switching, memory, and sensor application is disclosed. In one embodiment, the device resembles a conventional field-effect transistor (FET) formed on a silicon-on-insulator (SOI) substrate. Source and drain doped regions are formed in an upper surface of the SOI substrate, and a metallization layer which can serve as a gate contact is formed on a lower surface of the SOI substrate. A channel region spanning between the doped source and drain regions is left exposed, in order that a monolayer of molecules may be formed therein. Upon application of appropriate gating voltages to the gate contact, conduction between the source and drain regions can be modulated, possibly as a result of the reduction and oxidation of the molecules grafted to the gate region.

    摘要翻译: 公开了具有开关,存储器和传感器应用的混合分子电子器件。 在一个实施例中,该器件类似于形成在绝缘体上硅(SOI)衬底上的常规场效应晶体管(FET)。 源极和漏极掺杂区域形成在SOI衬底的上表面中,并且可以用作栅极接触的金属化层形成在SOI衬底的下表面上。 在掺杂源极和漏极区域之间跨越的沟道区域被暴露,以便可以在其中形成单分子层。 在向栅极接触施加适当的栅极电压时,源极和漏极区域之间的导电可以被调制,可能是由于接枝到栅极区域的分子的还原和氧化。

    Use of carbon nanomaterials with antioxidant properties to treat oxidative stress
    80.
    发明授权
    Use of carbon nanomaterials with antioxidant properties to treat oxidative stress 有权
    使用具有抗氧化性能的碳纳米材料来治疗氧化应激

    公开(公告)号:US09572834B2

    公开(公告)日:2017-02-21

    申请号:US14114007

    申请日:2012-04-26

    摘要: In some embodiments, the present invention provides methods of treating oxidative stress in a subject by administering a therapeutic composition to the subject. In some embodiments, the therapeutic composition comprises a carbon nanomaterial with anti-oxidant activity. In some embodiments, the anti-oxidant activity of the carbon nanomaterial corresponds to ORAC values between about 200 to about 15,000. In some embodiments, the administered carbon nanomaterials include at least one of single-walled nanotubes, double-walled nanotubes, triple-walled nanotubes, multi-walled nanotubes, ultra-short nanotubes, graphene, graphene nanoribbons, graphite, graphite oxide nanoribbons, carbon black, oxidized carbon black, hydrophilic carbon clusters, and combinations thereof. In some embodiments, the carbon nanomaterial is an ultra-short single-walled nanotube that is functionalized with a plurality of solubilizing groups. In some embodiments, the carbon nanomaterial is a polyethylene glycol functionalized hydrophilic carbon cluster (PEG-HCC). In some embodiments, the administered therapeutic compositions of the present invention may also include an active agent or targeting agent associated with the carbon nanomaterial. Additional embodiments of the present invention pertain to the aforementioned carbon nanomaterial compositions for treating oxidative stress.

    摘要翻译: 在一些实施方案中,本发明提供了通过向受试者施用治疗组合物来治疗受试者的氧化应激的方法。 在一些实施方案中,治疗组合物包含具有抗氧化活性的碳纳米材料。 在一些实施方案中,碳纳米材料的抗氧化活性对应于约200至约15,000之间的ORAC值。 在一些实施方案中,所施用的碳纳米材料包括单壁纳米管,双壁纳米管,三壁纳米管,多壁纳米管,超短纳米管,石墨烯,石墨烯纳米带,石墨,氧化石墨纳米带,碳 黑色,氧化炭黑,亲水性碳簇及其组合。 在一些实施方案中,碳纳米材料是用多个增溶基团官能化的超短单壁纳米管。 在一些实施方案中,碳纳米材料是聚乙二醇官能化的亲水性碳簇(PEG-HCC)。 在一些实施方案中,本发明施用的治疗组合物还可以包括与碳纳米材料相关的活性剂或靶向剂。 本发明的另外的实施方案涉及上述用于治疗氧化应激的碳纳米材料组合物。