SEQUESTERING POLYCYCLIC AROMATIC HYDROCARBONS IN ASPHALT
    74.
    发明申请
    SEQUESTERING POLYCYCLIC AROMATIC HYDROCARBONS IN ASPHALT 有权
    在ASPHALT中测序多环芳烃

    公开(公告)号:US20150020711A1

    公开(公告)日:2015-01-22

    申请号:US14506162

    申请日:2014-10-03

    摘要: This invention is based upon the discovery that activated carbon can be used to sequester polycyclic aromatic hydrocarbons that may be present in asphalt and creosote compositions. The treatment of asphalt and creosote compositions with activated carbon accordingly reduces the level of free polycyclic aromatic hydrocarbons in such compositions by sequestering them therein or removing them from the composition. After being sequestered the polycyclic aromatic hydrocarbons remain trapped in the asphalt or creosote composition, and are not available to the environment during normal processing into useful industrial products. This sequestration reduces the risk of exposing humans and the environment to the polycyclic aromatic hydrocarbons which would otherwise be free to migrate from the asphalt or creosote product during manufacturing and the service life of the product. In other words, the polycyclic aromatic hydrocarbons are absorbed onto the activated carbon and are not available for bioaccumulation from the environment.

    摘要翻译: 本发明基于以下发现:活性炭可用于螯合可能存在于沥青和杂酚油组合物中的多环芳烃。 用活性炭处理沥青和杂酚油组合物相应地降低了这些组合物中游离多环芳烃的含量,其中将它们封存在其中或将其从组合物中除去。 被隔离后,多环芳烃被捕获在沥青或杂酚油组合物中,并且在正常加工成有用的工业产品期间不能被环境使用。 这种隔离降低了将人类和环境暴露于多环芳烃的风险,多环芳烃在制造过程中和产品的使用寿命期间可能会从沥青或杂酚油产品中自由迁移。 换句话说,多环芳烃被吸收到活性炭上,不能用于从环境的生物累积。

    METHOD FOR PRODUCING POLYCYCLIC AROMATIC COMPOUND SUBSTITUTED BY ARYL GROUP
    75.
    发明申请
    METHOD FOR PRODUCING POLYCYCLIC AROMATIC COMPOUND SUBSTITUTED BY ARYL GROUP 有权
    用于生产由ARYL GROUP取代的多环芳香化合物的方法

    公开(公告)号:US20140206908A1

    公开(公告)日:2014-07-24

    申请号:US14125119

    申请日:2012-06-08

    IPC分类号: C07C41/30 C07C2/86 C07C17/361

    摘要: PAH is subjected to C—H/C—B coupling using a specific boron compound, a palladium compound, and o-chloranil to produce a compound in which a C—H bond of the PAH is directly arylated regioselectively in a simple manner. When the substrate and the boron compound are appropriately selected, a larger PAH can also be obtained by further performing an annulation reaction after the coupling reaction. Similarly, when PAH is subjected to C—H/C—H cross-coupling using a specific aromatic compound, a palladium compound, and o-chloranil, a compound in which a C—H bond of the PAH is directly arylated regioselectively can be produced in a simple manner. When the substrate and the aromatic compound are appropriately selected in this case, a larger PAH can also be obtained by further performing an annulation reaction after the cross-coupling reaction.

    摘要翻译: 使用特定的硼化合物,钯化合物和邻氯醌对PAH进行C-H / C-B偶联,得到其中PAH的C-H键以简单的方式直接芳基化的化合物。 当适当选择基材和硼化合物时,通过在偶联反应后进一步进行环化反应,也可以获得更大的PAH。 类似地,当使用特定芳族化合物,钯化合物和邻氯醌使PAH进行C-H / C-H交叉偶联时,其中PAH的C-H键直接芳基化的化合物可以是区域选择性的 以简单的方式生产。 当在这种情况下适当选择底物和芳香族化合物时,也可以通过进一步在交联反应后进行环丙烷化反应来获得更大的PAH。

    Bicyclo compound, method for producing pentacene and a film thereof using the same, and method for producing bicyclo compound
    78.
    发明授权
    Bicyclo compound, method for producing pentacene and a film thereof using the same, and method for producing bicyclo compound 有权
    双环化合物,并五苯的制造方法及其使用其的膜,以及双环化合物的制造方法

    公开(公告)号:US07884249B2

    公开(公告)日:2011-02-08

    申请号:US12551987

    申请日:2009-09-01

    IPC分类号: G03F7/20

    摘要: A method for producing highly purified fused aromatic ring compounds with high yield by a simpler method. A method for producing a fused aromatic ring compound comprising irradiating the bicyclo compound containing at least one bicyclo ring represented by formula (1) in a molecule with light to detach a leaving group X from a residual part to form an aromatic ring: wherein R1 and R3 each denotes a group to form an aromatic ring or a heteroaromatic ring which may be substituted, together with a group to which each thereof is bonded; R2 and R4 each denotes a hydrogen atom, an alkyl group, an alkoxy group, an ester group or a phenyl group; and X is a leaving group, which denotes a carbonyl group or —N═.

    摘要翻译: 通过较简单的方法生产高产率的高纯度稠合芳环化合物的方法。 一种稠合芳族环化合物的制造方法,其特征在于,在分子内用光分离含有至少一个式(1)表示的双环的双环化合物,从残留部分脱离出离去基团X,形成芳香环:其中R1和 R 3各自表示可以被取代的芳香环或杂芳环的基团以及与它们各自结合的基团。 R2和R4各自表示氢原子,烷基,烷氧基,酯基或苯基; X为离去基团,表示羰基或-N =。