Abstract:
By a silk fibroin porous material containing silk fibroin and an amino acid and a method for producing a silk fibroin porous material including freezing a fibroin solution having an amino acid added to a fibroin aqueous solution and subsequently thawing the solution to obtain a porous material, a porous material which does not contain a solvent and which is high in safety and a method for producing the same are provided.
Abstract:
Disclosed is a porous polyimide membrane of a three-layer structure having two surface layers (a) and (b) and a macrovoid layer interposed between the surface layers (a) and (b), wherein the macrovoid layer has a partition wall joined to the surface layers (a) and (b) and plural macrovoids surrounded by the partition wall and the surface layers (a) and (b), with an average void diameter in a membrane plane direction of from 10 to 500 μm; each of the partition wall of the macrovoid layer and the surface layers (a) and (b) has a thickness of from 0.1 to 50 μm and has plural pores having an average pore diameter of from 0.01 to 5 μm, the pores being communicated with each other and also communicated with the macrovoids; and the membrane has a total membrane thickness of from 5 to 500 μm and a porosity of from 70 to 95%.
Abstract:
This invention is directed to polysaccharide based aerogels, related to herein as aeropolysaccharides (aerocellulose) and reinforced aeropolysaccharides, and preparation thereof by an environmentally friendly process.
Abstract:
To provide a method for easily producing an ethylene/tetrafluoroethylene copolymer porous material having excellent chemical resistance and filtration performance and has a high heat resistance, within a wide range of the porosity, and an ethylene/tetrafluoroethylene copolymer porous material obtained by such a process.A process for producing an ethylene/tetrafluoroethylene copolymer porous material which comprises a step of dissolving an ethylene/tetrafluoroethylene copolymer having repeating units based on ethylene and repeating units based on tetrafluoroethylene at a temperature of at most 300° C. in a solvent which can dissolve the ethylene/tetrafluoroethylene copolymer at a temperature of at most 300° C., to achieve a predetermined concentration to obtain a solution, a step of forming the solution to obtain a formed product, and a step of cooling the formed product to a temperature of at most the phase separation temperature of the solution to solidify the ethylene/tetrafluoroethylene copolymer.
Abstract:
The invention relates to the production of microspheres having radial pores using thermally induced phase separation, especially microspheres for use in tissue engineering.
Abstract:
A process and kit to create a spongy polyamide material that absorbs hydrocarbons from liquid or solid surfaces is described. The process for making the spongy polyamide material includes dissolving a polyamide in a solvent, introducing a non-solvent into the polyamide solvent solution to precipitate a spongy polyamide material and thereafter formed into different shapes, if so desired. The kit allows for the spongy polyamide material to be made at the site of an hydrocarbon spill. In one embodiment, the kit includes a premixed polyamide and solvent solution for use with water to precipitate a spongy polyamide material to be extruded and cut into a user desired form.
Abstract:
A microporous biocompatible material is formed by preparing a segmented polyether urethane urea solution containing 25%.+-.1.5% solids dissolved in a solvent. The solution has sufficient viscosity to be preshaped and formed into the desired thickness of the finished article, then immediately immersed into a precipitation bath in which the solvent in the solution is miscible for a time interval sufficient to cause the solution to set up into an opaque elastomeric article. The article is immediately removed from the bath, any excess solvent extracted and then dried at a temperature on the order of 35.degree. C. to 70.degree. C. followed by heat treating by annealing for approximately sixty minutes at a temperature at 100.degree. C. to 130.degree. C. The void volume of the membrane solution is controlled to within the 50% to 80% range and the pore size from ca
Abstract:
The invention relates to films and tubular structures which are selectively permeable to liquids and gases which are based on a copolymer composed of a copolymerized fluorinated olefin, copolymerized vinyl acetate and, optionally, a copolymerized olefin. It is possible for the acetate groups of the copolymer to have been saponified to form OH groups. The films or tubular structures have in each case an inherent, latent capacity for modifying their structure and are at the same time oleophobic and oleophilic. The invention also embraces processes for the preparation of the shaped articles described and processes for modifying their structure. The invention also relates to the use of shaped articles according to the invention.
Abstract:
The present invention relates to molded articles of an open-cell structure, containing a copolymer which is comprised of copolymerized, fluorinated olefin, copolymerized vinyl acetate and optionally copolymerized olefin, the acetate groups of the copolymer being optionally saponified into OH groups. The molded articles possess an inherent latent structural convertibility and have effective pores of a diameter in the range from 0.002 to 10 .mu.m. The invention further includes processes for the preparation of the specified molded articles and processes for converting their structure. The invention also relates to several uses of molded articles according to the invention.
Abstract:
Simulated leather materials are described. These are obtained by treating a substrate having a microporous surface film layer by known processes for producing synthetic leathers. The microporous film is obtained by placing a dope containing film-forming polymer, a solvent therefore and an ionizable organic compound on a support and passing the dope bearing support through a coagulation bath under the application of an electric current. The resultant film has a microporous structure made up of open, vertically elongated and uniform cells which imparts a desirable full hand to the leather-like materials made therefrom.