公开(公告)号：US20140353554A1

公开(公告)日：2014-12-04

申请号：US14367041

申请日：2012-12-17

申请人： BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

发明人： Matthias Georg Schwab ,  Akimitsu Narita ,  Xinliang Feng ,  Klaus Muellen

IPC分类号： C01B31/04 ,  C08F138/00 ,  H01B1/04 ,  C07C49/683

CPC分类号： C01B31/0446 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C07C49/683 ,  C08F2/00 ,  C08F138/00 ,  C08G61/10 ,  C08G2261/1412 ,  C08G2261/312 ,  C08G2261/364 ,  C08G2261/46 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  C08L65/00 ,  H01B1/04 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/932

摘要： An oligophenylene monomer of general formula (I) wherein R1 and R2 are independently of each other H, halogene, —OH, —NH2, —CN, —NO2 or a linear or branched, saturated or unsaturated C1-C40 hydrocarbon residue, which can be substituted 1- to 5-fold with halogene (F, Cl, Br, I), —OH, —NH2, —CN and/or —NO2, and wherein one or more CH2-groups can be replaced by —O— or —S—, or an optionally substituted aryl, alkylaryl or alkoxyaryl residue; and m represents 0, 1 or 2.

摘要翻译： 通式（I）的低聚苯乙烯单体，其中R 1和R 2彼此独立地为H，卤素，-OH，-NH 2，-CN，-NO 2或直链或支链，饱和或不饱和的C 1 -C 40烃残基，其可以 用卤素（F，Cl，Br，I），-OH，-NH 2，-CN和/或-NO 2取代1至5倍，并且其中一个或多个CH 2 - 基团可以被-O-或 -S-或任选取代的芳基，烷基芳基或烷氧基芳基; m表示0,1或2。

公开(公告)号：US20140235813A1

公开(公告)日：2014-08-21

申请号：US13811758

申请日：2012-09-07

申请人： Glen Leon Brizius

发明人： Glen Leon Brizius

IPC分类号： C08F138/00 ,  C07F7/08

CPC分类号： C07F9/28 ,  C07F5/00 ,  C07F7/081 ,  C07F7/0827 ,  C07F9/4056 ,  C08F138/00 ,  C08G61/02 ,  C08G2261/1424 ,  C08G2261/212 ,  C08G2261/3328 ,  C08G2261/3422 ,  C08G2261/415

摘要： Methods for producing regioregular poly(aryl ethynyl)-poly(aryl vinyl) and monomers for preparing the regioregular poly(aryl ethynyl)-poly(aryl vinyl) polymers are described herein. Regioregular poly(aryl ethynyl)-poly(aryl vinyl) are useful for electronics, among other things.

摘要翻译： 本文描述了制备区域性聚（芳基乙炔基） - 聚（芳基乙烯基）和用于制备区域性聚（芳基乙炔基） - 聚（芳基乙烯基））聚合物的单体的方法。 方位聚（芳基乙炔基） - 聚（芳基乙烯基）可用于电子学等。

公开(公告)号：US08455590B2

公开(公告)日：2013-06-04

申请号：US13122792

申请日：2009-10-02

申请人： Takuro Oda

发明人： Takuro Oda

IPC分类号： C08F38/00 ,  C08F138/00 ,  C08F238/00

CPC分类号： C08F38/00 ,  C07C49/798 ,  C08F138/00 ,  C08F238/00

摘要： It is an object to provide a film having both high transparency and high heat resistance, and particularly a coating solution for forming a coating film from which an optical film can be produced. A triaroylbenzene-skeleton polymer in which a terminal of a polymer produced by polymerizing a compound of Formula [1] below is modified by a compound of Formula [2] below. A coating solution for forming a coating film, comprising the polymer. A film obtained from the coating solution for forming a coating film. In the formulae below, X1 is a divalent group of Formula [1a], Formula [1b], or Formula [1c] below (where Y1 and Y2 are independently a C1-2 alkylene group; n is an integer of 1 to 6; and m is an integer of 1 to 6), X2 is divalent benzene, thiophene, furan, or fluorine, and X3 is a hydrogen atom, a halogen atom, CF3, a C1-6 alkoxy group, or a C1-6 alkyl group.

摘要翻译： 本发明的目的是提供具有高透明度和高耐热性的膜，特别是用于形成可以制造光学膜的涂膜的涂布溶液。 通过聚合下述式[1]的化合物制备的聚合物的末端可以通过下述式[2]的化合物改性的三芳基苯骨架聚合物。 一种用于形成涂膜的涂布溶液，其包含聚合物。 从用于形成涂膜的涂布溶液获得的膜。 在下式中，X 1是式[1a]，式[1b]或式[1c]的二价基团（其中Y1和Y2独立地是C1-2亚烷基; n是1至6的整数; m为1〜6的整数），X2为二价苯，噻吩，呋喃或氟，X3为氢原子，卤素原子，CF3，C1-6烷氧基或C1-6烷基 。

公开(公告)号：US08436118B2

公开(公告)日：2013-05-07

申请号：US12451527

申请日：2008-03-04

申请人： Benzhong Tang ,  Ka Wai Jim ,  Anjun Qin ,  Matthias Haeussler ,  Wing Yip Lam

发明人： Benzhong Tang ,  Ka Wai Jim ,  Anjun Qin ,  Matthias Haeussler ,  Wing Yip Lam

IPC分类号： C08F138/00 ,  C08F38/00 ,  C07C15/00 ,  C07C15/02

CPC分类号： C08G63/20 ,  C08G63/00

摘要： The present invention provides a new metal-free cyclotrimerization reaction of alkynes to produce a 1,3,5-triacylarylene or 1,3,5-triacylbenzene. This reaction is catalyzed by secondary amines, is strictly regioselective, highly functionality-tolerant, and the resulting product can be obtained in high yields. This reaction can be further applied for the preparation of novel branched (co)polymers bearing the triacylarylenes as structural units. The preparation of the (co)polymers is carried out as a one-pot single-step reaction procedure, giving branched oligomers and polymers in high yields up to 90%. The produced (co)polymers are also processible, easily film-forming, and thermally stable.

摘要翻译： 本发明提供了一种新的无金属的炔炔环化三聚反应，产生1,3,5-三酰基亚芳基或1,3,5-三酰基苯。 该反应由仲胺催化，是严格区域选择性的，具有高度的官能度 - 耐受性，所得产物可以高产率获得。 该反应可以进一步用于制备具有三酰基亚芳基作为结构单元的新型支链（共）聚合物。 （共）聚合物的制备是作为一锅一步反应方法进行的，以高产率提供高达90％的支链低聚物和聚合物。 生产的（共）聚合物也是可加工的，容易成膜和热稳定的。

公开(公告)号：US20020193543A1

公开(公告)日：2002-12-19

申请号：US10108420

申请日：2002-03-29

发明人： Xumu Zhang ,  Aiwen Lei

IPC分类号： C08F138/00

CPC分类号： B01J31/0231 ,  B01J23/44 ,  B01J31/24 ,  B01J31/2452 ,  B01J2231/12 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2231/4205 ,  B01J2231/4211 ,  B01J2231/4277 ,  B01J2531/0266 ,  B01J2531/16 ,  B01J2531/64 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/847 ,  C07C1/321 ,  C07C17/269 ,  C07C45/72 ,  C07C201/12 ,  C07C205/06

摘要： Compositions and processes of forming chemical bonds, such as carbon-carbon and carbon-heteroatom bonds are provided. The compositions include at least one null-halo carbonyl compound, and one or more transmetallation reagents. The transmetallation reagents are formed by the addition of a metal or metal catalyst to a target compound. The target compound is the compound undergoing chemical bond formation. Bond formation can be carried out in both intermolecular reactions (i.e. between two or more target compounds), or intramolecular (within the same target compound) reactions.

摘要翻译： 提供了形成化学键的组成和方法，例如碳 - 碳和碳 - 杂原子键。 组合物包括至少一种α-卤代羰基化合物和一种或多种转金属试剂。 通过向目标化合物中加入金属或金属催化剂形成转金属试剂。 目标化合物是化学键形成的化合物。 键形成可以在分子间反应（即两种或多种目标化合物之间）或分子内（在相同的目标化合物）反应中进行。

公开(公告)号：US20020016422A1

公开(公告)日：2002-02-07

申请号：US09901891

申请日：2001-07-11

发明人： Thomas Preiss ,  Holger Friedrich ,  Jochem Henkelmann

IPC分类号： C08F004/06 ,  C08F004/42 ,  C08F030/08 ,  C08F038/00 ,  C08F138/00 ,  C08F238/00

CPC分类号： C07F7/1876 ,  C07F7/14

摘要： In the process for the preparation of vinylsilanes by reacting acetylenic hydrocarbons with silanes which have at least one silicon-bonded hydrogen atom in the liquid phase in the presence of a catalyst, the silane is added to the liquid phase. In particular, the reaction is carried out at superatmospheric pressure, and the spent acetylenic hydrocarbon is replenished during the reaction while maintaining a pressure which is constant during the entire reaction.

公开(公告)号：US5864050A

公开(公告)日：1999-01-26

申请号：US743997

申请日：1996-11-04

申请人： Yoshihiro Taguchi ,  Shiro Kobayashi ,  Hiroshi Uyama ,  Atsushi Nakamura

发明人： Yoshihiro Taguchi ,  Shiro Kobayashi ,  Hiroshi Uyama ,  Atsushi Nakamura

IPC分类号： C07C45/68 ,  C07C45/71 ,  C07C49/84 ,  C08F290/06 ,  C08F299/04 ,  C08G65/40 ,  C08G65/48 ,  C08F138/00 ,  C07C49/796

CPC分类号： C08G65/48 ,  C07C45/68 ,  C07C45/71 ,  C07C49/84 ,  C08G65/4012 ,  C08G2650/20 ,  C08G2650/60 ,  C08L2312/00

摘要： The present invention provides a curable resin compound which is soluble in organic solvents and easy to use, and a method for producing the same. The curable resin compound comprises a structure and crosslinkable groups which end-cap the structure, the structure comprising three or four non-substituted benzene rings each of which is joined with each adjacent benzene ring by an ether or ketone linkage so that both types of linkages are present in the structure. Though the curable resin compound exhibits satisfactory solubilities in organic solvents, a composition comprising the compound can be cured by a crosslinking reaction to be insoluble in the organic solvents while being provided with improved solvent resistance and chemical resistance. Accordingly, the present invention also provides a cured-resin material derived from the aforementioned curable resin compound, the cured-resin material being excellent in solvent resistance, chemical resistance and thermal resistance.

摘要翻译： 本发明提供一种可溶于有机溶剂且易于使用的可固化树脂化合物及其制备方法。 可固化树脂化合物包括结构和端基结构的可交联基团，其结构包含三个或四个未取代的苯环，每个苯环通过醚或酮键与每个相邻的苯环连接，使得两种类型的键 存在于结构中。 尽管可固化树脂化合物在有机溶剂中表现出令人满意的溶解性，但是包含该化合物的组合物可以通过交联反应固化而不溶于有机溶剂，同时具有改进的耐溶剂性和耐化学性。 因此，本发明还提供了由上述固化性树脂化合物衍生的固化树脂材料，其耐溶剂性，耐化学性和耐热性优异的固化树脂材料。

公开(公告)号：US5373071A

公开(公告)日：1994-12-13

申请号：US77483

申请日：1993-06-14

申请人： Eit Drent ,  Dennis H. L. Pello

发明人： Eit Drent ,  Dennis H. L. Pello

IPC分类号： C08F4/60 ,  C08F4/00 ,  C08F4/26 ,  C08F38/00 ,  C08F38/02 ,  C08F4/80 ,  C08F138/00

CPC分类号： C08F38/00

摘要： A process for the polymerization of actylenically unsaturated compounds by contacting the monomer(s) under polymerization conditions with a catalyst system comprising:a) a source of cations of one or more Group VIII metals;b) a bidentate ligand containing phosphorus, arsenic and/or antimony; andc) a source of anions.

摘要翻译： 通过使聚合条件下的单体与催化剂体系接触来使活性不饱和化合物聚合的方法包括：a）一种或多种VIII族金属的阳离子源; b）含磷，砷和/或锑的二齿配体; 和c）阴离子的来源。

公开(公告)号：US4925612A

公开(公告)日：1990-05-15

申请号：US402301

申请日：1989-09-05

申请人： Katsunori Waragai ,  Yukihiro Saito ,  Shiro Asakawa

发明人： Katsunori Waragai ,  Yukihiro Saito ,  Shiro Asakawa

IPC分类号： B05D1/30 ,  B29C41/12 ,  B29D7/01 ,  B29L7/00 ,  C08F138/00 ,  C08J5/18

CPC分类号： B29C41/12 ,  B29D7/01

摘要： A method for making a polymer thin film wherein a first polymer thin film is formed on a support liquid, on which a solution of a second polymer is dropped is described. The first polymer film is pulled in opposite directions to break the first polymer film as a slit, from which the second polymer solution is cast on the support liquid. As a result, the solution can spread uniformly without involving any appreciable irregularity in thickness of a final film product.

公开(公告)号：US4809573A

公开(公告)日：1989-03-07

申请号：US113552

申请日：1987-10-26

申请人： Harold D. Welch

发明人： Harold D. Welch

IPC分类号： B26D1/40 ,  B05D1/20 ,  B23D36/00 ,  B26D5/26 ,  B26D9/00 ,  C07C57/18 ,  C07C57/52 ,  C07C205/37 ,  C08F138/00 ,  G02F1/00 ,  G02F1/361 ,  G03F7/025

CPC分类号： B82Y30/00 ,  B05D1/202 ,  B23D36/0041 ,  B26D5/26 ,  B26D9/00 ,  B82Y40/00 ,  C07C205/37 ,  C07C57/18 ,  C07C57/52 ,  C08F138/00 ,  G02F1/0018 ,  G02F1/3615 ,  G03F7/025 ,  B26D2011/005 ,  Y10T83/0515 ,  Y10T83/141 ,  Y10T83/159 ,  Y10T83/175 ,  Y10T83/178 ,  Y10T83/4682 ,  Y10T83/4691 ,  Y10T83/525 ,  Y10T83/531 ,  Y10T83/538 ,  Y10T83/541 ,  Y10T83/543

摘要： A control system is established wherein, when there is a flow of continuous web material (2), an identification phase is provided by increasing the torque signal to a pull roll motor (13) until slippage between the pull roll (12) and continuous web is created at a breakaway torque point, the value of which is measurable. The pull roll motor is then caused to be driven by a signal which creates a motor torque output which is of a value less than the breakaway torque point. Thus, no slippage can occur. As the motor is driven at the lower torque value, a calibration phase is entered wherein an encoder output of the pull roll is properly equated with that of a measuring wheel (9), this phase occuring at a time when there can be no slip between the web-roll interface. The identification-calibration process can be repeated as often as desired. The control system further includes the ability to cause acceleration of the pull roll after the web has been severed upstream to thereby accelerate the tail or downstream portion of the severed discontinuous web until a desired gap is created for use in a slitting device (6). At this point, which is subsequent to the identification-calibration phases, the control returns the motor input to the lower torque value.

摘要翻译： 建立了一种控制系统，其中当存在连续幅材材料（2）的流动时，通过将拉力马达（13）的扭矩信号增加直到牵引辊（12）和连续幅材（12）之间滑动来提供识别阶段 在分离转矩点处产生，其值是可测量的。 然后通过产生具有小于分离转矩点的值的电动机转矩输出的信号使拉辊电动机驱动。 因此，不会发生滑动。 当电机以较低的扭矩值被驱动时，进入校准阶段，其中拉辊的编码器输出被适当地等于测量轮（9）的编码器输出，该相位在两相之间没有滑移之间发生 网络卷界面。 可以根据需要经常重复识别校准过程。 控制系统还包括在卷材已经被上游切断之后引起拉辊的加速的能力，从而加速切断的不连续卷材的尾部或下游部分，直到产生用于分切装置（6）的期望的间隙。 此时，在识别 - 校准阶段之后，控制将马达输入返回到较低的扭矩值。