摘要:
The present invention relates to genes, proteins and methods comprising or utilizing C-repeat binding factors (CBF), specifically CBF3 in the ryegrass family. In a preferred embodiment, the present invention relates to using ryegrass CBF3 for altering cold tolerance and growth in plants, specifically in warm season grasses, turfgrasses, fodder plants and microorganisms.
摘要:
Processes for producing citraconic anhydride and citraconic acid using porous materials with specific surface acidities and surface areas are described. The preferred catalyst is a porous gamma alumina. Itaconic acid is produced from citraconic acid. Itaconic acid is an intermediate to a variety of compounds including polymers.
摘要:
A process for producing organic substituted aromatic or heteroaromatic compounds including biaryl and biheteroaryl compounds in a two-step reaction. In the first step, the aromatic or heteroaromatic compound is borylated in a reaction comprising a borane or diborane reagent (any boron reagent where the boron reagent contains a BnullH, BnullB or BnullSi bond) and an iridium or rhodium catalytic complex. In the second step, a metal catalyst catalyzes the formation of the organic substituted aromatic or heteroaromatic compound from the borylated compound and an electrophile such as an aryl or organic halide, triflate (OSO2CF3), or nonaflate (OSO2C4F9). The steps in the process can be performed in a single reaction vessel or in separate reaction vessels. The present invention also provides a process for synthesis of complex polyphenylenes starting from halogenated aromatic compounds.
摘要翻译:一种在两步反应中制备包括联芳基和双杂芳基化合物的有机取代的芳族或杂芳族化合物的方法。 在第一步中,在包含硼烷或乙硼烷试剂(硼试剂含有B-H,B-B或B-Si键的任何硼试剂)和铱或铑催化络合物的反应中,芳族或杂芳族化合物被硼酸化。 在第二步中,金属催化剂催化从硼化化合物和亲电体如芳基或有机卤化物,三氟甲磺酸酯(OSO 2 CF 3)或非卤化物(OSO 2 C 4 F 9)形成有机取代的芳香族或杂芳族化合物。 该方法中的步骤可以在单个反应容器中或在单独的反应容器中进行。 本发明还提供从卤代芳族化合物开始合成络合聚苯的方法。
摘要:
A human pancreatic ductal epithelial cell line immortalized with the human papilloma virus E6 and E7 genes which has stem cell-like characteristics and which can be induced to differentiate into ductal-like cells and beta-like cells that produce insulin. The immortal cells or derivative thereof are useful for treating insulin-dependent diabetes and in assays for determining the ability of a chemical to induce pancreatic stem cell differentiation or malignancy.
摘要:
Mesoporous hexagonal, cubic or wormhole aluminosilicates derived from zeolite seeds using an ionic structure directing agent are described. The aluminum in the structures is stable so that the framework of the structures does not collapse when heated in the presence of water or water vapor (steam). The steam stable aluminosilicates can be used as acid catalysts for hydrocarbon conversions, including the fluidized bed catalytic cracking and the hydrocracking of petroleum oils, and other cracking of organic compounds.
摘要:
Processes for the preparation of pyrrolidones (7 and 8) and pyrrolidines (9 and 10) from tri-O-acetyl-D-erythro-4-pentulosonic acid esters are described. The compounds are aza sugar analogs of D-ribofuranoside and are intermediates to drugs which regulate nucleoside and nucleic acid synthesis.
摘要:
A process for the preparation of 1,5-dideoxy null1,5-imino hexitols of a hexose sugars from novel hydroxyl protected oxime intermediates. The process includes formation of a lactam which is reduced to the hexitol. The hexitols are useful as drugs.
摘要:
An elutriation apparatus which combines pressurized liquid nozzles (16A) and the low energy air nozzles (20) producing bubbles for flotation and separation of trace materials in a heterogeneous mixture of materials is described. Quantitative separation of trace evidence is achieved by the apparatus by a closed system of mechanical separations using the water and the air to isolate and deposit trace evidence on a fine mesh screen filter (17) submerged in the water (24) in a container (23). The method provides a rapid, quantitative and inexpensive method for detection of the evidence in soil samples.
摘要:
A novel isolate of Bacillus isolated from white pine is described. The isolate is used to produce monoterpene derivatives. Also described is a pinene hydroxylase enzyme from the isolate. The enzyme is a general allylic oxidizer.
摘要:
Polymers and processes for synthesizing the polymers from .alpha.,.beta.-unsaturated lactones, particularly 2(5H)-furanone, and amines with side chains. The polymers are used as hydrogels, as polymers that can bind metals and form complexes that are soluble in organic solvents, as polymers useful as flocculants in water purification, as polymers useful on non-fouling surfaces for biofilm suppression, polymers for use on non-thrombogenic surfaces, and polymers with uses as thin conductive films for microchips and other electronic devices. The process is a polymerization reaction involving the cyclic .alpha.,.beta.-unsaturated lactone and a primary amine or primary ammonium compound.