公开(公告)号：US06830596B1

公开(公告)日：2004-12-14

申请号：US09606887

申请日：2000-06-29

申请人： Harry W. Deckman ,  John W. Fulton ,  Jeffrey M. Grenda ,  Frank Hershkowitz

发明人： Harry W. Deckman ,  John W. Fulton ,  Jeffrey M. Grenda ,  Frank Hershkowitz

IPC分类号： C10J300

CPC分类号： C01B3/501 ,  B01J8/009 ,  B01J12/007 ,  B01J19/2425 ,  B01J19/2475 ,  B01J35/065 ,  B01J2208/00256 ,  B01J2208/00309 ,  B01J2208/0053 ,  B01J2208/00539 ,  B01J2219/0002 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0288 ,  C01B2203/041 ,  C01B2203/0495 ,  C01B2203/06 ,  C01B2203/0805 ,  C01B2203/0811 ,  C01B2203/0827 ,  C01B2203/0844 ,  C01B2203/0866 ,  C01B2203/0883 ,  C01B2203/1011 ,  C01B2203/1035 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1205 ,  C01B2203/1241 ,  C01B2203/1288 ,  C01B2203/148 ,  C01B2203/82 ,  C01B2203/84 ,  C01B2203/86 ,  Y02C10/14 ,  Y02P20/52 ,  Y02P30/30

摘要： This invention is directed to a heat exchanged membrane reactor for electric power generation. More specifically, the invention comprises a membrane reactor system that employs catalytic or thermal steam reforming and a water gas shift reaction on one side of the membrane, and hydrogen combustion on the other side of the membrane. Heat of combustion is exchanged through the membrane to heat the hydrocarbon fuel and provide heat for the reforming reaction. In one embodiment, the hydrogen is combusted with compressed air to power a turbine to produce electricity. A carbon dioxide product stream is produced in inherently separated form and at pressure to facilitate injection of the CO2 into a well for the purpose of sequestering carbon from the earth's atmosphere.

摘要翻译： 本发明涉及用于发电的热交换膜反应器。 更具体地，本发明包括在膜的一侧采用催化或热蒸汽重整和水煤气变换反应的膜反应器系统，并且在膜的另一侧上进行氢燃烧。 燃烧热通过膜交换以加热烃燃料并为重整反应提供热量。 在一个实施例中，氢气与压缩空气一起燃烧，为涡轮机供电以产生电力。 以固有分离的形式和压力产生二氧化碳产物流，以便于将CO 2注入井中，以便从地球大气中隔离碳。

公开(公告)号：US06726850B1

公开(公告)日：2004-04-27

申请号：US09484378

申请日：2000-01-14

申请人： Sebastian C. Reyes ,  Jennifer S. Feeley ,  Frank Hershkowitz ,  Harry W. Deckman ,  Ioannis P. Androulakis

发明人： Sebastian C. Reyes ,  Jennifer S. Feeley ,  Frank Hershkowitz ,  Harry W. Deckman ,  Ioannis P. Androulakis

IPC分类号： C01B326

CPC分类号： C01B3/386 ,  C01B2203/0261 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/065 ,  C01B2203/1011 ,  C01B2203/1029 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1276

摘要： A multistage catalytic partial oxidation (CPO) process for oxidizing a hydrocarbon feedstream comprising C1-C4 hydrocarbons, with an oxygen-containing feedstream to produce a product comprising CO and H2, also known as synthesis gas or syngas. The process employs a CPO catalyst, and controlled process features, including: (A) the total oxygen requirement for the process is introduced incrementally, in more than one reaction stage, using an oxygen-containing feedstream at more than one feed point in the process, each stage including a catalyst; (B) the oxygen-containing feedstream, hydrocarbon feedstream and, in reaction stages after the first of said multiple stages, the intermediate product produced in the prior stage, are mixed for a period of time, after they are brought into contact with one another, of less than about 1 millisecond to form a substantially uniform mixture, wherein the mixture is then contacted with the catalyst; (C) the oxygen-containing feedstream and the hydrocarbon feedstream are preheated prior to entry into the first stage, to a temperature of from about 450° C. to less than about 1,000° C.; and (D) the mixture temperature of the product in each stage following the first stage is from greater than about 600° C. to less than about 1,000° C. Preferably, the process comprises less than or equal to about five stages, the first stage preheat temperature recited in step (C) is greater than about 550° C. and the mixture temperature of the product in each stage following the first stage is at least 700° C.

摘要翻译： 用于将包含C1-C4烃的烃进料流与含氧进料流氧化以产生包含CO和H 2的产物（也称为合成气或合成气）的多级催化部分氧化（CPO）方法。 该方法采用CPO催化剂和受控工艺特征，包括：（A）在多于一个反应阶段中，使用含氧进料流在多于一个进料点的过程中逐步引入该方法的总氧需求量 ，每个阶段包括催化剂; （B）含氧进料流，烃类原料流，在上述多阶段第一阶段后的反应阶段中，将前一阶段生产的中间产物在彼此接触后混合一段时间 ，小于约1毫秒以形成基本均匀的混合物，其中混合物然后与催化剂接触; （C）在进入第一阶段之前将含氧进料流和烃进料流预热至约450℃至小于约1,000℃的温度; 和（D）在第一阶段之后的每个阶段中的产物的混合物温度为大于约600℃至小于约1000℃。优选地，该方法包括小于或等于约五个阶段，第一阶段 步骤（C）中所述的阶段预热温度大于约550℃，并且在第一阶段之后的每个阶段中的产品的混合物温度为至少700℃

公开(公告)号：US5935489A

公开(公告)日：1999-08-10

申请号：US845707

申请日：1997-04-25

申请人： Frank Hershkowitz ,  Harry W. Deckman ,  Robert P. Reynolds ,  Constantine P. Gonatas ,  John W. Fulton ,  Leonard Schoenman ,  Jack I. Ito

发明人： Frank Hershkowitz ,  Harry W. Deckman ,  Robert P. Reynolds ,  Constantine P. Gonatas ,  John W. Fulton ,  Leonard Schoenman ,  Jack I. Ito

IPC分类号： B01F3/02 ,  B01F5/00 ,  B01F5/06 ,  B01J4/00 ,  B01J8/02 ,  B01J10/00 ,  B01J19/24 ,  C01B3/36 ,  C01B3/38 ,  C10G2/00 ,  F23D14/22 ,  F23D14/62 ,  C07C1/02 ,  C01B3/24 ,  C01B31/18 ,  C07C27/00

CPC分类号： F23D14/62 ,  B01F5/0604 ,  B01F5/0682 ,  B01J10/00 ,  B01J19/249 ,  B01J8/0278 ,  C01B3/36 ,  C01B3/363 ,  C01B3/382 ,  C10G2/30 ,  F23D14/22 ,  B01F3/02 ,  B01J2208/022 ,  B01J2219/2453 ,  B01J2219/2462 ,  B01J2219/247 ,  B01J2219/2477 ,  B01J2219/2481 ,  B01J2219/2485 ,  C01B2203/142 ,  C01B2203/82

摘要： A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for recovery and/or subsequent hydrocarbon synthesis. Sources comprising a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas, preheated and pressurized, are injected through an injector means at high velocity into admixture with each other in the desired relative proportions, at a plurality of mixing nozzles which are open to the partial oxidation zone of a reactor and are uniformly-spaced over the face of the injector means, to form a reactant gaseous premix having a pressure at least 3% lower than the lowest upstream pressure of either of the streams of the individual gases. The gaseous premix is injected in a time period which is less than its autoignition time, preferably less than 9 milliseconds, at a velocity between about 25 to 1000 feet/second, into the partial oxidation zone of the reactor. The gas mixture reacts before or simultaneously with the autoignition time delay of the mixture, to reduce the amounts of CO.sub.2, H.sub.2 O and heat produced by the partial oxidation reaction to form a useful syngas which is cooled and recovered.

摘要翻译： 一种新颖的注射器/反应器装置以及用于部分氧化轻质烃气体（例如甲烷）的有效方法，以将这种气体转化成有用的合成气以用于回收和/或随后的烃合成。 源于包含轻质烃气体（例如甲烷）和预热和加压的氧气或含氧气体的源通过喷射器装置以高速度以相关比例以所需的相对比例在多个混合喷嘴 其对于反应器的部分氧化区开放并且在喷射器装置的表面上均匀间隔开，以形成反应物气体预混物，该反应物气体预混物的压力比其中任一流的最低上游压力低至少3％ 个别气体。 在低于其自燃时间（优选小于9毫秒）的时间段内，以约25至1000英尺/秒的速度将气体预混物注入反应器的部分氧化区。 气体混合物在混合物的自燃时间延迟之前或同时反应，以减少CO 2，H 2 O的量和由部分氧化反应产生的热量，以形成冷却和回收的有用的合成气。

公开(公告)号：US5210059A

公开(公告)日：1993-05-11

申请号：US775657

申请日：1991-10-10

申请人： Michael G. Matturo ,  Harry W. Deckman ,  James A. McHenry ,  Robert P. Reynolds, Jr.

发明人： Michael G. Matturo ,  Harry W. Deckman ,  James A. McHenry ,  Robert P. Reynolds, Jr.

IPC分类号： B01J31/06 ,  B01D71/02 ,  B01J35/02 ,  B01J35/06 ,  C23C14/06

CPC分类号： B01D69/12 ,  B01D67/0072 ,  B01D69/141 ,  B01D71/02 ,  B01J35/065 ,  B01D2325/10

摘要： The present invention is a multilayered catalyst structure coated onto the surface of a membrane which does not have physical micropores. The non-microporous membrane serves as a mechanical support for the thin multilayered catalyst structure and also can be used to control the rate at which some reactants arrive at (or some products leave from) the multilayered catalyst structure.A multilayered catalyst structure is coated on the non-microporous membrane which is composed of at least a catalyst layer and a separate transport layer.

公开(公告)号：US4801476A

公开(公告)日：1989-01-31

申请号：US93010

申请日：1987-09-03

申请人： John H. Dunsmuir ,  Harry W. Deckman ,  James A. McHenry

发明人： John H. Dunsmuir ,  Harry W. Deckman ,  James A. McHenry

IPC分类号： B05D1/20

CPC分类号： B05D1/20

摘要： A method is described which details the preparation of large area close packed monolayers of colloidal particles from random distributions of colloidal particles by compressing the random network.

公开(公告)号：US4497974A

公开(公告)日：1985-02-05

申请号：US443197

申请日：1982-11-22

申请人： Harry W. Deckman ,  Horst Witzke ,  Christopher Wronski

发明人： Harry W. Deckman ,  Horst Witzke ,  Christopher Wronski

IPC分类号： H01L31/04 ,  H01L31/0216 ,  H01L31/052 ,  H01L31/06

CPC分类号： H01L31/0236 ,  H01L31/02168 ,  H01L31/056 ,  Y02E10/52

摘要： The present invention is an optically enhanced solar cell having a detached reflector. The optically enhanced solar cell includes a semiconductor material bounded on each side by transparent electrical contacts and an optional antireflection coating with the surface of at least one of these layers being textured. Light is reflected in the cell by a reflector which is detached (i.e., spaced) from the enhanced cell using a layer of dielectric material.

摘要翻译： 本发明是具有分离反射器的光学增强型太阳能电池。 光学增强的太阳能电池包括通过透明电触点在每一侧上界定的半导体材料和任选的抗反射涂层，其中至少一层的表面被纹理化。 光通过使用电介质材料层与增强电池分离（即间隔开）的反射器在电池中反射。

公开(公告)号：US4380855A

公开(公告)日：1983-04-26

申请号：US113146

申请日：1980-01-18

申请人： Harry W. Deckman ,  Gerald M. Halpern ,  John G. Dunsmuir

发明人： Harry W. Deckman ,  Gerald M. Halpern ,  John G. Dunsmuir

IPC分类号： H05H1/22 ,  G21C21/00

CPC分类号： G21B1/19 ,  Y02E30/16 ,  Y10T29/49769 ,  Y10T29/49998

摘要： Hollow shell laser fusion targets, such as glass microballoons, are filled with gases of the type which do not permeate through the wall of the balloon. A hole is laser-drilled in the balloon, a plug is placed over the hole and gas is introduced into the balloon through the loosely plugged hole. Thereafter the plug is melted to form a seal over the hole, entrapping the gas within the target. The plug is, for example, a polymer such as highly crystalline polystyrene, or glass.

摘要翻译： 空心壳激光融合目标，例如玻璃微球，填充有不透过气球壁的气体。 在气球中激光钻孔，将塞子放置在孔上方，气体通过松动堵塞的孔被引入气球。 此后，塞子被熔化以在孔上形成密封，将气体截留在靶内。 插塞例如是聚合物，例如高度结晶的聚苯乙烯或玻璃。

公开(公告)号：US4188532A

公开(公告)日：1980-02-12

申请号：US873567

申请日：1978-01-30

申请人： Harry W. Deckman ,  Gerald M. Halpern

发明人： Harry W. Deckman ,  Gerald M. Halpern

IPC分类号： H01J47/06 ,  H05H1/22 ,  G01J1/00

CPC分类号： G21B1/19 ,  H01J47/065 ,  Y02E30/16

摘要： In order to assay the tritium fuel content in laser fusion targets and/or to measure the pressurization of laser fusion targets of the type which use deuterium and tritium (DT) gas mixtures, without destroying the targets, the flux of beta particles which emerges from the target is measured with the aid of a gas flow proportional counter. The count rates are related to the tritium content and the pressurization. The tritium content in terms of the mass of the tritium in the target can be derived from the counting rate.

摘要翻译： 为了测定激光融合靶中的氚燃料含量和/或测量使用氘和氚（DT）气体混合物的类型的激光熔化靶的加压，而不破坏靶，则出现的β粒子的通量 借助气流比例计数器测量目标。 计数率与氚含量和加压有关。 目标中的氚质量的氚含量可以从计数率得出。

公开(公告)号：US09874396B2

公开(公告)日：2018-01-23

申请号：US14516726

申请日：2014-10-17

申请人： Jaime A. Valencia ,  Harry W. Deckman ,  Charles J. Mart ,  James T. Wilkins ,  Paul Scott Northrop

发明人： Jaime A. Valencia ,  Harry W. Deckman ,  Charles J. Mart ,  James T. Wilkins ,  Paul Scott Northrop

IPC分类号： F25J3/00 ,  F25J3/06 ,  C10L3/10 ,  F25J3/02 ,  B01D3/42 ,  C07C7/05 ,  F25J1/00 ,  F25J3/08

CPC分类号： F25J3/067 ,  B01D3/42 ,  C07C7/05 ,  C10L3/102 ,  C10L3/104 ,  C10L3/107 ,  C10L2290/543 ,  C10L2290/545 ,  C10L2290/58 ,  C10L2290/60 ,  F25J1/0022 ,  F25J3/0209 ,  F25J3/0233 ,  F25J3/0266 ,  F25J3/061 ,  F25J3/0635 ,  F25J3/08 ,  F25J2200/02 ,  F25J2200/30 ,  F25J2200/50 ,  F25J2200/74 ,  F25J2205/04 ,  F25J2205/20 ,  F25J2220/66 ,  F25J2235/60 ,  F25J2280/02 ,  F25J2280/40 ,  F25J2290/12 ,  F25J2290/40 ,  Y02C10/12

摘要： The present disclosure provides a method for separating a feed stream in a distillation tower which includes separating a feed stream in a stripper section into an enriched contaminant bottom liquid stream and a freezing zone vapor stream; contacting the freezing zone vapor stream in the controlled freeze zone section with a freezing zone liquid stream at a temperature and pressure at which a solid and a hydrocarbon-enriched vapor stream form; directly applying heat to a controlled freeze zone wall of the controlled freeze zone section with a heating mechanism coupled to at least one of a controlled freeze zone internal surface of the controlled freeze zone wall and a controlled freeze zone external surface of the controlled freeze zone wall; and at least one of destabilizing and preventing adhesion of the solid to the controlled freeze zone wall with the heating mechanism.

公开(公告)号：US09737846B2

公开(公告)日：2017-08-22

申请号：US14963371

申请日：2015-12-09

申请人： Barbara Carstensen ,  Daniel P. Leta ,  Preeti Kamakoti ,  Peter Ravikovitch ,  Joshua Varon ,  Tilman Wolfram Beutel ,  Karl Gottlieb Strohmaier ,  Ivy Dawn Johnson ,  Harry W. Deckman ,  Frank Cheng-Yu Wang ,  Charanjit Singh Paur

发明人： Barbara Carstensen ,  Daniel P. Leta ,  Preeti Kamakoti ,  Peter Ravikovitch ,  Joshua Varon ,  Tilman Wolfram Beutel ,  Karl Gottlieb Strohmaier ,  Ivy Dawn Johnson ,  Harry W. Deckman ,  Frank Cheng-Yu Wang ,  Charanjit Singh Paur

IPC分类号： B01D53/04 ,  B01J20/18 ,  B01D53/047 ,  B01J20/28 ,  B01D53/02 ,  B01J20/32

CPC分类号： B01D53/047 ,  B01D53/02 ,  B01D53/0462 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2253/25 ,  B01D2253/304 ,  B01D2253/34 ,  B01D2256/245 ,  B01D2257/504 ,  B01J20/18 ,  B01J20/183 ,  B01J20/28004 ,  B01J20/28011 ,  B01J20/28016 ,  B01J20/3204 ,  B01J20/3238 ,  B01J20/3293 ,  Y02C10/08

摘要： Adsorbent materials comprising a core, for example CHA, and at least one coating, for example DDR, are provided herein. Adsorbent contactors and gas separation processes using the adsorbent materials are also provided herein.