Process for producing anionic clay using boehmite which has been peptized with an acid
    81.
    发明授权
    Process for producing anionic clay using boehmite which has been peptized with an acid 失效
    使用已经用酸胶溶的勃姆石生产阴离子粘土的方法

    公开(公告)号:US06800578B2

    公开(公告)日:2004-10-05

    申请号:US10271920

    申请日:2002-10-15

    IPC分类号: B01J2116

    摘要: This patent describes economical and environment-friendly processes for the synthesis of anionic clays. It involves reacting a slurry comprising boehmite, which has been peptized with acid with a divalent metal source followed by addition of source of base. The slurry is then hydrothermally aged. There is no necessity to wash or filter the product and it can be spray dried directly to form microspheres, or can be extruded to form shaped bodies. The product can be combined with other ingredients in the manufacture of catalysts, absorbents, pharmaceuticals, cosmetics, detergents, polymeric nanocomposites and other commodity products that contain anionic clays.

    摘要翻译: 该专利描述了用于合成阴离子粘土的经济和环境友好的方法。 其包括将已经与酸缔合的勃姆石与二价金属源反应,然后加入碱源。 然后将该浆液水热老化。 没有必要洗涤或过滤产品,并且可以直接喷雾干燥以形成微球体,或者可以挤出以形成成形体。 该产品可以与催化剂,吸收剂,药物,化妆品,洗涤剂,聚合物纳米复合材料和其它含有阴离子粘土的商品产品的制造中的其他成分组合。

    Composite and process for the in-situ preparation of a composite comprising a cationic clay and binder/matrix material
    82.
    发明授权
    Composite and process for the in-situ preparation of a composite comprising a cationic clay and binder/matrix material 失效
    用于原位制备包含阳离子粘土和粘合剂/基质材料的复合材料的复合材料和方法

    公开(公告)号:US06716785B2

    公开(公告)日:2004-04-06

    申请号:US10259140

    申请日:2002-09-27

    IPC分类号: B01J2906

    摘要: A process for the in-situ preparation of a composite comprising a cationic clay and binder/matrix material from sources comprising an aluminum containing source, a silicon containing source and a di-valent metal containing source comprising the steps of: a. preparing a precursor mixture by mixing the aluminum containing source, the silicon containing source and the di-valent metal containing source with seeding material, b. homogenizing the precursor mixture, and c. aging the precursor mixture to obtain the composite. One or two of the aluminum containing source, silicon containing source or di-valent metal containing source is to be in excess of the amount required for stoichiometry of the three sources with respect to the formation of the cationic clay. The excess source or sources will form the binder/matrix material of the composite. The invention also includes a body comprising a composite obtained by this process having binding/matrix material present in a discontinuous phase.

    摘要翻译: 一种包含阳离子粘土和粘合剂/基体材料的复合材料的方法,所述复合材料包括含铝的源,含硅源和含二价金属的源,所述方法包括以下步骤:a。 b。通过将含铝源,含硅源和含二价金属的源与接种材料混合来制备前体混合物,b。 均化前体混合物,和c。 老化前体混合物以获得复合材料。含铝的源,含硅源或含二价金属的源中的一种或两种应超过三种源的化学计量所需的量,相对于形成 阳离子粘土。 多余的源或来源将形成复合材料的粘合剂/基体材料。 本发明还包括一种主体,其包含通过该方法获得的具有不连续相中存在的结合/基质材料的复合物。

    Process for the preparation of anionic clay and boehmite-containing compositions
    83.
    发明授权
    Process for the preparation of anionic clay and boehmite-containing compositions 失效
    用于制备阴离子粘土和勃姆石组合物的方法

    公开(公告)号:US06710004B2

    公开(公告)日:2004-03-23

    申请号:US10071386

    申请日:2002-02-07

    IPC分类号: B01J2116

    摘要: This invention relates to a process for the preparation of anionic clay and boehmite-containing compositions. These compositions may also contain unreacted trivalent metal source and/or divalent metal source. The process involves subjecting a precursor mixture comprising a divalent metal source and a trivalent metal source to at least two aging steps, wherein at least once between two aging steps an aluminum source is added. An advantage of the invention is that the crystallinity of the boehmite in the composition can be tuned.

    摘要翻译: 本发明涉及一种制备阴离子粘土和勃姆石组合物的方法。 这些组合物还可以含有未反应的三价金属源和/或二价金属源。 该方法包括将包含二价金属源和三价金属源的前体混合物经历至少两个老化步骤,其中在两个老化步骤之间至少一次加入铝源。 本发明的一个优点是可以调节组合物中勃姆石的结晶度。

    Micro-crystalline boehmites containing additives
    84.
    发明授权
    Micro-crystalline boehmites containing additives 失效
    含有添加剂的微晶布氏体

    公开(公告)号:US06555496B1

    公开(公告)日:2003-04-29

    申请号:US09636688

    申请日:2000-08-11

    IPC分类号: B01J2340

    摘要: A microcrystalline boehmite containing additive in a homogeneously dispersed state. Suitable additives are compounds containing elements selected from the group consisting of alkaline earth metals, alkaline metals, rare earth metals, transition metals, actinides, silicon, gallium, boron, titanium, and phosphorus. The microcrystalline boehmite according to the invention may be prepared in several ways. In general, a microcrystalline boehmite precursor and an additive are converted to a microcrystalline boehmite containing the additive in a homogeneously dispersed state. The additive does not contain zirconia or magnesia.

    摘要翻译: 含有均匀分散状态的含微晶勃姆石的添加剂。 合适的添加剂是含有选自碱土金属,碱金属,稀土金属,过渡金属,锕系元素,硅,镓,硼,钛和磷的元素的化合物。 根据本发明的微晶勃姆石可以以几种方式制备。 通常,微晶勃姆石前体和添加剂以均匀分散的状态转化为含有添加剂的微晶勃姆石。 添加剂不含氧化锆或氧化镁。

    Mg-Al anionic clay having 3R2 stacking
    85.
    发明授权
    Mg-Al anionic clay having 3R2 stacking 失效
    具有3R2堆叠的Mg-Al阴离子粘土

    公开(公告)号:US06468488B1

    公开(公告)日:2002-10-22

    申请号:US09636693

    申请日:2000-08-11

    IPC分类号: B01J2104

    摘要: The present invention pertains to Mg—Al anionic clay having 3R2 stacking. This new polytype of anionic clay has a three-layer repeat, but it has a different interlayer arrangement than the conventional 3R1 hydrotalcite. Said new polytype can be applied in all applications described before for the conventional 3R1 polytype anionic clay such as in catalyst compositions, catalyst additive compositions, catalyst supports, absorbent compositions, stabilizer compositions and in medicaments.

    摘要翻译: 本发明涉及具有3R2堆叠的Mg-Al阴离子粘土。 这种新型的阴离子粘土具有三层重复性,但与常规的3R1水滑石具有不同的层间布置。 所述新型多型可用于传统3R1多型阴离子粘土所述的所有应用,如催化剂组合物,催化剂添加剂组合物,催化剂载体,吸收剂组合物,稳定剂组合物和药物中。

    Quasi-crystalline carboxylates
    88.
    发明授权
    Quasi-crystalline carboxylates 失效
    准结晶羧酸盐

    公开(公告)号:US06835364B2

    公开(公告)日:2004-12-28

    申请号:US10066079

    申请日:2002-01-31

    IPC分类号: C01B330

    摘要: The present invention provides new compositions of matter, referred to as quasi-crystalline carboxylates (QCCs), their preparation and use. The materials comprise a quasi-crystalline hydrated magnesium-aluminium hydroxy carboxylate and are characterised by the presence of at least a strong reflection in the powder X-ray diffraction pattern at a basal spacing in the range of 5 to 15 Å. The invention further relates to a process for preparing the QCCs, Mg—Al solid solutions and anionic clays under acidic conditions. The QCC is prepared by aging an acidic mixture of a magnesium carboxylate and an aluminium source. Calcination of the QCC results in a Mg—Al solid solution; rehydration of this solid solution gives an anionic clay.

    摘要翻译: 本发明提供新的物质组合物,称为准结晶羧酸盐(QCC),其制备和用途。 这些材料包含准晶体水合的镁 - 铝羟基羧酸盐,其特征在于在粉末X射线衍射图中存在至少在5至15范围内的基础间距的强反射。 本发明还涉及在酸性条件下制备QCC,Mg-Al固溶体和阴离子粘土的方法。 通过老化羧酸镁和铝源的酸性混合物来制备QCC。 煅烧QCC导致Mg-Al固溶体; 该固溶体的再水化产生阴离子粘土。

    Process for producing anionic clay using non-peptized boemite and compositions produced therefrom
    89.
    发明授权
    Process for producing anionic clay using non-peptized boemite and compositions produced therefrom 有权
    使用非胶溶的波希米特生产阴离子粘土的方法和由其生产的组合物

    公开(公告)号:US06541409B1

    公开(公告)日:2003-04-01

    申请号:US09491263

    申请日:2000-01-26

    IPC分类号: B01J2116

    摘要: An economical and environment-friendly processes for the synthesis of anionic clays and the products made therefrom. It involves reacting a slurry comprising non-peptized boehmite with a magnesium source. There is no necessity to wash or filter the product. It can be spray dried directly to form microspheres or can be extruded to form shaped bodies. The product can be combined with other ingredients in the manufacture of catalysts, absorbents, pharmaceuticals, cosmetics, detergents, and other commodity products that contain anionic clays.

    摘要翻译: 用于合成阴离子粘土和由其制备的产品的经济和环境友好的方法。 它包括使包含非胶溶勃姆石的浆料与镁源反应。 没有必要洗涤或过滤产品。 它可以直接喷雾干燥以形成微球体,或者可以挤出形成成型体。 该产品可以与制造催化剂,吸收剂,药物,化妆品,洗涤剂和其他含有阴离子粘土的商品一起制成其他成分。