公开(公告)号：US5928980A

公开(公告)日：1999-07-27

申请号：US795669

申请日：1997-02-06

Applicant: Santosh Gangwal ,  Kandaswamy Jothimurugesan

Inventor： Santosh Gangwal ,  Kandaswamy Jothimurugesan

IPC: B01J20/02 ,  B01J20/06 ,  B01J20/32 ,  B01J23/22 ,  B01J23/755 ,  B01J23/94 ,  C10G2/00 ,  C10G49/02 ,  C10K1/32 ,  C10K1/34 ,  B01J20/34

CPC classification number: C10G2/33 ,  B01J20/02 ,  B01J20/06 ,  B01J20/16 ,  B01J20/18 ,  B01J20/28057 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  B01J20/3433 ,  B01J20/3458 ,  B01J20/3483 ,  B01J23/22 ,  B01J23/755 ,  B01J23/94 ,  C10G49/02 ,  C10K1/32 ,  C10K1/34 ,  B01J2220/42 ,  Y02P20/584

Abstract: A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption processes, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gasses from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or "passivating" the heavy metals on the spent FCC catalyst as an intermediate step.

Abstract translation: 重金属中毒，废FCC催化剂通过用新的催化金属或金属盐化学浸渍中毒的催化剂来处理，以提供用于不同催化或吸收方法的耐磨催化剂或吸附剂，例如用于费 - 托罗合成的催化剂，和 用于从燃料气体和烟道气中去除硫气的吸附剂。 重金属污染的FCC催化剂直接用作制备具有新吸附剂性能的催化剂的载体和具有新的吸附剂性质的吸附剂，而不用去除或“钝化”废催化剂催化剂上的重金属作为中间步骤。

公开(公告)号：US5695724A

公开(公告)日：1997-12-09

申请号：US557088

申请日：1995-12-05

Applicant: Shiou-Shan Chen ,  Shyh-Yuan Hwang ,  Slawomir A. Oleksy ,  Sanjeev Ram

Inventor： Shiou-Shan Chen ,  Shyh-Yuan Hwang ,  Slawomir A. Oleksy ,  Sanjeev Ram

IPC: B01J20/34 ,  B01J23/04 ,  B01J23/78 ,  B01J23/94 ,  B01J38/04 ,  B01J38/06 ,  B01J38/08 ,  C07B61/00 ,  C07C5/333 ,  C07C5/42 ,  C07C15/44 ,  C07C15/46 ,  B01J8/02

CPC classification number: C07C5/3332 ,  B01J23/04 ,  B01J23/78 ,  B01J23/94 ,  B01J38/04 ,  B01J38/06 ,  B01J38/08 ,  C07C2523/04 ,  C07C2523/745 ,  C07C2523/78 ,  Y02P20/584

Abstract: A method and associated apparatus for regenerating and/or stabilizing catalyst used in dehydrogenation of alkylaromatic hydrocarbons is disclosed. The alkylaromatic hydrocarbon (1) and steam (2) are combined to form feedstream (3) and pass into reactor (50). The ensuing product stream (4) is reheated in heater (52) to restore the heat lost and passed as partially converted reactant stream (5) into second reactor (54) and leaves as stream (6) comprising the dehydrogen product. Restoration and/or stabilization of catalyst is accomplished by an alkali metal compound which is fed into feedstream (2) and/or product stream (5) via supply means (46 and 66), respectively. The amount of alkali metal compound entering the reactor(s) is monitored by means (42 and 62) which may in turn be coupled to activating means (44 and 64) to signal and activate the supply means. This method and apparatus permit the restoration and/or stabilization of the catalyst to be performed without interrupting the dehydrogenation reaction.

Abstract translation: PCT No.PCT / US94 / 07474 Sec。 371 1995年12月5日第 102（e）日期1995年12月5日PCT提交1994年6月30日PCT公布。 第WO95 / 01947号公报 公开了一种用于烷基芳族烃脱氢中用于再生和/或稳定催化剂的方法和相关装置，1995年1月19日。 将烷基芳族烃（1）和蒸汽（2）组合以形成原料流（3）并进入反应器（50）。 随后的产物流（4）在加热器（52）中再加热以恢复热量的损失，并且作为部分转化的反应物流（5）进入第二反应器（54）并作为包含脱氢产物的流（6）离开。 催化剂的还原和/或稳定通过分别经由供给装置（46和66）进料到进料流（2）和/或产物流（5）中的碱金属化合物来实现。 通过装置（42和62）监测进入反应器的碱金属化合物的量，该装置又可耦合到激活装置（44和64）以发出信号并激活供应装置。 该方法和装置允许催化剂的恢复和/或稳定化而不中断脱氢反应。

公开(公告)号：US5686369A

公开(公告)日：1997-11-11

申请号：US467301

申请日：1995-06-06

Applicant: Shiou-Shan Chen ,  Shyh-Yuan Hwang ,  Slawomir A. Oleksy ,  Sanjeev Ram

Inventor： Shiou-Shan Chen ,  Shyh-Yuan Hwang ,  Slawomir A. Oleksy ,  Sanjeev Ram

IPC: B01J20/34 ,  B01J23/04 ,  B01J23/78 ,  B01J23/94 ,  B01J38/04 ,  B01J38/06 ,  B01J38/08 ,  C07B61/00 ,  C07C5/333 ,  C07C5/42 ,  C07C15/44 ,  C07C15/46 ,  B01J38/64

CPC classification number: C07C5/3332 ,  B01J23/04 ,  B01J23/78 ,  B01J23/94 ,  B01J38/04 ,  B01J38/06 ,  B01J38/08 ,  C07C2523/04 ,  C07C2523/745 ,  C07C2523/78 ,  Y02P20/584

Abstract: A method and apparatus are disclosed for regenerating and/or stabilizing the activity of a dehydrogenation catalyst used in dehydrogenating an alkylaromatic hydrocarbon to obtain an alkenylaromatic hydrocarbon, the method comprising the steps of continuously or intermittently adding to a reactant stream an effective amount of an alkali metal compound without interrupting the dehydrogenation reaction.

Abstract translation: 公开了用于再生和/或稳定用于脱氢烷基芳族烃的脱氢催化剂的活性以获得链烯基芳烃的方法和装置，所述方法包括以下步骤：连续或间歇地向反应物流中加入有效量的碱 金属化合物而不中断脱氢反应。

公开(公告)号：US5674796A

公开(公告)日：1997-10-07

申请号：US362845

申请日：1994-12-22

Applicant: Ho-in Lee ,  Sang-heup Moon ,  Gyo-hyun Hwang ,  Byung-youl Coh ,  Seung-hyun Hur ,  Sung-hee Han ,  Heung-sun Park ,  Jong-hae Lee

Inventor： Ho-in Lee ,  Sang-heup Moon ,  Gyo-hyun Hwang ,  Byung-youl Coh ,  Seung-hyun Hur ,  Sung-hee Han ,  Heung-sun Park ,  Jong-hae Lee

IPC: B01J23/94 ,  B01J38/60 ,  B01J20/34 ,  B01J38/02 ,  B01J38/10

CPC classification number: B01J38/60 ,  B01J23/94

Abstract: The present invention relates to processes of regenerating Ni catalysts which had been used in a hydrogenation of unsaturated fatty oil or petroleum resin, which comprise separating the Ni-extracted solution and support by extracting the pretreated Ni catalysts with an acid, preparing support-containing solution by burning the separated support in the flow of air or oxygen diluted with nitrogen at the temperature of 300.degree. to 800.degree. C. for 5 to 15 hours and adding deionized water to the support, preparing a catalyst precursor by dropping the Ni-extracted solution and the mixed solution of a basic compound and a compound with free oxygen in the support-containing solution during agitation so as to keep PH of the solution at 9 to 13, whereby nickel oxide precipitates on the support, carrying out a step consisting of aging, washing, filtering and drying the catalyst precursor, and stabilizing the dried catalyst precursor by reducing with hydrogen and passing in nitrogen diluted with oxygen or an organic material.

Abstract translation: 本发明涉及用于不饱和脂肪油或石油树脂的氢化中的Ni催化剂的再生方法，其包括用酸萃取预处理的Ni催化剂来分离Ni提取溶液和载体，制备含支撑物的溶液 在300〜800℃的温度下，用空气或氧气稀释的空气或氧气中分离的载体燃烧5〜15小时，并向载体中加入去离子水，通过滴加Ni提取液制备催化剂前体 以及在搅拌期间将碱性化合物和游离氧化合物与载体的溶液混合，以使溶液的PH保持在9〜13，由此氧化镍沉淀在载体上，进行由老化 ，洗涤，过滤和干燥催化剂前体，以及通过用氢还原并通过用氧稀释的氮来稳定干燥的催化剂前体 gen或有机材料。

公开(公告)号：US5602280A

公开(公告)日：1997-02-11

申请号：US266190

申请日：1994-06-27

Applicant: Koichi Nagai ,  Yoshisaburou Nomura ,  Yoshihiko Nagaoka

Inventor： Koichi Nagai ,  Yoshisaburou Nomura ,  Yoshihiko Nagaoka

IPC: B01J23/887 ,  C07C45/35 ,  C07C45/37 ,  C07C51/23 ,  C07C51/25 ,  C07C51/16

CPC classification number: C07C51/23 ,  B01J23/002 ,  B01J23/8876 ,  B01J23/94 ,  B01J27/192 ,  B01J27/285 ,  B01J35/0006 ,  B01J37/04 ,  B01J38/00 ,  C07C45/35 ,  C07C45/37 ,  C07C51/252 ,  B01J2523/00 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/08 ,  B01J38/485 ,  Y02P20/584

Abstract: Disclosed are a process for producing an unsaturated aldehyde and an unsaturated carboxylic acid which comprises subjecting propylene, isobutylene or tertiary butanol to gas phase catalytic oxidation with molecular oxygen in the presence of (i) a catalyst comprising composite oxide of the formula Mo.sub.a Bi.sub.b Fe.sub.c A.sub.d B.sub.e C.sub.f D.sub.g O.sub.x and (ii) a molybdenum oxide which in itself is substantially inert to the gas phase catalytic oxidation; a process for reusing the catalyst deteriorated due to the gas phase catalytic oxidation after mixing it with the molybdenum oxide; and a method of regenerating the deteriorated catalyst by mixing it with the molybdenum oxide.

Abstract translation: 公开了一种制备不饱和醛和不饱和羧酸的方法，其包括在（i）包含式MoaBibFecAdBeCfDgOx的复合氧化物和（ii）的催化剂的存在下，用分子氧对丙烯，异丁烯或叔丁醇进行气相催化氧化 ）本身对气相催化氧化基本上是惰性的氧化钼; 在与氧化钼混合之后，由于气相催化氧化而使催化剂重复使用的方法劣化; 以及通过将其与氧化钼混合来再生劣化的催化剂的方法。

公开(公告)号：US5559066A

公开(公告)日：1996-09-24

申请号：US381916

申请日：1995-02-13

Applicant: Wolfgang J. Poepel ,  Gregor Tremmel ,  Wolfgang Buechele ,  Axel Deimling ,  Hermann Petersen

Inventor： Wolfgang J. Poepel ,  Gregor Tremmel ,  Wolfgang Buechele ,  Axel Deimling ,  Hermann Petersen

IPC: B01J23/78 ,  B01J23/85 ,  B01J23/94 ,  B01J37/00 ,  B01J38/00 ,  B01J38/68 ,  C07C5/32

CPC classification number: B01J23/94 ,  B01J37/0036 ,  B01J38/68 ,  C07C5/321 ,  Y02P20/584

Abstract: A process for the preparation of iron-, potassium- and cerium-containing catalysts for the dehydrogenation of hydrocarbons from the same spent catalysts (regeneration) by grinding and, if necessary, purifying the spent material, restoring the original activity by adjusting the composition and restoring the external shape comprises adding to the ground material an effective amount of potassium and such an amount of cerium that the total amount of cerium is greater than the amount originally present.

Abstract translation: PCT No.PCT / EP93 / 03083第 371日期1995年2月13日 102（e）日期1995年2月13日PCT 1993年11月5日PCT公布。 出版物WO94 / 11104 日期1994年5月26日制备用于通过研磨从相同的废催化剂（再生）中脱氢烃类的含铁，钾和铈的催化剂的方法，如有必要，纯化废料，通过 调整组成并恢复外部形状包括向研磨材料中加入有效量的钾和这样一定量的铈，使铈的总量大于原来存在的量。

公开(公告)号：US5512525A

公开(公告)日：1996-04-30

申请号：US189734

申请日：1994-02-01

Applicant: Andreas Tenten ,  Ulrich Hammon ,  Peter Weidlich ,  Walter Doerflinger

Inventor： Andreas Tenten ,  Ulrich Hammon ,  Peter Weidlich ,  Walter Doerflinger

IPC: B01J23/85 ,  B01J23/94 ,  B01J38/48 ,  B01J38/52 ,  B01J38/62 ,  C07C57/055 ,  B01J20/34

CPC classification number: B01J38/52 ,  B01J23/94 ,  B01J38/62

Abstract: A process for regenerating spent multimetal oxide oxidation catalysts from the catalytic gas-phase oxidation of lower organic compounds and which, in fresh form, contain as basic constituents the elements Mo, W, V and Cu in oxidic form, by the action of oxidizing agents or means and solubilizing, aqueous ammonia to which acetic acid and/or the ammonium salt thereof has been added, with subsequent drying and calcination, comprises quantitatively determining the content of metallic constituents during the process and making this content up to the respective original value.

Abstract translation: 一种从低级有机化合物的催化气相氧化中再生废多元氧化物氧化催化剂的方法，其以新鲜形式含有氧化剂中的Mo，W，V和Cu元素作为基本成分的元素Mo，W，V和Cu， 或手段和溶解其中加入了乙酸和/或其铵盐的氨水，随后进行干燥和煅烧，包括在该过程中定量测定金属成分的含量并使其含量达到相应的原始值。

公开(公告)号：US5283216A

公开(公告)日：1994-02-01

申请号：US949934

申请日：1992-09-24

Applicant: Willard N. Mitchell

Inventor： Willard N. Mitchell

IPC: B01J23/94 ,  B01J38/10 ,  B01J38/48 ,  B01J38/58 ,  C07C1/04 ,  C10G2/00 ,  B01J20/20 ,  C07C27/00

CPC classification number: C10G2/331 ,  B01J23/94 ,  B01J38/10 ,  B01J38/48 ,  B01J38/58 ,  C07C1/045 ,  C07C2521/06 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C10G2300/703 ,  Y02P20/584

Abstract: A cobalt- or ruthenium-containing hydrocarbon synthesis catalyst, subjected to short term, reversible, partial deactivation in a slurry synthesis process can be rejuvenated, i.e., at least about 80+% catalyst activity recovery, by treating the catalyst in the presence of liquid hydrocarbons, preferably the slurry hydrocarbons, with hydrogen at elevated temperatures and pressures.

Abstract translation: 通过在液体存在下处理催化剂，在浆料合成过程中经受短期，可逆，部分失活的含钴或钌的烃合成催化剂可以复原，即至少约80 +％的催化剂活性回收率 烃，优选浆料烃，在升高的温度和压力下与氢气接触。

公开(公告)号：US5260239A

公开(公告)日：1993-11-09

申请号：US992981

申请日：1992-12-18

Applicant: Stephen J. Hsia

Inventor： Stephen J. Hsia

IPC: B01J8/22 ,  B01J23/90 ,  B01J23/94 ,  B01J38/10 ,  B01J38/50 ,  B01J38/56 ,  C10G2/00 ,  B01J38/58 ,  C07C27/00

CPC classification number: C10G2/342 ,  B01J23/90 ,  B01J23/94 ,  B01J38/10 ,  B01J38/50 ,  B01J38/56 ,  B01J8/228

Abstract: Catalyst which has become deactivated during a hydrocarbon synthesis (HCS) process is reactivated - rejuvenated using an external reactivation - rejuvenation vessel resulting in a multiple HCS reaction - catalyst rejuvenation reactor vessel design. Flow of the catalyst is synthesis product slurry from the reactor vessel to the rejuvenation vessel and the flow of rejuvenated catalyst back to the reactor vessel are driven by gravity only.

Abstract translation: 在烃合成（HCS）方法中已失活的催化剂被再活化 - 使用外部再活化 - 再生容器进行再生，导致多个HCS反应 - 催化剂复原反应器容器设计。 催化剂的流动是从反应器容器到再生容器的合成产物浆料，并且再生催化剂回到反应器容器的流动仅由重力驱动。

公开(公告)号：US5254513A

公开(公告)日：1993-10-19

申请号：US702480

申请日：1991-05-20

Applicant: David E. Sherwood, Jr. ,  Johnnie R. Hardee, Jr.

Inventor： David E. Sherwood, Jr. ,  Johnnie R. Hardee, Jr.

IPC: B01J23/94 ,  B01J38/06 ,  B01J38/50 ,  C10G45/08 ,  B01J20/34

CPC classification number: C10G45/08 ,  B01J23/94 ,  B01J38/06 ,  B01J38/50 ,  Y10S502/514 ,  Y10S502/516

Abstract: Spent or inactive alumina-supported catalysts removed from a catalytic hydrotreating process and having carbonaceous and metallic deposits thereon are reactivated. After a solvent wash to remove process oils, the spent catalyst is contacted with steam at a temperature of 1000.degree. to about 1250.degree. F. for a period of about 2 to about 5 hours to form a reactivated catalyst suitable for reuse in a catalytic hydrotreating process. Optionally, the steam-treated catalyst can be regenerated by contact with an oxygen-containing gas at a temperature of about 700.degree. to about 900.degree. F. to remove carbon deposits from the catalyst, or, alternatively, the steam-treated catalyst can be acid-leached to remove undesired metals and then contacted with an oxygen-containing gas at an elevated temperature to remove carbon deposits.

Abstract translation: 从催化加氢处理过程中除去并在其上具有碳质和金属沉积物的废活性氧化铝负载催化剂被再活化。 经过溶剂洗涤以除去加工油后，废催化剂在1000至1250°F的温度下与蒸汽接触约2至约5小时，形成适于在催化加氢处理中再利用的再活化催化剂 处理。 任选地，蒸汽处理的催化剂可以通过在约700°至约900°F的温度下与含氧气体接触来再生，以从催化剂中除去碳沉积物，或者，蒸汽处理的催化剂可以是 酸浸以除去不想要的金属，然后在升高的温度下与含氧气体接触以除去碳沉积物。