Oxidization of an oxidizable charge in the gaseous phase and a reactor
for implementing this method
    82.
    发明授权
    Oxidization of an oxidizable charge in the gaseous phase and a reactor for implementing this method 失效
    气相中可氧化电荷的氧化和用于实施该方法的反应器

    公开(公告)号:US5037619A

    公开(公告)日:1991-08-06

    申请号:US507507

    申请日:1990-04-11

    Abstract: An oxidizable charge is oxidized in a gaseous phase reaction. The oxidizable charge and an oxidizing gas flow simultaneously and separately through a distribution zone made of a ceramic material. In at least a part of the distribution zone, the oxidizable charge and the oxidizing gas flow through a multiplicity of passages of a dimension so small that any flame resulting from oxidation of the oxidizable charge will be quenched. The oxidizable charge and oxidizing gas are then mixed in a mixing zone made from a ceramic material defining a multiplicity of spaces with passages having a dimension comparable to the dimension of the passages in the distribution zone. The mixture of gases then flows through a reaction zone made from a ceramic material defining another multiplicity of passages having dimensions comparable to those in the distribution zone. The distance between each of the distribution, mixing and reaction zones is also so small that any flame resulting from oxidation of the oxidizable charge will be quenched.

    Abstract translation: 可氧化的电荷在气相反应中被氧化。 可氧化的电荷和氧化性气体流动同时且分开地通过由陶瓷材料制成的分布区域。 在分配区域的至少一部分中,可氧化电荷和氧化气体流过多个尺寸小的通道,使得由可氧化电荷的氧化产生的任何火焰都将被淬灭。 然后将可氧化的电荷和氧化气体在由限定多个空间的陶瓷材料制成的混合区中混合,通道具有与分配区中的通道的尺寸相当的尺寸。 气体混合物然后流过由陶瓷材料制成的反应区,该反应区限定了与分配区相当的尺寸的多个通道。 分配,混合和反应区域之间的距离也很小,使得可氧化的电荷的氧化产生的任何火焰都将被淬火。

    Process involving oxidation reactor used oxidize a gaseous phase
oxidizable feed
    83.
    发明授权
    Process involving oxidation reactor used oxidize a gaseous phase oxidizable feed 失效
    使用氧化反应器的方法氧化气相可氧化的进料

    公开(公告)号:US4971770A

    公开(公告)日:1990-11-20

    申请号:US264393

    申请日:1988-10-31

    Abstract: A new technique for oxidizing a gaseous phase oxidizable feed involves a process wherein a gas mixture containing at least one oxidizing gas is placed in contact with an oxidizable feed inside a mixing contact zone situated between at least one first zone passed through by the feed and at least one second zone passed through by the oxidation reaction products. The first and second zones define a multiplicity of multidirectional spaces exhibiting passages having, along at least one direction, a dimension at most equal to the jamming distance of the flame possibly resulting from oxidations of feed. The contact zone comprises an oxidizing gas mixture supply means comprising a plurality of parallel pipes with porous walls situated at a distance from the first and second zones which is at most equal to the jamming distance.

    Abstract translation: 用于氧化气相可氧化进料的新技术涉及一种方法,其中将含有至少一种氧化气体的气体混合物置于与位于至少由进料通过的至少一个第一区域之间的混合接触区域内, 至少一个第二区域被氧化反应产物穿过。 第一和第二区域限定多个多向空间,其显示通道,沿着至少一个方向具有最大等于可能由进料氧化引起的火焰的干扰距离的尺寸。 所述接触区包括氧化气体混合物供应装置,所述氧化气体混合物供应装置包括多个平行的管道,所述多个平行管道具有位于距离所述第一和第二区域一定距离的多孔壁,所述第一和第二

    Mobile atom insertion reaction, mobile atom transmissive membrane for
carrying out the reaction, and reactor incorporating the mobile atom
transmissive membrane
    84.
    发明授权
    Mobile atom insertion reaction, mobile atom transmissive membrane for carrying out the reaction, and reactor incorporating the mobile atom transmissive membrane 失效
    移动原子插入反应,用于进行反应的移动原子透射膜,以及并入移动原子透射膜的反应器

    公开(公告)号:US4908114A

    公开(公告)日:1990-03-13

    申请号:US117298

    申请日:1987-11-06

    Applicant: William Ayers

    Inventor: William Ayers

    Abstract: Disclosed is a method of carrying out a mobile atom insertion reaction, such as a hydrogen insertion reaction, for the synthesis of reduced, hydrogenated compounds. Such reactions include the production of ammonia and hydrazine from nitrogen, formic acid and methanol from carbon dioxide, and hydrogen peroxide from oxygen. The insertion reactions are carried out at a bipolar mobile atom transmissive membrane comprising a membrane formed of a mobile atom pump material, as a hydrogen pump material, conductive atom transmissive means on one surface of the membrane and conductive atom transmissive means on the opposite surface of the membrane. The mobile atom, such as hydrogen, diffuses across the membrane, to provide a source of hydrogen on the insertion reaction side of the membrane. The insertion reaction side of the membrane is positively biased with respect to a counterelectrode so that a reactant molecule, such as carbon dioxide, is electrosorbed on that surface of the membrane. The electrosorbed reactant molecular chemically reacts with the surface hydrogen by the insertion reaction to form a reduced, hydrogenated product such as formic acid. Also disclosed is a chemical reactor, containing the membrane, and several electrical field assisted chemical reactions utilizing the membrane and reactor.

    Abstract translation: 公开了用于合成还原的氢化化合物的进行诸如氢插入反应的可移动的原子插入反应的方法。 这样的反应包括从氮气中生成氨和肼,从二氧化碳生成甲酸和甲醇,以及从氧气生产过氧化氢。 插入反应在双极移动原子透射膜上进行,该双极移动原子透射膜包括由移动原子泵材料形成的膜,作为氢泵材料,在膜的一个表面上的导电原子透射装置和在膜的相对表面上的导电原子透射装置 膜。 诸如氢的移动原子扩散到膜上,以在膜的插入反应侧提供氢源。 膜的插入反应侧相对于反电极被正偏置,使得诸如二氧化碳的反应物分子在膜的表面上被电泳。 电泳反应物分子通过插入反应与表面氢化学反应形成还原的氢化产物如甲酸。 还公开了含有膜的化学反应器和利用膜和反应器的几个电场辅助化学反应。

    Acoustic acceleration of fluid mixing in porous materials
    89.
    发明授权
    Acoustic acceleration of fluid mixing in porous materials 有权
    多孔材料流体混合声学加速度

    公开(公告)号:US08789999B2

    公开(公告)日:2014-07-29

    申请号:US13832151

    申请日:2013-03-15

    Abstract: Apparatus and methods are disclosed for uniformly mixing fluid phases entrained in a porous material. A mixer may have a vessel and at least one porous material held by the vessel. At least one actuator may be acoustically coupled with at least one wall of the vessel for generating a wave. The wave effects mixing of at least two fluids in the porous material. The actuator may be a linear motor actuated with a control signal of predetermined frequency. The actuator may have a number of actuator pairs each including respective first and second actuators at respective first and second sides of the vessel. The actuators may be hinged for reciprocal movement. The actuators may be actuated to form a compression expansion wave to effect fluid motion in the porous material.

    Abstract translation: 公开了用于均匀混合夹带在多孔材料中的流体相的装置和方法。 混合器可以具有容器和由容器保持的至少一个多孔材料。 至少一个致动器可以与容器的至少一个壁声学耦合以产生波。 波浪影响多孔材料中至少两种流体的混合。 致动器可以是用预定频率的控制信号致动的线性电动机。 致动器可以具有多个致动器对,每个致动器对在容器的相应的第一和第二侧分别包括相应的第一和第二致动器。 致动器可以铰接用于往复运动。 致动器可以被致动以形成压缩膨胀波,以在多孔材料中实现流体运动。

    Hydrogen transport membranes for dehydrogenation reactions
    90.
    发明申请
    Hydrogen transport membranes for dehydrogenation reactions 有权
    用于脱氢反应的氢传输膜

    公开(公告)号:US20100290961A1

    公开(公告)日:2010-11-18

    申请号:US12009969

    申请日:2008-01-23

    Abstract: A method of converting C2 and/or higher alkanes to olefins by contacting a feedstock containing C2 and/or higher alkanes with a first surface of a metal composite membrane of a sintered homogenous mixture of an Al oxide or stabilized or partially stabilized Zr oxide ceramic powder and a metal powder of one or more of Pd, Nb, V, Zr, Ta and/or alloys or mixtures thereof. The alkanes dehydrogenate to olefins by contact with the first surface with substantially only atomic hydrogen from the dehydrogenation of the alkanes passing through the metal composite membrane. Apparatus for effecting the conversion and separation is also disclosed.

    Abstract translation: 将C2和/或高级烷烃转化为烯烃的方法是将含有C2和/或高级烷烃的原料与Al氧化物或稳定或部分稳定的Zr氧化物陶瓷粉末的烧结同质混合物的金属复合膜的第一表面接触 以及Pd,Nb,V,Zr,Ta和/或其合金或其混合物中的一种或多种的金属粉末。 烷烃通过与通过金属复合膜的烷烃的脱氢基本上仅与原子氢接触而与第一表面接触而脱氢成烯烃。 还公开了用于实现转换和分离的装置。

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