公开(公告)号：US4929781A

公开(公告)日：1990-05-29

申请号：US277743

申请日：1988-11-30

申请人： Robert B. James, Jr. ,  Tom N. Kalnes

发明人： Robert B. James, Jr. ,  Tom N. Kalnes

IPC分类号： A62D3/00 ,  A62D3/37 ,  A62D101/22 ,  C10G65/04

CPC分类号： A62D3/37 ,  C10G65/04 ,  A62D2101/22 ,  A62D2203/02 ,  A62D2203/10

摘要： A process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds which process comprises: (a) contacting the first feedstock comprising unsaturated, halogenated organic compounds with hydrogen in a first hydrogenation reaction zone operated at hydrogenation conditions selected to minimize the polymerization of unsaturated organic compounds and to produce a first hydrogenated hydrocarbonaceous stream; (b) contacting at least a portion of the first hydrogenated hydrocarbonaceous stream and the second feedstock comprising saturated, halogenated organic compounds with hydrogen in a second hydrogenation reaction zone operated at hydrogenation conditions selected to produce a second hydrogenated hydrocarbonaceous stream and to generate at least one water-soluble hydrogen halide compound; (c) contacting the resulting effluent from the second hydrogenation zone containing hydrogenated hydrocarbonaceous compounds, a hydrogen-rich gas and at least one water-soluble hydrogen halide compound with a halide-lean absorber solution in an absorption zone; (d) withdrawing a halide-rich absorber solution containing at least a portion of the water-soluble hydrogen halide compound from the absorption zone; (e) withdrawing a stream comprising hydrogenated hydrocarbonaceous compounds and a hydrogen-rich gas from the absorption zone; and (f) introducing the stream recovered in step (e) into a separation zone to provide a hydrogen-rich gaseous stream and a third hydrogenated hydrocarbonaceous stream.

摘要翻译： 用于同时加氢转化包含不饱和卤代有机化合物的第一原料和包含饱和卤代有机化合物的第二原料的方法，该方法包括：（a）在第一氢化反应中使包含不饱和卤代有机化合物的第一原料与氢接触 在选择的氢化条件下操作的区域使不饱和有机化合物的聚合最小化并产生第一氢化烃流; （b）在被选择产生第二氢化烃物流的氢化条件下操作的第二加氢反应区中使至少一部分第一氢化烃物流和包含饱和卤代有机化合物的第二原料与氢接触，并产生至少一种 水溶性卤化氢化合物; （c）使来自含有氢化烃类化合物的第二氢化区，富氢气体和至少一种水溶性卤化氢化合物的所得流出物与吸收区中的贫卤素吸收剂溶液接触; （d）从吸收区取出含有至少一部分水溶性卤化氢化合物的富卤化物吸收剂溶液; （e）从吸收区取出包含氢化烃类化合物和富氢气体的物流; 和（f）将步骤（e）中回收的物流引入分离区，以提供富氢气流和第三氢化烃流。

公开(公告)号：US4927520A

公开(公告)日：1990-05-22

申请号：US265969

申请日：1988-11-02

申请人： Tom N. Kalnes ,  Robert B. James, Jr. ,  Darrell W. Staggs

发明人： Tom N. Kalnes ,  Robert B. James, Jr. ,  Darrell W. Staggs

IPC分类号： A62D3/00 ,  A62D3/40 ,  A62D101/22 ,  A62D101/24 ,  A62D101/43 ,  C10G69/00 ,  C10G69/06 ,  C10G69/14

CPC分类号： A62D3/40 ,  C10G69/00 ,  C10G69/06 ,  C10G69/14 ,  A62D2101/22 ,  A62D2101/24 ,  A62D2101/43 ,  A62D2203/10

摘要： A process for treating a hydrocarbonaceous stream containing a non-distillable component to produce a hydrogenated distillable hydrocarbonaceous product while minimizing thermal degradation of the hydrocarbonaceous stream which process comprises the steps of: (a) contacting the hydrocarbonaceous stream with a hot first hydrogen-rich gaseous stream having a temperture greater than the hydrocarbonaceous stream in a flash zone at flash conditions thereby increasing the temperature of the hydrocarbonaceous stream without indirect heat exchange and vaporizing at least a portion thereof to provide a hydrocarbonaceous vapor stream comprising hydrogen and a heavy stream comprising the non-distillable component; (b) contacting the hydrocarbonaceous vapor stream comprising hydrogen with a hydrogenation catalyst in a hydrogenation reaction zone at hydrogenation conditions to increase the hydrogen content of the hydrocarbonaceous compounds contained in the hydrocarbonaceous vapor stream; (c) condensing at least a portion of the resulting effluent from the hydrogenation reaction zone to provide a second hydrogen-rich gaseous stream and a liquid stream comprising hydrogenated distillable hydrocarbonaceous compounds; (d) recovering a hydrogenated distillable hydrocarbonaceous product from the liquid stream comprising hydrogenated distillable hydrocarbonaceous compounds; and (e) reacting at least a portion of the heavy stream comprising the non-distillable component recovered from step (a) in a thermal coking zone at thermal coking conditions to provide a thermal coking zone effluent.

摘要翻译： 一种用于处理含有不可蒸馏组分的烃物流以产生氢化的可蒸馏烃产物同时最小化烃流的热降解的方法，该方法包括以下步骤：（a）使烃流与热的第一富氢气体 流在闪蒸条件下在闪蒸区中具有大于烃流的温度，从而提高烃流的温度，而不间接热交换并蒸发其至少一部分，以提供包含氢的含烃蒸气流和包含非烃的重质流， 可分离组分; （b）在加氢条件下，在加氢反应区中使包含氢气的烃类蒸气物流与氢化催化剂接触，以增加烃类蒸气流中所含烃类化合物的氢含量; （c）将来自氢化反应区的所得流出物的至少一部分冷凝以提供第二富氢气流和包含氢化的可蒸馏烃类化合物的液体流; （d）从包含氢化的可馏分烃类化合物的液体物流中回收氢化的可蒸馏烃类产物; 和（e）使包含从步骤（a）回收的不可蒸馏组分的至少一部分重质流在热焦化条件下在热焦化区中反应，以提供热焦化区流出物。

公开(公告)号：US4902842A

公开(公告)日：1990-02-20

申请号：US309508

申请日：1989-02-13

申请人： Tom N. Kalnes ,  Robert B. James, Jr.

发明人： Tom N. Kalnes ,  Robert B. James, Jr.

IPC分类号： A62D3/00 ,  A62D3/37 ,  A62D101/22 ,  B01J23/44 ,  C07B61/00 ,  C07C1/26 ,  C07C5/03 ,  C07C9/00 ,  C07C9/08 ,  C07C17/00 ,  C10G1/00

CPC分类号： A62D3/37 ,  C07C1/26 ,  A62D2101/22 ,  A62D2203/02 ,  A62D2203/10 ,  C07C2521/04 ,  C07C2523/44

摘要： A process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds which process comprises: (a) contacting the first feedstock comprising unsaturated, halogenated organic compounds with a first dried hydrogen-rich gas stream in a first hydrogenation reaction zone operated at hydrogenation conditions selected to minimize the polymerization of unsaturated organic compounds and to produce a first hydrogenated stream comprising hydrocarbonaceous compounds; (b) reacting at least a portion of the first hydrogenated stream comprising hydrocarbonaceous compounds and the second feedstock comprising saturated, halogenated organic compounds with hydrogen in a second hydrogenation reaction zone operated at hydrogenation conditions selected to produce a second hydrogenated stream comprising hydrocarbonaceous compounds and to generate at least one water-soluble hydrogen halide compound; (c) contacting the the second hydrogenated stream with a halide-lean absorber solution in an absorption zone; (d) withdrawing a halide-rich absorber solution containing at least a portion of the water-soluble hydrogen halide compound from the absorption zone; (e) withdrawing a stream comprising hydrogenated hydrocarbonaceous compounds and a hydrogen-rich gas from the absorption zone; (f) introducing the stream recovered in step (e) into a separation zone to produce a hydrogen-rich gas stream comprising water vapor and a third hydrogenated stream comprising hydrocarbonaceous compounds; (g) removing at least a portion of the water vapor from the hydrogen-rich gas stream comprising water vapor in a drying zone to produce a second dried hydrogen-rich gas stream; and (h) recycling at least a portion of the second dried hydrogen-rich gas stream to step (a) as the first dried hydrogen-rich gas stream.

公开(公告)号：US4839042A

公开(公告)日：1989-06-13

申请号：US916533

申请日：1986-10-08

申请人： Wander Tumiatti ,  Gilberto Nobile ,  Pietro Tundo

发明人： Wander Tumiatti ,  Gilberto Nobile ,  Pietro Tundo

IPC分类号： C10G29/22 ,  A62D3/34 ,  A62D101/22 ,  B01D15/00 ,  C10M175/00 ,  C10N40/16 ,  H01B3/24

CPC分类号： A62D3/34 ,  B01D15/00 ,  A62D2101/22 ,  A62D2203/10 ,  Y10S210/909

摘要： An immobilized reagent for the decontamination of fluids is described, consisting of a solid, carrier on which there are absorbed (a) polyethylene glycols, (b) alkali or alkaline-earth metal alcoholates.

摘要翻译： 描述了用于净化流体的固定化试剂，其由吸收了（a）聚乙二醇的固体载体，（b）碱金属或碱土金属醇化物组成。

公开(公告)号：US4804779A

公开(公告)日：1989-02-14

申请号：US794928

申请日：1985-11-04

申请人： Thomas Novinson

发明人： Thomas Novinson

IPC分类号： A62D3/00 ,  A62D3/34 ,  A62D3/37 ,  A62D3/38 ,  A62D101/22 ,  B09C1/08 ,  C02F1/70 ,  C02F1/72 ,  C07C51/31 ,  C07C51/16

CPC分类号： A62D3/38 ,  A62D3/37 ,  B09C1/08 ,  C02F1/70 ,  C02F1/722 ,  C07C51/31 ,  C07C51/316 ,  A62D2101/22 ,  A62D2203/02

摘要： The invention provides a two-step process where polychlorinated biphenyls CBs), i.e. biphenyl having 2 to 10 chlorine atoms, are first reduced to unsubstituted biphenyl, then oxidized to a biodegradable dicarboxylic acid having the formula: (CH.sub.2).sub.n (CO.sub.2 H).sub.2, where n=0 to 10 possible --CH.sub.2 --units for application in aqueous systems including water, mud and wet soil.

摘要翻译： 本发明提供了两步法，其中首先将具有2-10个氯原子的联苯的多氯联苯（PCB）还原成未取代的联苯，然后氧化成具有下式的可生物降解的二羧酸：（CH 2）n（CO 2 H）2 ，其中n = 0至10个可能的-CH 2单元用于包括水，泥土和湿土在含水体系中的应用。

公开(公告)号：US4804479A

公开(公告)日：1989-02-14

申请号：US171995

申请日：1988-03-23

申请人： Wolfgang W. Schneider ,  William A. Wagner

发明人： Wolfgang W. Schneider ,  William A. Wagner

IPC分类号： A62D3/00 ,  A62D3/34 ,  A62D3/38 ,  A62D101/22 ,  B09B3/00 ,  C07C17/02 ,  C02F1/74

CPC分类号： C07C17/02 ,  Y10S210/912

摘要： Under certain operating conditions, an emulsion of an acidified unfiltrable tarry bottoms stream from a reactor for the chlorination of ethylene to 1,2-dichloroethane can be demulsified and separated in a phase separation tank. The presence of FeCl.sub.3 in an amount more than 5 ppm Fe in the separated organic waste, fouls the reboiler and lower internals of a "heavies" column in which the separated organic waste is concentrated, and deactivates the catalyst in a Catoxid fluid bed reactor in which the concentrate is burned. By maintaining an iron salt chlorination catalyst in a concentration which results in 2000 ppm to 4000 ppm of Fe in the HTC reactor bottoms, and operating the HTC reactor at a temperature in the range from about 90.degree. C. to 120.degree. C. and a pressure in the range from 9 psig to 12 psig, an unfiltrable reactor bottoms drawoff is produced which may be acidified without forming an emulsion. Formation of an emulsion is avoided by mixing each volume of the HTC bottoms drawoff with at least 50 volumes of dilute aqueous HCl in a concentration range from 2 to 4% so as to demulsify the emulsion into aqueous acid and organic phases. The mixture is gravity-separated in a phase separation tank by decantation. The lower layer (60-70% by wt EDC, the remainder being heavies) is concentrated by recovering EDC overhead and producing a bottoms concentrate in which the Fe is present in no more than 50 ppm. The concentrate may be economically disposed of in a Catoxid reactor using a support-free gamma alumina catalyst found to be highly sensitive to iron.

公开(公告)号：US4781826A

公开(公告)日：1988-11-01

申请号：US128314

申请日：1987-12-03

申请人： Ashok K. Mendiratta ,  Wayne F. Morgan ,  Craig W. Horneck ,  Nie-Jiann Wen

发明人： Ashok K. Mendiratta ,  Wayne F. Morgan ,  Craig W. Horneck ,  Nie-Jiann Wen

IPC分类号： H01F41/00 ,  A62D3/00 ,  A62D3/34 ,  A62D101/22 ,  B01D21/30 ,  B01J19/00

CPC分类号： A62D3/34 ,  A62D2101/22 ,  A62D2203/10 ,  Y10S210/909

摘要： A mobile apparatus for chemically decontaminating PCB-contaminated dielectric fluids utilizes three reactors through which the contaminated fluid is processed on a repetitive, sequential batch basis automated by a programmable controller. The processing of each reactor batch includes a charging cycle during which a reactor is filled with contaminated fluid, a reaction cycle during which the PCBs are destroyed by reaction with reagents introduced into a reactor, and a discharging cycle during which the reactor is emptied of decontaminated fluid and reaction by-products into a decanting tank for ultimate separation. The controller coordinates the sequential batch processing through the three reactors in 120.degree. time phased relation such that a charging cycle of one reactor batch, a reaction cycle of a second reactor batch and a discharging cycle of the third reactor batch are all coincident in time during normal operation.

公开(公告)号：US4685220A

公开(公告)日：1987-08-11

申请号：US528910

申请日：1983-09-02

申请人： William C. Meenan ,  George D. Sullivan

发明人： William C. Meenan ,  George D. Sullivan

IPC分类号： A62D3/00 ,  A62D3/38 ,  A62D101/22 ,  A62D101/28 ,  B09C1/06 ,  C02F11/00 ,  C02F11/12 ,  F26B3/08

CPC分类号： C02F11/12 ,  B09C1/06 ,  C02F11/004

摘要： A process and apparatus for treating any fluidizable solid material having a dioxin contaminant absorbed or adsorbed thereon. The method and apparatus includes heating the fluidizable solids, using hot turbulent gas at a temperature in the range of 850.degree. to 2,500.degree. F. to vaporize and thereby separate the dioxin from the fluidizable solids and to fluidize at least a portion of the solids. The dioxin are then further treated to dispose of the dioxins, such as by condensing the liquid and filtering or decanting them from the condensed water.

摘要翻译： 一种用于处理吸收或吸附二恶英污染物的任何可流化固体材料的方法和装置。 该方法和设备包括使用在850-2500°F范围内的温度下的热湍流气体加热可流化的固体，从而使二恶英与可流化固体分离并使至少一部分固体流体化。 然后将二恶英进一步处理以处理二恶英，例如通过冷凝液体并从冷凝水中过滤或倾析它们。

公开(公告)号：US4675464A

公开(公告)日：1987-06-23

申请号：US883785

申请日：1986-07-09

申请人： Charles J. Rogers ,  Alfred Kornel

发明人： Charles J. Rogers ,  Alfred Kornel

IPC分类号： A62D3/34 ,  A62D3/00 ,  A62D101/22 ,  C07C1/26 ,  C07C2/02

CPC分类号： A62D3/34 ,  C07C1/26 ,  A62D2101/22

摘要： Method for the total dehydrohalogenation of halogenated compounds. The method includes providing a reaction mixture by dissolving an alkali metal hydroxide in a molar excess of an ethylene glycol to form an alkali metal glycolate and reacting the halogenated organic compound with the alkali metal glycolate. In halogenated compounds having one carbon, carbon dioxide is the reaction product. In those having more than one carbon, acetylene is formed. The preferred ethylene glycol is tetraethylene glycol and the preferred alkali metal is potassium hydroxide. The method is particularly useful for disposing of toxic halogenated compounds which make up soil contaminants, like ethylene dibromide.

摘要翻译： 卤代化合物总脱卤化氢的方法。 该方法包括通过将摩尔过量的乙二醇溶解碱金属氢氧化物形成碱金属乙醇酸盐并使卤代有机化合物与碱金属乙醇酸反应来提供反应混合物。 在具有一个碳的卤代化合物中，二氧化碳是反应产物。 在具有多于一个碳的那些中，形成乙炔。 优选的乙二醇是四甘醇，优选的碱金属是氢氧化钾。 该方法特别适用于处理构成土壤污染物的有毒卤化物质，如二溴乙烷。

公开(公告)号：US4663027A

公开(公告)日：1987-05-05

申请号：US835574

申请日：1986-03-03

申请人： Ashok K. Mendiratta ,  Wayne F. Morgan

发明人： Ashok K. Mendiratta ,  Wayne F. Morgan

IPC分类号： A62D3/00 ,  A62D3/34 ,  A62D3/36 ,  A62D101/22 ,  C10G29/04

CPC分类号： A62D3/34 ,  A62D2101/22

摘要： A method is provided for reducing the level of polychlorinated aromatic hydrocarbons dissolved in organic solvents at a faster rate wherein the organic solvent is treated with a glycol, such as polyethylene glycol, and an alkali metal hydroxide in the form of a uniform solids slurry.

摘要翻译： 提供了一种以更快的速度降低溶解在有机溶剂中的多氯芳烃的水平的方法，其中有机溶剂用二醇例如聚乙二醇和碱金属氢氧化物以均匀固体浆料的形式进行处理。