摘要:
An open-cell porous shaped body for heat exchangers, and process for making same, comprising a thermomagnetic material selected from, for example, a compound of the general formula (I): (AyB1−y)2+δCwDxEz (I) where A is Mn or Co; B is Fe, Cr or Ni; at least two of C, D and E are different, have a non-vanishing concentration and are selected from P, B, Se, Ge, Ga, Si, Sn, N, As and Sb, where at least one of C, D and E is Ge or Si; δ is a number from −0.1 to 0.1; and w, x, y, z are each a number from 0 to 1, where w+x+z=1.
摘要翻译:一种用于热交换器的开孔多孔成形体及其制造方法,其包含选自例如通式(I)的化合物:(AyB1-y)2 +δCwDxEz(I)的热磁性材料,其中A 是Mn或Co; B是Fe,Cr或Ni; C,D和E中的至少两个是不同的,具有非消失浓度并且选自P,B,Se,Ge,Ga,Si,Sn,N,As和Sb,其中C,D中的至少一个 E为Ge或Si; δ是从-0.1到0.1的数字; 并且w,x,y,z各自为0至1的数,其中w + x + z = 1。
摘要:
The invention is directed to a process for carrying out a chemical reaction in a reactor, comprising passing a reaction mixture in liquid phase through at least one structured reactor element present in said reactor, the internal surface of said reactor element that comes into contact with the reaction mixture being catalytically active, the improvement comprising passing said reaction mixture through the said at least one reactor element, said reaction mixture comprising at least one liquid and at least one gas in liquid phase.
摘要:
A nickel catalyst comprising 0.1 to 12.5 wt. % of at least one structural promoter, selected from the group of oxides of metals and metalloids and combinations thereof, and 87.5 to 99.9 wt. % nickel, calculated on the weight of nickel and the structural promoter together, the catalyst having an nickel surface area, as defined herein, of at least 10 m2/g catalyst and an average pore diameter, as defined herein, of 10 to 60 nm. It has been found that already very small amounts of promoter improves the structure of the catalyst. High amounts still provide a stable, sinter resistant material, but result in a decrease in the pore size to lower levels. Furthermore, properties and sulfur uptake capacity.
摘要:
The invention is directed to a process for the production of cyclohexane by catalytic hydrogenation of benzene using hydrogen, said process comprising the hydrogenation of benzene in the presence of a supported nickel catalyst having a nickel content of at least 10 wt. %, calculated as nickel, said catalyst containing sulfur, or compounds thereof, as promotor.
摘要:
The invention is directed to a process for the purification of benzene feedstock containing contaminating sulfur compounds, more in particular thiophenic sulfur compounds, said process comprising contacting the benzene feedstock in the presence of hydrogen with a sulfided nickel adsorbent, wherein in said adsorbent part of the nickel is present in the metallic form, and subsequently contacting the said feedstock with a supported metallic copper adsorbent.
摘要:
The invention concems a process for hydrogenation, hydroisomerization and/or hydrodesulfurization of a sulfur contaminant containing hydrocarbon feedstock, wherein the feedstock is contacted in the presence of hydrogen gas with a catalyst, which catalyst comprises platinum, palladium or a combination thereof on a non-crystalline, acidic silica-alumina support, which support is obtained by sol-gel techniques and wherein the ratio of Si to Al is from 1:10 to 200:1.
摘要:
In a method for producing form bodies for heat exchangers, comprising a thermomagnetic material, said form bodies having channels for passage of a fluid heat exchange medium, a powder of the thermomagnetic material is introduced into a binder, the resulting molding material is applied to a carrier by printing methods, and the binder and if appropriate a carrier are removed subsequently and the resulting green body is sintered.
摘要:
The invention is directed to a process for the hydrogenation of a sulfur containing feedstock, having a sulfur content of less than 50 ppm, wherein the feedstock is hydrogenated in the presence of a precious metal catalyst and a nickel-catalyst, said process being carried out in such a manner, that the feedstock is contacted with a mixture of precious metal catalyst, metal oxide and nickel catalyst, the feedstock is contacted initially with the precious metal catalyst followed by contact with the metal oxide and nickel catalyst, either in combination or sequentially, or the feedstock is contacted first with a mixture of precious metal catalyst and metal oxide, followed by contact with the nickel catalyst.
摘要:
The invention is directed to a process for the hydrogenation of a hydrocarbon feed containing thiophenic sulfur contaminants, wherein the entire feed is contacted with a nickel catalyst, the improvement comprising contacting the said feed additionally with a platinum group metal prior to or simultaneously with contacting the nickel.
摘要:
The invention relates to a process for the catalytic interesterification of triglycerides, which is characterized in that a heterogeneous catalyst is used, based on one or more oxides and/or oxysalts of metals of the groups IA and IIA of the Periodic System, at least one of the oxides and/or oxysalts having an optical basicity .LAMBDA. which is at least 0.5.