摘要:
The known condensation reaction of lower alkanoylacetic acid lower alkyl esters with aldehydes catalyzed by amines proceeds safe and in high yields if the amineis an aliphatic tertiary amine. The products are precursors of aromatic amines.
摘要:
Novel valuable, water-insoluble disazo pigments of the general formula 1 ##SPC1##Wherein R is hydrogen, methyl, methoxy or halogen, preferably chlorine or bromine, and X also represents hydrogen or halogen, preferably chlorine. The disazo compounds are obtained by bisdiazotizing a 2,7-diaminodiphenylenesulfone and coupling it on an acetoacetylbenzimidazolone. These pigments are suitable for preparing printing inks, color lakes and dispersion paints, for dyeing rubber, plastics and natural or synthetic resins. Furthermore, they are suitable for the printing of pigments on substrates, especially textile fibre materials or other flat articles such as paper.The pigments may be used for other purposes, for example in a finely divided form for dyeing rayon of viscose or cellulose ethers or esters, polyamides, polyurethanes, polyglycolterephthalate or polyacrylonitriles in the spinning mass or for dyeing paper. The pigments may be processed well in the mentioned media. The dyeings have a good color intensity as well as good fastnesses to light and to migration and are resistant to the influence of heat and chemical products, above all solvents.
摘要:
The invention relates to a process for the preparation of pyrene compounds of the formula ##STR1## by reaction of cyanuric chloride with pyrene in the presence of an aluminum halide in an aromatic solvent in a Friedel-Crafts reaction, which comprises using as solvent non-polar, halogen-free aromatic compounds, preferably composed of methyl-, ethyl- and/or propyl-substituted benzene, and carrying out the reaction in the presence of non-aqueous bases, particularly carbonates of alkaline earth and alkali metals, bicarbonates of alkaline earth and alkali metals, and also alkali metal alcoholates of the formula MOR (R=C.sub.1 -C.sub.4 -alkyl, M=alkali metal).
摘要翻译:本发明涉及一种通过在Friedel-Crafts反应中在芳族溶剂中的卤化铝存在下,将氰尿酰氯与芘反应制备式“芘化合物”的方法,该方法包括使用溶剂型 极性,无卤素的芳族化合物,优选由甲基,乙基和/或丙基取代的苯组成,并在非水性碱,特别是碱土金属和碱金属的碳酸盐,碱金属的碳酸氢盐的存在下进行反应 碱金属和碱金属,以及式MOR(R = C 1 -C 4烷基,M =碱金属)的碱金属醇化物。
摘要:
Aqueous dispersions of fluorine-containing polymersThe aqueous solvent-free dispersions contain polymers of monomers of the formulae (1) and (2)H.sub.2 C.dbd.CR--COOC.sub.2 H.sub.4 --C.sub.n F.sub.2n+1 (1)where R is fluorine, chlorine, hydrogen or methyl and n is from 5 to 18,H.sub.2 C.dbd.CRX (2)where R is hydrogen or methyl and X is a group of the formula C.sub.6 H.sub.5, CO.sub.2 CH.sub.2 C.sub.6 H.sub.5, CO.sub.2 C.sub.2 H.sub.4 C.sub.6 H.sub.5, CN, CO.sub.2 CH.sub.2 C.sub.6 H.sub.4 Cl, CO.sub.2 C.sub.6 H.sub.4 --C.sub.1 --C.sub.4 --alkyl, CO.sub.2 C.sub.2 H.sub.2n+1, where n is from 10 to 22, CONHY, where Y is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -hydroxyalkyl, C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.4 -alkyl or CO.sub.2 -C.sub.1 -C.sub.20 -alkyl, and one or more emulsifiers of the formula (3)C.sub.n F.sub.2n+1 --CR.sup.1 R.sup.2 --CHR.sup.3 --(CH.sub.2).sub.x --NR.sub.2 O (3)where R is C.sub.1 -C.sub.4 -alkyl or hydroxyethyl R.sup.1 and R.sup.2 are identical or different and each is C.sub.1 -C.sub.4 -alkyl, hydrogen or fluorine, R.sup.3 is hydrogen or C.sub.1 -C.sub.4 -alkyl, x is 1, 2 or 3 and n is from 3 to 9, and/or of the formula (4)R.sup.1 R.sup.2 R.sup.3 NO (4)where R.sup.1 and R.sup.2 are identical or different and each is C.sub.1 -C.sub.4 -alkyl or hydrogen and R.sup.3 is C.sub.8 -C.sub.18 -alkyl.The dispersions are used as water and oil repellants for textiles.
摘要:
New bisesters of alkenylsuccinic acids and ethylene oxide/propylene oxide block polymers, which are obtained by reaction of alkenylsuccinic anhydride of the Formula 1 ##STR1## wherein R denotes branched or unbranched C.sub.2 -C.sub.20 alkyl, with an ethylene oxide/propylene oxide block polymer of the Formula 2 ##STR2## wherein R denotes methyl or ethyl, n and m are numbers selected such that the polyethylene oxide contribution to the total molecule is 5 to 80% of the molecular weight and p is a number from 10 to 70, and their use as demulsifiers for oil-water emulsions, as corrosion-protective agents and as dispersants for dyestuffs.
摘要:
The catalytic hydrogenation of 4-chloro-2,5-dimethoxy nitrobenzene can be performed in water with a nickel catalyst if the average particle size is below 0.1 mm. The resulting aniline is reacted with diketene and the so-obtained N-acetoacetyl derivative is an azoic coupling component.
摘要:
Mixtures of dyestuffs of the formula ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen, lower alkyl or lower alkoxy and A is hydroxy phenyl or .beta.-hydroxy naphthyl. These dyestuff mixtures are prepared in usual manner by diazotizing and coupling. They allow to prepare highly concentrated mother solutions in hydrocarbons which are useful for coloring hydrocarbons, oils, fuels.
摘要:
The use of comb polymers obtained by condensation of a) a polycarboxylic acid or a polyalcohol b) one or more optionally sulfo-substituted polyalcohols having 2 to 4 OH groups or polyglycols of the formula HO—(XO)a—H, in which X is C2H4 and/or C3H7 and a is a number from 2 to 35, preferably from 2 to 5, c) one or more optionally sulfonated C2-C10-dicarboxylic acids and d) one or more compounds of the formulae NH2R, NHR2, ROH, R1COOH, HO(XO)b—H and HO(CH2CH2)dSO3K, in which R is C1-C22-alkyl or C6-C10-aryl, R1 is C1-C22-alkyl, C1-C22-sulfoalkyl, C6-C10-aryl or C6-C10-sulfoaryl, X is C2H4 and/or C3H7, b is a number from 3 to 40, preferably 3 to 20, d is a number from 1 to 10, preferably 1 to 4, and K is a cation, as soil release polymers.
摘要:
Copolymers based on ethylenically unsaturated dicarboxylic anhydrides, long-chain olefins and fluoroolefins Copolymers containing 10 to 60% by weight of bivalent structural units of the formula A ##STR1## wherein R.sup.1 and R.sup.2, independently of one another, are hydrogen or C.sub.1 -C.sub.6 -alkyl,a and b are zero or one and a+b is one,X and Y are identical or different and are the group --N--HR.sup.3,where R.sup.3 is C.sub.1 -C.sub.40 -alkyl, C.sub.3 -C.sub.40 -alkenyl, C.sub.5 -C.sub.20 -cycloalkyl or C.sub.6 -C.sub.18 -aryl, the group --N--(R.sup.3).sub.2,where R.sup.3 are identical or different and have the abovementioned meaning, and/or the group --O--R.sup.4,where R.sup.4 is hydrogen, an alkali metal cation, one equivalent of an alkaline earth metal ion, a cation of the formula H.sub.2 N.sup..sym. (R.sup.3).sub.2 or H.sub.3 N.sup..sym. R.sup.3, C.sub.1 -C.sub.40 -alkyl, C.sub.5 -C.sub.20 -cycloalkyl or C.sub.6 -C.sub.18 -aryl, 30 to 89% by weight of bivalent structural units of the formula B ##STR2## wherein R.sup.5 is hydrogen or C.sub.1 -C.sub.4 -alkyl andR.sub.6 is C.sub.6 -C.sub.40 -alkyl or C.sub.6 -C.sub.18 -aryl, and1 to 20% by weight of bivalent structural units of the formula C ##STR3## wherein n is a number from 6 to 24.The invention also relates to a process for the preparation of these copolymers and to the utilization thereof.