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    FUEL STEAM REFORMER SYSTEM AND REFORMER STARTUP PROCESS
    1.
    发明申请
    FUEL STEAM REFORMER SYSTEM AND REFORMER STARTUP PROCESS 有权
    燃料蒸汽改造系统和改造器启动过程

    公开(公告)号：US20100172827A1

    公开(公告)日：2010-07-08

    申请号：US12687625

    申请日：2010-01-14

    申请人： Richard Root Woods ,  Brook Forest Porter ,  Kandaswamy Duraiswamy

    发明人： Richard Root Woods ,  Brook Forest Porter ,  Kandaswamy Duraiswamy

    IPC分类号： C01B3/26

    CPC分类号： C01B3/0005 ,  B01J2219/00006 ,  C01B3/384 ,  C01B3/50 ,  C01B2203/0233 ,  C01B2203/043 ,  C01B2203/0495 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0888 ,  C01B2203/1294 ,  C01B2203/1604 ,  Y02E60/324 ,  Y02P20/128

    摘要： A hydrogen generation system is disclosed that has a vaporization section receiving and vaporizing fuel along with water and passing the vapor to a reformer catalyst section heated by a combustor section which generates reformate gas and is fueled by off-gas from a H2 purification unit along with a combustion air source. The off-gas outlet feeds the combustor section in the reformer assembly to heat the catalyst section and the vaporization section. An H2 storage unit connected to the H2 purification unit pure H2 outlet receives the pure H2. The storage unit has an outlet selectively connectable to the reformer assembly process inlet during startup without the need for a spark igniter. The startup process includes generating heat in the combustor section of the reformer assembly by passing H2 from the H2 storage unit through the vaporization section, the reformer catalyst section, the H2 purification unit and through the off-gas connection to the combustor section, then introducing water and fuel through the vaporization section and reformer catalyst section to generate reformate gas when the system is warmed, passing the reformate gas through the H2 purification unit to the off-gas connection to the combustor section, and establishing a back pressure on the reformer catalyst section and vaporizer section to decrease the hydrogen flow from the H2 storage unit until the system is fully sustainable without addition of H2 from the H2 storage unit.

    摘要翻译： 公开了一种氢气发生系统，其具有蒸发部分，其与水一起接收和蒸发燃料，并将蒸气传递到由燃烧器部分加热的重整器催化剂部分，燃烧器部分产生重整气体，并由来自H 2净化单元的废气燃料连同，以及 燃烧空气源。 废气出口将重整器组件中的燃烧器部分供给到加热催化剂部分和蒸发部分。 连接到H2净化单元纯H2出口的H2储存单元接收纯H2。 存储单元具有在启动期间可选择性地连接到重整器组件过程入口的出口，而不需要火花点火器。 启动过程包括通过使来自H 2存储单元的H 2通过蒸发部分，重整器催化剂部分，H 2纯化单元和通过与燃烧器部分的废气连接而引入重整器组件的燃烧器部分中的热量，然后引入 通过蒸发部分和重整器催化剂部分的水和燃料，当系统被加热时产生重整气体，使重整气体通过H 2净化单元到达与燃烧器部分的废气连接，并在重整器催化剂上建立背压 截面和蒸发器部分，以减少来自H 2存储单元的氢气流，直到系统完全可持续，而不需要从H 2存储单元中添加H 2。

    HYDROGEN PURIFICATION PROCESS AND SYSTEM
    2.
    发明申请
    HYDROGEN PURIFICATION PROCESS AND SYSTEM 有权
    氢气净化过程和系统

    公开(公告)号：US20090041641A1

    公开(公告)日：2009-02-12

    申请号：US12205171

    申请日：2008-09-05

    申请人： Richard Root Woods ,  Brook Forest Porter ,  Kandaswamy Duraiswamy

    发明人： Richard Root Woods ,  Brook Forest Porter ,  Kandaswamy Duraiswamy

    IPC分类号： B01J12/00

    CPC分类号： C01B3/48 ,  C01B3/34 ,  C01B2203/0216 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/0495 ,  C01B2203/146 ,  C01B2203/147 ,  Y02P20/129

    摘要： A hydrogen generation system is disclosed that includes a fuel reforming reactor generating a hydrogen-rich reformate gas at a temperature greater than 150 C., a pressure swing adsorption (PSA) hydrogen purification unit that separates the reformate gas into a relatively pure hydrogen stream and an off-gas stream, and a catalytic reactor down stream of the PSA unit that converts carbon monoxide (CO) and hydrogen (H2) contained in the relatively pure hydrogen stream into methane (CH4) and water vapor (H2O). The method of purification involves generating a hydrogen-rich reformate gas at a temperature greater than 150 C. in a fuel reforming reactor, separating the reformate gas into a relatively pure hydrogen stream and an off-gas stream in a pressure swing adsorption (PSA) hydrogen purification unit, and converting carbon monoxide (CO) and hydrogen (H2) contained in the relatively pure hydrogen stream into methane (CH4) and water vapor (H2O) in a catalytic reactor down stream of the PSA unit. The hydrogen can be further purified by including a secondary purification stage downstream of the PSA unit and the catalytic reactor wherein the secondary purification stage has a water adsorbent material bed that adsorbs the water vapor H2O and a hydrogen absorbent material downstream of the water absorbent material that absorbs hydrogen gas preferentially, thus concentrating the non-hydrogen components, such as CH4, into an exhaust stream that exits the bed, wherein the absorbed hydrogen gas is then desorbed to create an exiting very pure hydrogen stream.

    摘要翻译： 公开了一种氢生成系统，其包括在大于150℃的温度下产生富氢重整气体的燃料重整反应器，将重整气体分离成相对纯的氢气流的变压吸附（PSA）氢气净化单元， 尾气流和PSA单元的下游催化反应器，其将包含在相对纯的氢流中的一氧化碳（CO）和氢（H 2）转化成甲烷（CH4）和水蒸汽（H 2 O）。 纯化方法包括在燃料重整反应器中在大于150℃的温度下产生富氢重整气体，将重整气体分离成相对纯的氢气流和变压吸附（PSA）中的废气流， 氢气净化单元，并将包含在相对纯的氢气流中的一氧化碳（CO）和氢气（H2）转化为PSA单元下游的催化反应器中的甲烷（CH4）和水蒸汽（H 2 O）。 可以通过在PSA单元和催化反应器的下游包括二级净化级来进一步纯化氢气，其中二级净化级具有吸附水蒸气H 2 O的水吸附材料床和在吸水材料下游的吸氢材料， 优先吸收氢气，从而将非氢组分如CH4浓缩到离开床的排气流中，其中吸收的氢气然后被解吸以产生离开非常纯的氢气流。

    Hydrogen purification process and system
    3.
    发明授权
    Hydrogen purification process and system 有权
    氢气净化过程及系统

    公开(公告)号：US07439273B2

    公开(公告)日：2008-10-21

    申请号：US11536279

    申请日：2006-09-28

    申请人： Richard Root Woods ,  Brook Forest Porter ,  Kandaswamy Duraiswamy

    发明人： Richard Root Woods ,  Brook Forest Porter ,  Kandaswamy Duraiswamy

    IPC分类号： C07C27/00 ,  C07B3/26

    CPC分类号： C01B3/48 ,  C01B3/34 ,  C01B2203/0216 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/0495 ,  C01B2203/146 ,  C01B2203/147 ,  Y02P20/129

    摘要： A hydrogen generation system is disclosed that includes a fuel reforming reactor generating a hydrogen-rich reformate gas at a temperature greater than 150 C, a pressure swing adsorption (PSA) hydrogen purification unit that separates the reformate gas into a relatively pure hydrogen stream and an off-gas stream, and a catalytic reactor down stream of the PSA unit that converts carbon monoxide (CO) and hydrogen (H2) contained in the relatively pure hydrogen stream into methane (CH4) and water vapor (H2O). The method of purification involves generating a hydrogen-rich reformate gas at a temperature greater than 150 C in a fuel reforming reactor, separating the reformate gas into a relatively pure hydrogen stream and an off-gas stream in a pressure swing adsorption (PSA) hydrogen purification unit, and converting carbon monoxide (CO) and hydrogen (H2) contained in the relatively pure hydrogen stream into methane (CH4) and water vapor (H2O) in a catalytic reactor down stream of the PSA unit. The hydrogen can be further purified by including a secondary purification stage downstream of the PSA unit and the catalytic reactor wherein the secondary purification stage has a water adsorbent material bed that adsorbs the water vapor H2O and a hydrogen absorbent material downstream of the water absorbent material that absorbs hydrogen gas preferentially, thus concentrating the non-hydrogen components, such as CH4, into an exhaust stream that exits the bed, wherein the absorbed hydrogen gas is then desorbed to create an exiting very pure hydrogen stream.

    摘要翻译： 公开了一种氢生成系统，其包括在大于150℃的温度下产生富氢重整气体的燃料重整反应器，将重整气分离成相对纯的氢气流的变压吸附（PSA）氢气净化单元，以及 以及PSA单元的下游催化反应器，其将包含在相对纯的氢气流中的一氧化碳（CO）和氢（H 2 N 2）转化成甲烷（CH 4） ）和水蒸汽（H 2 O 2）。 纯化方法包括在燃料重整反应器中在大于150℃的温度下产生富氢重整气体，将重整气体分离成相对纯的氢气流和变压吸附（PSA）氢气中的废气流 净化单元，并将包含在相对纯的氢气流中的一氧化碳（CO）和氢（H 2 H 2）转化成甲烷（CH 3/4）和水蒸气（H 2 O）在PSA单元的下游催化反应器中。 可以通过在PSA单元和催化反应器的下游包括二级净化级来进一步纯化氢气，其中二次净化级具有吸附水蒸气H 2 O 2的水吸附剂床和氢 吸收材料下游的吸收材料，优先吸收氢气，从而将非氢组分（例如CH 4）浓缩到离开床的排气流中，其中吸收的氢气是 脱附以产生离开的非常纯的氢气流。

    FUEL STEAM REFORMER SYSTEM AND REFORMER STARTUP PROCESS
    4.
    发明申请
    FUEL STEAM REFORMER SYSTEM AND REFORMER STARTUP PROCESS 有权
    燃料蒸汽改造系统和改造器启动过程

    公开(公告)号：US20070212293A1

    公开(公告)日：2007-09-13

    申请号：US11534822

    申请日：2006-09-25

    申请人： Brook Forest Porter ,  Kandaswamy Duraiswamy ,  Richard Root Woods

    发明人： Brook Forest Porter ,  Kandaswamy Duraiswamy ,  Richard Root Woods

    IPC分类号： C01B3/26 ,  B01J8/00 ,  B01J19/00

    CPC分类号： C01B3/0005 ,  B01J2219/00006 ,  C01B3/384 ,  C01B3/50 ,  C01B2203/0233 ,  C01B2203/043 ,  C01B2203/0495 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0888 ,  C01B2203/1294 ,  C01B2203/1604 ,  Y02E60/324 ,  Y02P20/128

    摘要： A hydrogen generation system is disclosed that has a vaporization section receiving and vaporizing fuel along with water and passing the vapor to a reformer catalyst section heated by a combustor section which generates reformate gas and is fueled by off-gas from a H2 purification unit along with a combustion air source. The off-gas outlet feeds the combustor section in the reformer assembly to heat the catalyst section and the vaporization section. An H2 storage unit connected to the H2 purification unit pure H2 outlet receives the pure H2. The storage unit has an outlet selectively connectable to the reformer assembly process inlet during startup without the need for a spark igniter. The startup process includes generating heat in the combustor section of the reformer assembly by passing H2 from the H2 storage unit through the vaporization section, the reformer catalyst section, the H2 purification unit and through the off-gas connection to the combustor section, then introducing water and fuel through the vaporization section and reformer catalyst section to generate reformate gas when the system is warmed, passing the reformate gas through the H2 purification unit to the off-gas connection to the combustor section, and establishing a back pressure on the reformer catalyst section and vaporizer section to decrease the hydrogen flow from the H2 storage unit until the system is fully sustainable without addition of H2 from the H2 storage unit.

    摘要翻译： 公开了一种氢气发生系统，其具有蒸发部分，其与水一起接收和蒸发燃料，并将蒸汽传递到由燃烧器部分加热的重整器催化剂部分，该燃烧器部分产生重整气体，并由H 2 净化单元以及燃烧空气源。 废气出口将重整器组件中的燃烧器部分供给到加热催化剂部分和蒸发部分。 连接到H 2纯化单元纯H 2 2出口的H 2存储单元接收纯H 2 N 2。 存储单元具有在启动期间可选择性地连接到重整器组件过程入口的出口，而不需要火花点火器。 启动过程包括通过使H 2 H 2从H 2存储单元通过蒸发部分，重整器催化剂部分，H 纯化单元，并通过与燃烧器部分的废气连接，然后将水和燃料通过蒸发部分和重整器催化剂部分引入，以在系统升温时产生重整气体，使重整气体通过 H 2净化单元连接到与燃烧器部分的废气连接，并且在重整器催化剂部分和蒸发器部分上建立背压以降低来自H 2 H 2的氢气流量， SUB>存储单元，直到系统完全可持续，而不从H 2 2存储单元添加H 2 2。

    Fuel steam reformer system and reformer startup process
    8.
    发明授权
    Fuel steam reformer system and reformer startup process 有权
    燃油蒸汽重整系统和改造者启动过程

    公开(公告)号：US08372170B2

    公开(公告)日：2013-02-12

    申请号：US12687625

    申请日：2010-01-14

    申请人： Richard Root Woods ,  Brook Forest Porter ,  Kandaswamy Duraiswamy

    发明人： Richard Root Woods ,  Brook Forest Porter ,  Kandaswamy Duraiswamy

    IPC分类号： B01J8/00

    CPC分类号： C01B3/0005 ,  B01J2219/00006 ,  C01B3/384 ,  C01B3/50 ,  C01B2203/0233 ,  C01B2203/043 ,  C01B2203/0495 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0888 ,  C01B2203/1294 ,  C01B2203/1604 ,  Y02E60/324 ,  Y02P20/128

    摘要： A hydrogen generation system is disclosed that has a vaporization section receiving and vaporizing fuel along with water and passing the vapor to a reformer catalyst section heated by a combustor section which generates reformate gas and is fueled by off-gas from a H2 purification unit along with a combustion air source. The off-gas outlet feeds the combustor section in the reformer assembly to heat the catalyst section and the vaporization section. An H2 storage unit connected to the H2 purification unit pure H2 outlet receives the pure H2. The storage unit has an outlet selectively connectable to the reformer assembly process inlet during startup without the need for a spark igniter. The startup process includes generating heat in the combustor section of the reformer assembly by passing H2 from the H2 storage unit through the vaporization section, the reformer catalyst section, the H2 purification unit and through the off-gas connection to the combustor section, then introducing water and fuel through the vaporization section and reformer catalyst section to generate reformate gas when the system is warmed, passing the reformate gas through the H2 purification unit to the off-gas connection to the combustor section, and establishing a back pressure on the reformer catalyst section and vaporizer section to decrease the hydrogen flow from the H2 storage unit until the system is fully sustainable without addition of H2 from the H2 storage unit.

    摘要翻译： 公开了一种氢气发生系统，其具有蒸发部分，其与水一起接收和蒸发燃料，并将蒸气传递到由燃烧器部分加热的重整器催化剂部分，燃烧器部分产生重整气体，并由来自H 2净化单元的废气燃料连同，以及 燃烧空气源。 废气出口将重整器组件中的燃烧器部分供给到加热催化剂部分和蒸发部分。 连接到H2净化单元纯H2出口的H2储存单元接收纯H2。 存储单元具有在启动期间可选择性地连接到重整器组件过程入口的出口，而不需要火花点火器。 启动过程包括通过使来自H 2存储单元的H 2通过蒸发部分，重整器催化剂部分，H 2纯化单元和通过与燃烧器部分的废气连接而引入重整器组件的燃烧器部分中的热量，然后引入 通过蒸发部分和重整器催化剂部分的水和燃料，当系统被加热时产生重整气体，使重整气体通过H 2净化单元到达与燃烧器部分的废气连接，并在重整器催化剂上建立背压 截面和蒸发器部分，以减少来自H 2存储单元的氢气流，直到系统完全可持续，而不需要从H 2存储单元中添加H 2。

    HYDROGEN PURIFICATION PROCESS AND SYSTEM
    10.
    发明申请
    HYDROGEN PURIFICATION PROCESS AND SYSTEM 有权
    氢气净化过程和系统

    公开(公告)号：US20070212295A1

    公开(公告)日：2007-09-13

    申请号：US11536279

    申请日：2006-09-28

    申请人： Richard Root Woods ,  Brook Forest Porter ,  Kandaswamy Duraiswamy

    发明人： Richard Root Woods ,  Brook Forest Porter ,  Kandaswamy Duraiswamy

    IPC分类号： C07C27/26 ,  C01B3/16 ,  B01J8/04

    CPC分类号： C01B3/48 ,  C01B3/34 ,  C01B2203/0216 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/0495 ,  C01B2203/146 ,  C01B2203/147 ,  Y02P20/129

    摘要： A hydrogen generation system is disclosed that includes a fuel reforming reactor generating a hydrogen-rich reformate gas at a temperature greater than 150 C, a pressure swing adsorption (PSA) hydrogen purification unit that separates the reformate gas into a relatively pure hydrogen stream and an off-gas stream, and a catalytic reactor down stream of the PSA unit that converts carbon monoxide (CO) and hydrogen (H2) contained in the relatively pure hydrogen stream into methane (CH4) and water vapor (H2O). The method of purification involves generating a hydrogen-rich reformate gas at a temperature greater than 150 C in a fuel reforming reactor, separating the reformate gas into a relatively pure hydrogen stream and an off-gas stream in a pressure swing adsorption (PSA) hydrogen purification unit, and converting carbon monoxide (CO) and hydrogen (H2) contained in the relatively pure hydrogen stream into methane (CH4) and water vapor (H2O) in a catalytic reactor down stream of the PSA unit. The hydrogen can be further purified by including a secondary purification stage downstream of the PSA unit and the catalytic reactor wherein the secondary purification stage has a water adsorbent material bed that adsorbs the water vapor H2O and a hydrogen absorbent material downstream of the water absorbent material that absorbs hydrogen gas preferentially, thus concentrating the non-hydrogen components, such as CH4, into an exhaust stream that exits the bed, wherein the absorbed hydrogen gas is then desorbed to create an exiting very pure hydrogen stream.

    摘要翻译： 公开了一种氢生成系统，其包括在大于150℃的温度下产生富氢重整气体的燃料重整反应器，将重整气分离成相对纯的氢气流的变压吸附（PSA）氢气净化单元，以及 以及PSA单元的下游催化反应器，其将包含在相对纯的氢气流中的一氧化碳（CO）和氢（H 2 N 2）转化成甲烷（CH 4） ）和水蒸汽（H 2 O 2）。 纯化方法包括在燃料重整反应器中在大于150℃的温度下产生富氢重整气体，将重整气体分离成相对纯的氢气流和变压吸附（PSA）氢气中的废气流 净化单元，并将包含在相对纯的氢气流中的一氧化碳（CO）和氢（H 2 H 2）转化成甲烷（CH 3/4）和水蒸气（H 2 O）在PSA单元的下游催化反应器中。 可以通过在PSA单元和催化反应器的下游包括二级净化级来进一步纯化氢气，其中二次净化级具有吸附水蒸气H 2 O 2的水吸附剂床和氢 吸收材料下游的吸收材料，优先吸收氢气，从而将非氢组分（例如CH 4）浓缩到离开床的排气流中，其中吸收的氢气是 脱附以产生离开的非常纯的氢气流。