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    Degradation protection of solid alkali ion conductive electrolyte membrane
    5.
    发明授权
    Degradation protection of solid alkali ion conductive electrolyte membrane 有权
    固体碱离子导电电解质膜的降解保护

    公开(公告)号：US09431682B2

    公开(公告)日：2016-08-30

    申请号：US14072468

    申请日：2013-11-05

    申请人： Ceramatec, Inc.

    发明人： Sai Bhavaraju ,  Mathew Robins ,  Chett Boxley

    IPC分类号： H01M10/0562 ,  H01M10/42 ,  H01M4/36 ,  H01M10/39 ,  H01M4/52

    CPC分类号： H01M10/4235 ,  H01M4/368 ,  H01M4/52 ,  H01M10/0562 ,  H01M10/39 ,  H01M10/3918 ,  H01M2300/0074

    摘要： The present invention provides an electrochemical cell having an negative electrode compartment and a positive electrode compartment. A solid alkali ion conductive electrolyte membrane is positioned between the negative electrode compartment and the positive electrode compartment. A catholyte solution in the positive electrode compartment includes a halide ion or pseudohalide ion concentration greater than 3M, which provides degradation protection to the alkali ion conductive electrolyte membrane. The halide ion or pseudohalide ion is selected from chloride, bromide, iodide, azide, thiocyanate, and cyanide. In some embodiments, the electrochemical cell is a molten sodium rechargeable cell which functions at an operating temperature between about 100° C. and about 150° C.

    摘要翻译： 本发明提供具有负电极室和正电极室的电化学电池。 固体碱离子传导性电解质膜位于负极室和正极室之间。 正电极室中的阴极电解液包含大于3M的卤离子或拟卤化物离子浓度，其为碱离子导电电解质膜提供降解保护。 卤离子或拟卤离子选自氯化物，溴化物，碘化物，叠氮化物，硫氰酸盐和氰化物。 在一些实施方案中，电化学电池是在约100℃至约150℃的操作温度下起作用的熔融钠可再充电电池。

    SODIUM-HALOGEN SECONDARY CELL
    6.
    发明申请
    SODIUM-HALOGEN SECONDARY CELL 审中-公开
    钠卤素二次细胞

    公开(公告)号：US20160087313A1

    公开(公告)日：2016-03-24

    申请号：US14956078

    申请日：2015-12-01

    申请人： CERAMATEC, INC.

    发明人： Sai Bhavaraju ,  Mathew Robins ,  Alexis Eccleston

    IPC分类号： H01M10/39 ,  H01M10/0563 ,  H01M4/38 ,  H01M10/054

    CPC分类号： H01M10/399 ,  H01M2/40 ,  H01M4/381 ,  H01M4/388 ,  H01M4/62 ,  H01M4/661 ,  H01M10/054 ,  H01M10/0562 ,  H01M10/0563 ,  H01M10/36 ,  H01M10/4235 ,  H01M2300/0054 ,  H01M2300/0068

    摘要： An intermediate temperature sodium-halogen secondary cell that includes a negative electrode compartment housing a negative, molten sodium-based electrode and a positive electrode compartment housing a current collector disposed in a highly conductive molten positive electrolyte. A sodium halide (NaX) positive electrode is disposed in a molten positive electrolyte comprising one or more AlX3 salts, wherein X may be the same or different halogen selected from Cl, Br, and I, wherein the ratio of NaX to AlX3 is greater than or equal to one. A sodium ion conductive solid electrolyte membrane separates the molten sodium negative electrode from the molten positive electrolyte. The secondary cell operates at a temperature in the range from about 80° C. to 210° C.

    摘要翻译： 一种中间温度的钠卤素二次电池，其包括容纳负极熔融钠基电极的负极室和容纳设置在高导电性熔融正电解质中的集电体的正电极室。 将卤化钠（NaX）正极置于包含一种或多种AlX 3盐的熔融正电解质中，其中X可以是相同或不同的选自Cl，Br和I的卤素，其中NaX与AlX3的比例大于 或等于1。 钠离子传导性固体电解质膜将熔融的钠负极与熔融的正电解质分离。 二次电池在约80℃至210℃的温度下工作。

    TREATMENT OF INCINERATOR OFF GAS
    7.
    发明申请
    TREATMENT OF INCINERATOR OFF GAS 审中-公开
    焚烧炉关闭气体处理

    公开(公告)号：US20150321143A1

    公开(公告)日：2015-11-12

    申请号：US14707645

    申请日：2015-05-08

    申请人： CERAMATEC, INC.

    发明人： S. ELANGOVAN ,  Joseph Hartvigsen

    IPC分类号： B01D53/32 ,  B01D53/46 ,  B01D53/86

    CPC分类号： B01D53/323 ,  B01D53/32 ,  B01D53/346 ,  B01D53/46 ,  B01D53/86 ,  B01D2251/102 ,  B01D2257/70 ,  B01D2257/93 ,  B01D2258/0291

    摘要： A system treats off gas from a waste incinerator to decrease potentially negative aspects of the off gas to the environment. The system includes a waste incinerator and a plasma oxidizer. The waste incinerator includes an incineration chamber to contain a waste material during at least a portion of an incineration process of the waste material. The waste incinerator also includes an exhaust outlet to exhaust an off gas from the incineration process of the waste material. The plasma oxidizer is coupled to the waste incinerator to receive and oxidize the off gas from the exhaust outlet of the waste incinerator. The plasma oxidizer includes a non-thermal gliding electric arc oxidation system to generate the plasma.

    摘要翻译： 一个系统处理来自废物焚化炉的废气，以减少废气对环境的潜在负面影响。 该系统包括废物焚化炉和等离子体氧化器。 废物焚化炉包括焚烧室，用于在废物的焚烧过程的至少一部分期间容纳废料。 垃圾焚烧炉还包括排气口，用于从废料的焚烧过程排出废气。 等离子体氧化器耦合到废物焚烧炉以从废物焚烧炉的排气出口接收和氧化废气。 等离子体氧化器包括用于产生等离子体的非热滑动电弧氧化系统。

    Fixed bed reactor heat transfer structure
    8.
    发明授权
    Fixed bed reactor heat transfer structure 有权
    固定床反应器传热结构

    公开(公告)号：US09157689B2

    公开(公告)日：2015-10-13

    申请号：US14078040

    申请日：2013-11-12

    申请人： Ceramatec, Inc.

    发明人： Joseph J. Hartvigsen

    IPC分类号： F28F7/00 ,  B01J8/00 ,  B01J8/02 ,  B01J19/00 ,  B01J19/24

    CPC分类号： F28F7/00 ,  B01J8/067 ,  B01J2208/00115 ,  B01J2208/0015 ,  B01J2208/00168 ,  B01J2208/00212 ,  B01J2208/00238 ,  B01J2208/00513 ,  B01J2208/065 ,  B01J2219/30223 ,  B01J2219/30242 ,  B01J2219/30408 ,  B01J2219/30416 ,  F28D2021/0022 ,  F28F1/40

    摘要： An apparatus includes a heat transfer structure configured to be disposed at least partially within an enclosure of a fixed bed reactor and operable to transfer heat from a heat source to a heat sink. The heat transfer structure includes a plurality of fins each fin including a first end and a second end, the first end contacting an inner surface of the enclosure of the fixed bed reactor, the second end at least partially enclosed within the enclosure of the fixed bed reactor. A path of at least one of the plurality of fins comprises the shortest possible length between the first end of the at least one of the plurality of fins and the second end of the at least one of the plurality of fins.

    摘要翻译： 一种装置包括传热结构，其被配置为至少部分地设置在固定床反应器的外壳内并可操作以将热量从热源传递到散热器。 传热结构包括多个翅片，每个翅片包括第一端和第二端，第一端接触固定床反应器的外壳的内表面，第二端至少部分地封闭在固定床的外壳内 反应堆。 所述多个翅片中的至少一个的路径包括所述多个翅片中的所述至少一个翅片的所述第一端与所述多个翅片中的所述至少一个翅片的所述第二端之间的最短可能长度。

    METHOD AND DEVICE FOR CARBOXYLIC ACID PRODUCTION
    9.
    发明申请
    METHOD AND DEVICE FOR CARBOXYLIC ACID PRODUCTION 审中-公开
    羧酸生产的方法和装置

    公开(公告)号：US20150233002A1

    公开(公告)日：2015-08-20

    申请号：US14704783

    申请日：2015-05-05

    申请人： Ceramatec, Inc.

    发明人： SAI Bhavaraju ,  Kean Duffey

    IPC分类号： C25B13/04 ,  C25B3/02 ,  C25B15/08

    CPC分类号： C25B13/04 ,  B01D61/422 ,  C25B1/02 ,  C25B3/00 ,  C25B3/02 ,  C25B15/08

    摘要： A multi-compartment electrolysis cell includes an anodic compartment, a cathodic compartment, and a solid alkali ion transporting membrane (such as a NaSICON membrane). An anolyte is added to the anodic compartment. The anolyte comprises an alkali salt of a carboxylic acid, a first solvent, and a second solvent. The alkali salt of the carboxylic acid is partitioned into the first solvent. The anolyte is then electrolyzed to produce a carboxylic acid, wherein the produced carboxylic acid is partitioned into the second solvent. The second solvent may then be separated from the first solvent and the produced carboxylic acid may be recovered from the second solvent. The first solvent may be water and the second solvent may be an organic solvent.

    摘要翻译： 多室电解槽包括阳极室，阴极室和固体碱离子传输膜（例如NaSICON膜）。 将阳极电解液加入阳极室。 阳极电解液包含羧酸的碱金属盐，第一溶剂和第二溶剂。 将羧酸的碱金属盐分成第一溶剂。 然后电解阳极电解液以产生羧酸，其中所产生的羧酸被分配到第二溶剂中。 然后可以将第二溶剂与第一溶剂分离，并且可以从第二溶剂回收所产生的羧酸。 第一溶剂可以是水，第二溶剂可以是有机溶剂。