公开(公告)号：US5032641A

公开(公告)日：1991-07-16

申请号：US380595

申请日：1989-06-26

申请人： Kiyoshi Nanishi ,  Hideo Kogure ,  Heihachi Murase

发明人： Kiyoshi Nanishi ,  Hideo Kogure ,  Heihachi Murase

IPC分类号： C08L33/16 ,  C08L43/04 ,  C09D133/16 ,  C09D143/04

CPC分类号： C09D133/16 ,  C09D143/04 ,  C08L33/16 ,  C08L43/04

摘要： A water-repellant film-forming composition comprisinga mixture of(a) a (co)polymer of 5 to 100% by weight of a specific fluoroalkyl group-containing (meth)acrylic monomer and 0 to 95% by weight of an unsaturated monomer co-polymerizable with the fluoroalkyl group-containing (meth)acrylic monomer, and(b) a copolymer of 0.1 to 75% by weight of a specific silicon-containing polymerizable unsaturated monomer and 25 to 99.9% by weight of an unsaturated monomer copolymerizalbe with the silicon-containing polymerizable unsaturated monomer, andfine silica particles having an average particle diameter of not more than 5 micrometers, in specified amounts.

公开(公告)号：US4636324A

公开(公告)日：1987-01-13

申请号：US712724

申请日：1985-03-18

申请人： Heihachi Murase ,  Kiyoshi Nanishi

发明人： Heihachi Murase ,  Kiyoshi Nanishi

IPC分类号： C09D183/04 ,  C09K3/18 ,  C09D5/20

CPC分类号： C09D183/04 ,  C08K3/0075 ,  C08K5/01 ,  C08K5/09

摘要： The present invention provides: a composition for use in preventing the formation of ice comprising (A) organopolysiloxane, (B) alkali metal compound and (C) liquid or solid paraffin; a method for preventing the formation of ice by applying the composition to the surface of an object; and another method for preventing the formation of ice by applying a primer containing a silane coupling agent to the surface of an object and applying the composition to the primer coat formed.

摘要翻译： 本发明提供：用于防止形成冰的组合物，其包含（A）有机聚硅氧烷，（B）碱金属化合物和（C）液体或固体石蜡; 一种通过将组合物施用到物体的表面来防止形成冰的方法; 以及另一种通过将含有硅烷偶联剂的底漆施用到物体表面并将组合物施加到所形成的底漆涂层来防止形成冰的方法。

公开(公告)号：US5196487A

公开(公告)日：1993-03-23

申请号：US712279

申请日：1991-06-10

申请人： Hideo Kogure ,  Heihachi Murase ,  Naozumi Iwasawa

发明人： Hideo Kogure ,  Heihachi Murase ,  Naozumi Iwasawa

IPC分类号： C07F7/18 ,  C08F2/46 ,  C08F299/00 ,  C09D5/08 ,  C09D183/07 ,  C09D183/08

CPC分类号： C07F7/1836 ,  C08F299/00 ,  C09D183/08 ,  C09D5/08

摘要： A corrosion preventive resin having in the molecule at least one chelate forming group selected from among groups represented by the formula ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and are each a hydrogen atom or alkyl having 1 to 8 carbon atoms, and groups represented by teh general formula ##STR2## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are the same or different and are each a hydrogen atom, alkyl having 1 to 8 carbon atoms or a group forming a bivalent o-phenylene group along with two carbon atoms attached thereto. A photopolymerizable composition which includes (a) a resin having in the molecule at least one mole of polymerizable double bond per 1000 g of the resin and having per molecule at least one chelate forming group selected from among the groups represented by formula (II) and formula (III), and (b) a photopolymerization initiator is also disclosed.

摘要翻译： 一种防腐树脂，其在分子中具有至少一种螯合形成基团，其选自由式（I）表示的基团，其中R 1和R 2相同或不同，各自为氢原子或具有1至8个碳原子的烷基 原子和由通式（II）表示的基团，其中R 3，R 4，R 5和R 6相同或不同，各自为氢原子，具有1至8个碳原子的烷基或形成二价o- 亚苯基以及与其连接的两个碳原子。 一种可光聚合组合物，其包含（a）分子中每1000克所述树脂具有至少1摩尔可聚合双键并且每分子具有选自式（II）表示的基团中的至少一种螯合形成基团和 式（III）和（b）光聚合引发剂也被公开。

公开(公告)号：US5443900A

公开(公告)日：1995-08-22

申请号：US115252

申请日：1993-09-01

申请人： Toshiaki Nagano ,  Heihachi Murase ,  Hideo Kogure

发明人： Toshiaki Nagano ,  Heihachi Murase ,  Hideo Kogure

IPC分类号： H01Q17/00 ,  H05K9/00 ,  B32B5/16

CPC分类号： H05K9/0088 ,  H01Q17/00 ,  Y10T428/12535 ,  Y10T428/12556 ,  Y10T428/12562 ,  Y10T428/12569 ,  Y10T428/26 ,  Y10T428/265 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31699

摘要： An electromagnetic wave absorber comprising at least one of a unit film as a multilayered film comprising a resin layer (A) optionally containing a pigment and a layer (B) applied onto the resin layer (A), selected from a group consisting of a metal layer, an alloy layer and a partly oxidized layer of the metal layer or the alloy layer, and having a film thickness of 1 nm to 50 nm.

摘要翻译： 一种电磁波吸收体，包括作为多层膜的单位膜中的至少一种，其包含任选地含有颜料的树脂层（A）和施加到树脂层（A）上的层（B），所述层（B）选自金属 层，合金层和金属层或合金层的部分氧化层，并且具有1nm至50nm的膜厚度。

公开(公告)号：US5281449A

公开(公告)日：1994-01-25

申请号：US742232

申请日：1991-08-08

申请人： Naozumi Iwasawa ,  Hideo Kogure ,  Heihachi Murase

发明人： Naozumi Iwasawa ,  Hideo Kogure ,  Heihachi Murase

IPC分类号： G03F7/027 ,  G03F7/028 ,  G03F7/031 ,  G03F7/038 ,  G03F7/075 ,  H01L21/027 ,  H05K3/00 ,  B05D3/06 ,  G03C1/705

CPC分类号： G03F7/038 ,  H05K3/0076

摘要： The invention provides a method for forming a pattern coating, the method including the steps of:applying to a substrate a radiation curable composition containing a resin (a) which contains, per kilogram of said resin (a) about 1.5 to about 4.5 moles of a polyermizable unsaturated group, about 0.4 to about 2.5 moles of a carboxyl group and 0.2 to about 3.5 moles of a thioether group, the resin having a number average molecular weight of about 500 to about 50,000; selectively irradiating a portion of the applied coating with actinic rays; and subjecting the coating to development with an alkali aqueous solution.

摘要翻译： 本发明提供一种形成图案涂层的方法，该方法包括以下步骤：向基材施加含有树脂（a）的可辐射固化组合物，该树脂（a）每千克所述树脂（a）含有约1.5至约4.5摩尔 约0.4至约2.5摩尔的羧基和0.2至约3.5摩尔的硫醚基团，所述树脂的数均分子量为约500至约50,000; 用光化射线选择性地照射所涂敷的涂层的一部分; 并用碱性水溶液对涂层进行显影。

公开(公告)号：US5342901A

公开(公告)日：1994-08-30

申请号：US930524

申请日：1992-09-30

申请人： Hideo Kogure ,  Heihachi Murase ,  Masafumi Kume

发明人： Hideo Kogure ,  Heihachi Murase ,  Masafumi Kume

IPC分类号： C08F8/30 ,  C09D5/44 ,  C08F8/32 ,  C08F26/02

CPC分类号： C09D5/4407 ,  C08F8/30 ,  C09D5/4419 ,  Y10S423/14

摘要： The invention provides a film-formable, chelate-forming resin having, per 1000 g of the resin, about 0.2 to about 3.5 moles of chelate-forming group represented by the formula [1], [2], [3] or [4]: ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and each represents a hydrogen atom, a halogen atom, a nitro group, a nitroso group, a cyano group, a hydrocarbon group having up to 18 carbon atoms, or an alkoxyalkyl group having up to 12 carbon atoms, and a process for preparing the resin.The invention also provides a metal surface treating composition and a corrosion preventive coating composition both containing the above chelate-forming resin, and a chelate-forming resin composition comprising the resin and a crosslinking agent.The invention further provides a method for forming an electrophoretic coating, comprising the steps of bringing the metal surface treating composition into contact with a metal surface before electrodeposition on the metal surface to accomplish pretreatment, and conducting electrodeposition on the pretreated metal surface.

摘要翻译： PCT No.PCT / JP92 / 00113 Sec。 371日期：1992年9月30日 102（e）日期1992年9月30日PCT提交1992年2月5日PCT公布。 第WO92 / 13902号公报 本发明提供一种可成膜的螯合形成树脂，其每千克树脂具有约0.2至约3.5摩尔由式[1]，[2]表示的螯合形成基团， ，[3]或[4]： [1] [2] [3]不同，各自表示氢原子，卤素原子，硝基，亚硝基，氰基 ，具有至多18个碳原子的烃基或具有至多12个碳原子的烷氧基烷基，以及制备该树脂的方法。 本发明还提供了含有上述螯合形成树脂的金属表面处理组合物和防腐涂料组合物，以及包含树脂和交联剂的螯合形成树脂组合物。 本发明还提供一种形成电泳涂层的方法，包括以下步骤：在电沉积在金属表面上之前使金属表面处理组合物与金属表面接触，以实现预处理，并在预处理的金属表面上进行电沉积。

公开(公告)号：US5188750A

公开(公告)日：1993-02-23

申请号：US790088

申请日：1991-11-13

申请人： Hideo Kogure ,  Heihachi Murase ,  Koichi Tamura

发明人： Hideo Kogure ,  Heihachi Murase ,  Koichi Tamura

IPC分类号： C09D143/04 ,  C09D183/04 ,  C09D183/14 ,  C09K3/18

CPC分类号： C09K3/185 ,  C09D143/04 ,  C09D183/04 ,  C09D183/14

摘要： This invention provides:(A) an anti-icing composition comprising a silicone resin which is at least one condensate selected from the group consisting of:(i) a condensate of an alkoxydimethylsiloxane compound represented by the formula ##STR1## wherein R.sub.1 l is a methyl group or an ethyl group, A is an oxygen atom, an ethylene group or a 1,3-propylene group, a is an integer of 5 to 150, b and e are different or the same and each represent an integer of 1 to 3, c is an integer of 3-b and d is an integer of 3-e,(ii) a condensate of the compound of the formula (I) and an alkoxysilane compound represented by the formula(R.sub.3)h--Si--(OR.sub.2)j (II) wherein R.sub.2 is a methyl group or an ethyl group, R.sub.3 is an alkyl group having 1 to 8 carbon atoms, h is an integer of 0 to 3 and j is an integer of 4-h,(iii) a condensate of the compound of the formula (I) and a dihydroxydimethylsiloxane compound represented by the formula ##STR2## wherein k is an integer of 10 to 200, and (iv) a condensate of the compound of the formula (I), the alkoxysilane compound of the formula (II) and the dihydroxydimethylsiloxane compound of the formula (III); and(B) a method of preventing icing which comprises applying to an article an aerosol comprising the foregoing anti-icing composition and a propellant.

摘要翻译： 本发明提供：（A）防结冰组合物，其包含硅氧烷树脂，其为至少一种选自下列的缩合物：（i）由式（I）表示的烷氧基二甲基硅氧烷化合物的缩合物，其中R1 l是甲基或乙基，A是氧原子，亚乙基或1,3-亚丙基，a是5〜150的整数，b和e不同或相同，各自表示整数 1〜3的整数，c为3-b的整数，d为3-e的整数，（ii）式（I）的化合物与式（R3）表示的烷氧基硅烷化合物的缩合物，h- Si（OR 2）j（II）其中R 2为甲基或乙基，R 3为碳原子数1〜8的烷基，h为0〜3的整数，j为4〜 （iii）式（I）化合物和由式（III）表示的二羟基二甲基硅氧烷化合物的缩合物，其中k为10至200的整数，和（iv）t的缩合物 式（I）的化合物，式（II）的烷氧基​​硅烷化合物和式（III）的二羟基二甲基硅氧烷化合物; 和（B）防结冰的方法，其包括向制品施加包含前述防冰组合物和推进剂的气溶胶。

公开(公告)号：US5445871A

公开(公告)日：1995-08-29

申请号：US279066

申请日：1994-07-22

申请人： Heihachi Murase ,  Tsutomu Norimatsu ,  Masao Ogawa ,  Naoya Haruta

发明人： Heihachi Murase ,  Tsutomu Norimatsu ,  Masao Ogawa ,  Naoya Haruta

IPC分类号： C08J7/04 ,  B32B7/02

CPC分类号： C08J7/045 ,  C08J7/047 ,  C08J2483/00 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/265 ,  Y10T428/31504 ,  Y10T428/31507 ,  Y10T428/31612 ,  Y10T428/31663 ,  Y10T428/31667

摘要： A surface-modified plastic plate for use in optical disc bases, windows of aircrafts, automobiles or of architectural structures, solar cell receptors, liquid crystal display panels and protective sheet of computer touch panels, which comprises a laminate consisting of a plastic substrate; a cured film of an actinic ray-curable primer composition, said cured film formed onto a surface of the plastic substrate in a film thickness of 0.1 to 10 .mu.m; and an inorganic material layer formed onto the cured film by a physical deposition process and having a thickness of 0.1 .mu.m or more but less than 1.0 .mu.m; and a surface-modified plastic plate for use in windows, preferably windows of aircrafts, automobiles and architectural structures, which comprises a laminate consisting of a plastic plate, preferably comprising a plastic selected from polymethyl methacrylate polymer and polycarbonate in the case of the window of the aircraft; a cured film of a heat-curable primer composition, said cured film being formed on a surface of the plastic plate in a film thickness of 0.1 to 10 .mu.m; and an inorganic material layer formed onto the cured film by a physical deposition process and having a thickness of 0.25 .mu.m or more but less than 1.0 .mu.m.

摘要翻译： 用于光盘基座，飞机窗口，汽车或建筑结构的表面改性塑料板，太阳能电池接收器，液晶显示面板和计算机触摸面板的保护片，其包括由塑料基板组成的层压板; 光固化性底漆组合物的固化膜，所述固化膜形成在塑料基板的表面上，膜厚为0.1〜10μm; 以及通过物理沉积工艺形成在固化膜上并具有0.1μm以上且小于1.0μm的厚度的无机材料层; 以及用于窗户，优选飞机，汽车和建筑结构的窗户的表面改性塑料板，其包括由塑料板组成的层压板，该塑料板优选地包括选自聚甲基丙烯酸甲酯聚合物和聚碳酸酯的塑料，在窗口 飞机; 热固性底漆组合物的固化膜，所述固化膜形成在所述塑料板的表面上，膜厚度为0.1-10μm; 以及通过物理沉积工艺在固化膜上形成的厚度为0.25μm以上且小于1.0μm的无机材料层。

公开(公告)号：US4246368A

公开(公告)日：1981-01-20

申请号：US903260

申请日：1978-05-05

申请人： Heihachi Murase

发明人： Heihachi Murase

IPC分类号： C09D5/46 ,  C09D157/00 ,  C08L63/00 ,  C08L33/06 ,  C08L33/14 ,  C08L67/00

CPC分类号： C09D157/00 ,  Y10S524/904 ,  Y10S525/934

摘要： A powder coating composition for forming multi layer coatings comprising:(1) at least one of finely divided thermosetting addition copolymers having a glass transition temperature of 35.degree. to 75.degree. C. and comprising as comonomers a wt. % of a hardness imparting monomer and b wt. % of a softness imparting monomer based on the copolymer wherein a+b.ltoreq.60, b.ltoreq.a and b.ltoreq.20, and(2) at least one of finely divided thermosetting resinous materials having incompatibility or low compatibility with the copolymer and a substantially greater surface tension than the copolymer when melted at the same temperature and substantially differing from the copolymer in composite parameter.

摘要翻译： 一种用于形成多层涂层的粉末涂料组合物，包括：（1）至少一种细分热固性加成共聚物，其玻璃化转变温度为35-75℃，并且包含共聚单体wt％ ％的硬度赋予单体和bwt。 ％的基于共聚物的柔软性赋予单体，其中a +b≤60，b≤a和b≤20，和（2）至少一种细分散的热固性树脂材料，其具有不相容性或与 该共聚物和当在相同温度下熔融并且与复合参数中的共聚物基本不同时，共聚物具有显着更大的表面张力。

公开(公告)号：US4305994A

公开(公告)日：1981-12-15

申请号：US177509

申请日：1980-08-12

申请人： Heihachi Murase

发明人： Heihachi Murase

IPC分类号： B05D3/10 ,  C09D5/46 ,  B05D1/36

CPC分类号： B05D3/102 ,  B05D3/10 ,  B05D7/54 ,  B05D2202/00 ,  B05D2451/00 ,  Y10T428/31529 ,  Y10T428/31678 ,  Y10T428/31681

摘要： In a process for forming a multilayer coated film which comprises coating a multilayer coat-forming paint on the surface of a substrate to form a multilayer coated film thereon, the improvement wherein prior to the coating, the surface of the substrate is treated with a solution containing at least one onium compound selected from compounds of formulae (I) and (II) below ##STR1## wherein Y represents a nitrogen, phosphorus or arsenic atom, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are identical or different and each represents a hydrogen atom or an organic group having not more than 8 carbon atoms, and X.sub..crclbar. represents an anion.

摘要翻译： 在形成多层涂膜的方法中，其包括在基材表面上涂覆多层涂层涂料以在其上形成多层涂膜，其改进在于，在涂布之前，用溶液处理基材表面 含有至少一种选自下述式（I）和（II）的化合物的鎓化合物，其中Y表示氮，磷或砷原子，R 1，R 2，R 3和R 4相同或不同，各自表示氢原子 或不大于8个碳原子的有机基团，X（ - ）表示阴离子。