公开(公告)号：US4044197A

公开(公告)日：1977-08-23

申请号：US651610

申请日：1976-01-22

申请人： Hubert Wiest ,  Erwin Lieb ,  Heinz Schafer

发明人： Hubert Wiest ,  Erwin Lieb ,  Heinz Schafer

IPC分类号： C08F2/00 ,  C08F2/22 ,  C08F10/00 ,  C08F20/00 ,  C08F20/52 ,  C08F210/00 ,  C08F218/00 ,  C08F218/02 ,  C08F218/08 ,  C08F220/00 ,  C08F220/04 ,  C09D131/04 ,  C09J131/04 ,  D04H1/58 ,  D06M15/333 ,  C08F210/02

CPC分类号： C08F218/08

摘要： A thermally self-cross-linkable ethylene/vinyl acetate copolymer consisting essentially of the following monomer units:A. from 5 to 50% by weight of ethylene,B. from 30 to 87% by weight of vinyl acetate,C. from 2 to 10% by weight of a copolymerizable compound containing an N-methylol group,D. from 5 to 20% by weight of an acryl compound selected from the group consisting of alkyl acrylate and alkyl methacrylate where alkyl has from 1 to 10 carbon atoms,E. from 0.5 to 3% by weight of a mono-olefinically-unsaturated carboxylic acid, andF. up to 1% by weight of a poly-olefinically-unsaturated monomer, and having a glass transition temperature of between -40.degree. and +10.degree. C; as well as the process for its preparation.

摘要翻译： 基本上由以下单体单元组成的热自交联乙烯/乙酸乙烯酯共聚物：

公开(公告)号：US4328325A

公开(公告)日：1982-05-04

申请号：US136544

申请日：1980-04-02

申请人： Klaus Marquardt ,  Hubert Wiest

发明人： Klaus Marquardt ,  Hubert Wiest

IPC分类号： C08F299/00 ,  C08F2/48 ,  C08F290/00 ,  C08F299/06 ,  C08G18/67 ,  C09J4/00 ,  C08F216/12 ,  C08F220/36 ,  C08F220/60 ,  C08F283/00

CPC分类号： C08G18/6725 ,  C08F299/065

摘要： The invention relates to a process for the preparation of polymers from polymerizable urethanes prepared by reacting isocyanates having at least two isocyanato groups with polyesters of the formula ##STR1## wherein R is alkylene having from 2 to 10 carbon atoms, A is an ethylenically-unsaturated radical, and n is an integer of from 1 to 100.

摘要翻译： 本发明涉及一种由可聚合的聚氨酯制备聚合物的方法，其通过使具有至少两个异氰酸酯基的异氰酸酯与下式的聚酯反应制备：其中R是具有2-10个碳原子的亚烷基，A是烯属不饱和的 自由基，n为1〜100的整数。

公开(公告)号：US4322516A

公开(公告)日：1982-03-30

申请号：US131785

申请日：1980-03-19

申请人： Hubert Wiest ,  Rudolf Weissgerber ,  Erwin Lieb

发明人： Hubert Wiest ,  Rudolf Weissgerber ,  Erwin Lieb

IPC分类号： C08F20/00 ,  C08F20/10 ,  C08F218/00 ,  C08F218/02 ,  C08F218/08 ,  C08F220/00 ,  C08F220/10 ,  C08F220/18 ,  C09J131/04 ,  C08F210/02

CPC分类号： C08F220/18 ,  C08F218/08 ,  Y10T428/2878 ,  Y10T428/2887 ,  Y10T428/2891

摘要： A copolymer having good properties for use as a pressure-sensitive adhesive from an aqueous dispersion comprising:(a) from 10% to 30% by weight of ethylene units,(b) from 29% to 69% by weight of acrylic ester units,(c) from 20% to 55% by weight of vinyl acetate units,(d) from 0.2% to 8% by weight of (meth)acrylamide units, and(e) from 0 to 12% of other olefinically-unsaturated monomer units copolymerizable with the above,said copolymer having a glass transition temperature of from -20.degree. C. to -60.degree. C. and a K-value according to Fikentscher, measured in tetrahydrofuran, of from 50 to 180; as well as processes to make the same and aqueous dispersions of the same for use as pressure-sensitive adhesives.

摘要翻译： 一种由水分散体用作压敏粘合剂的具有良好性能的共聚物，其包含：（a）10重量％至30重量％的乙烯单元，（b）29重量％至69重量％的丙烯酸酯单元， （c）20重量％至55重量％的乙酸乙烯酯单元，（d）0.2重量％至8重量％的（甲基）丙烯酰胺单元，和（e）0至12重量％的其它烯属不饱和单体单元 与上述共聚物，所述共聚物的玻璃化转变温度为-20℃至-60℃，根据Fikentscher测得的K值在四氢呋喃中为50至180; 以及制备相同的水性分散体并用作压敏粘合剂的方法。

公开(公告)号：US4205161A

公开(公告)日：1980-05-27

申请号：US858206

申请日：1977-12-07

申请人： Hubert Wiest ,  Peter Ludwig ,  Klaus Hafener ,  Erwin Lieb

发明人： Hubert Wiest ,  Peter Ludwig ,  Klaus Hafener ,  Erwin Lieb

IPC分类号： C08F214/00 ,  C08F2/00 ,  C08F2/22 ,  C08F4/00 ,  C08F4/40 ,  C08F6/00 ,  C08F6/06 ,  C08F14/00 ,  C08F214/06 ,  C08F6/24 ,  C08F6/16

CPC分类号： C08F214/06 ,  C08F6/006

摘要： A process for the manufacture of vinyl chloride copolymers having a reduced content of free vinyl chloride comprising polymerizing a monomer mixture containing from 15% to 90% by weight of vinyl chloride under aqueous emulsion polymerization conditions with conventional post-polymerization, releasing the pressure, flushing the gas space above the copolymer dispersion free of monomer, cooling the copolymer dispersion to a temperature of from 10.degree. to 40.degree. C., adding a redox catalyst to the cooled dispersion consisting of from 0.002% to 0.5% by weight of the dispersion of an oil-soluble peroxy compound, and a water-soluble sulfur-containing reducing agent in a ratio of reducing agent to peroxy compound of 0.5 to 3 equivalents, allowing the dispersion to stand at a temperature of from 10.degree. to 40.degree. C. for a period of two hours to two days and recovering a copolymer dispersion having a vinyl chloride content of less than 50 ppm.

摘要翻译： 一种制造具有降低的游离氯乙烯含量的氯乙烯共聚物的方法，包括在含水乳液聚合条件下聚合含有15-90％重量的氯乙烯的单体混合物，常规后聚合，释放压力，冲洗 在共聚物分散体上方的气体空间不含单体，将共聚物分散体冷却至10℃至40℃的温度，向冷却的分散体中加入氧化还原催化剂，该分散体由0.002重量％至0.5重量％ 油溶性过氧化合物和还原剂与过氧化合物的比例为0.5〜3当量的水溶性含硫还原剂，使分散体在10℃〜40℃的温度下放置， 时间为2小时至2天，并回收氯乙烯含量小于50ppm的共聚物分散体。

公开(公告)号：US4959249A

公开(公告)日：1990-09-25

申请号：US423002

申请日：1989-10-18

申请人： Bernd Schilling ,  Gerhard Brink ,  Ingo Harder ,  Hubert Wiest

发明人： Bernd Schilling ,  Gerhard Brink ,  Ingo Harder ,  Hubert Wiest

IPC分类号： D06M15/643 ,  C08L31/04 ,  C08L43/00 ,  C08L43/04 ,  C09J131/04 ,  D06M15/227 ,  D06M15/263 ,  D06M15/285 ,  D06M15/29 ,  D06M15/327 ,  D06M15/333 ,  D06M15/356 ,  D06M101/08

CPC分类号： D06M15/285 ,  D06M15/227 ,  D06M15/263 ,  D06M15/29 ,  D06M15/333 ,  D06M15/3568 ,  Y10T442/2566

摘要： Binders for strengthening textile fiber structures and based on aqueous, self-crosslinking vinyl ester dispersions having a reduced formaldehyde content or containing no formaldehyde. The low content of free formaldehyde in the dispersion is achieved by partial or complete substitution of the crosslinking comonomers containing N-methylol groups by vinylalkoxysilanes as crosslinking agents. Non-woven treated with these formaldehyde-free or low formaldehyde binder systems are distinguished by high strength values and excellent solvent resistance.

摘要翻译： 用于加强纺织纤维结构并基于具有降低的甲醛含量或不含甲醛的水性，自交联乙烯基酯分散体的粘合剂。 分散体中游离甲醛的含量低是通过乙烯基烷氧基硅烷作为交联剂部分或完全取代含有N-羟甲基的交联共聚单体来实现的。 用这些无甲醛或低甲醛粘合剂体系处理的无纺织物具有高强度值和优异的耐溶剂性。

公开(公告)号：US4247438A

公开(公告)日：1981-01-27

申请号：US63082

申请日：1979-08-02

申请人： Herbert Eck ,  Klaus Hafener ,  Hubert Wiest

发明人： Herbert Eck ,  Klaus Hafener ,  Hubert Wiest

IPC分类号： C08F214/00 ,  C08F2/00 ,  C08F2/22 ,  C08F2/24 ,  C08F14/00 ,  C08F210/00 ,  C08F210/02 ,  C08F214/06 ,  C08F218/00 ,  C08F218/02 ,  C08F220/00 ,  C08F220/10 ,  C08L1/00 ,  C08L23/00 ,  C08L27/00 ,  C08L31/00 ,  C08L31/04 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C08L27/06

CPC分类号： C08F214/06 ,  C08F210/02

摘要： Aqueous ethylene/vinyl chloride/vinyl alkanoate and/or alkyl acrylate copolymer dispersions having a non-uniform particle size distribution, in which one particle size distribution maximum is at 0.03 to 0.2.mu. and a second maximum is at 0.15 to 1.mu. and in which 5% to 60% by weight of the particles belong to the amount of particles having said second maximum, which are produced by free-radical polymerization at 0.degree. to 90.degree. C., while stirring, in the presence of emulsifiers which, in amounts of 0.5% to 15% by weight, calculated on the final solid resin, are not added until a polymerization conversion of 1% to 60% by weight of the total amount of monomer has been reached. The copolymer dispersions have solids contents of 20% to 70% by weight of copolymer comprising 20% to 92% by weight of vinyl chloride, 5% to 60% by weight of ethylene and 3% to 75% by weight of vinyl esters and/or acrylic acid esters, and, optionally, up to 15% by weight of other monomers copolymerizable with ethylene and vinyl chloride, said monomers being metered into the polymerization mixture together with the emulsifiers during the manufacturing process.

摘要翻译： 具有不均匀粒度分布的乙烯/氯乙烯/链烷酸乙烯酯水溶液和/或丙烯酸烷基酯共聚物分散体，其中一个粒度分布最大值为0.03至0.2μm，第二个最大值为0.15至1μm，其中 颗粒的5重量％至60重量％属于具有所述第二最大值的颗粒的量，它是在0-90℃自由基聚合反应产生的，同时搅拌，在乳化剂存在下，其量为 在最终固体树脂计算出的重量百分比为0.5％至15％之间，直到达到单体总量的1％至60％重量的聚合转化率为止。 共聚物分散体的固体含量为20重量％至70重量％的共聚物，其包含20重量％至92重量％的氯乙烯，5重量％至60重量％的乙烯和3重量％至75重量％的乙烯基酯和/ 或丙烯酸酯，以及任选地至多15重量％的可与乙烯和氯乙烯共聚的其它单体，所述单体在制造过程中与乳化剂一起计量加入到聚合混合物中。

公开(公告)号：US4098985A

公开(公告)日：1978-07-04

申请号：US718456

申请日：1976-08-30

申请人： Hartmut Brabetz ,  Hubert Wiest ,  Dieter Gorzel

发明人： Hartmut Brabetz ,  Hubert Wiest ,  Dieter Gorzel

IPC分类号： C08F218/04 ,  C08F220/12 ,  C08F226/06

CPC分类号： C08F218/04 ,  C08F220/12

摘要： Ester copolymers cross-linkable under acid, alkaline and heated conditions consisting essentially of a copolymerizate with from 75% to 99% by weight of vinyl and/or acrylic ester monomer units, from 0.2% to 15% by weight of olefinically-unsaturated halotriazine monomer units, from 0.2% to 10% by weight of mono-olefinically unsaturated monomer units containing free or protected N-methylol groups and, optionally, up to 10% by weight of other monomer units copolymerizable with ester monomer units.

公开(公告)号：US4073779A

公开(公告)日：1978-02-14

申请号：US713420

申请日：1976-08-11

申请人： Hubert Wiest ,  Rainer Berger ,  Erwin Lieb

发明人： Hubert Wiest ,  Rainer Berger ,  Erwin Lieb

IPC分类号： C08L23/00 ,  C08F14/00 ,  C08F210/02 ,  C08F214/00 ,  C08F214/06 ,  C08F218/00 ,  C08F218/02 ,  C08F218/04 ,  C08L1/00 ,  C08L27/00 ,  C08L27/06 ,  C08L31/00 ,  C08L31/04 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C09D127/04 ,  C09J123/02 ,  C09J127/04 ,  C09J131/04 ,  C08L23/08

CPC分类号： C08F210/02 ,  C08F214/06 ,  C08F218/04

摘要： A hydrolysis-resistant, film-forming, aqueous dispersion of a copolymer consisting essentially of(a) from 5% to 50% by weight of ethylene units,(b) from 10% to 60% by weight of vinyl alkanoate units having from 1 to 14 carbon atoms in the alkanoate moiety,(c) from 20% to 70% by weight of vinyl chloride units, and(d) from 5% to 30% by weight of alkyl methylacrylate units having from 1 to 8 carbon atoms in the alkyl moiety; as well as the hydrolysis-resistant films produced on drying the above aqueous dispersion having a hydrolysis resistance in a 5.times. 5 cm film having a thickness of 0.1.+-. 0.02 mm, such that after storage for four days in a 25% aqueous sodium hydroxide solution, its weight loss is less than 10%.

摘要翻译： 基本上由（A）5％至50％乙烯单位重量组成的共聚物的抗水解性，成膜性水分散体，（B）10重量％至60重量％，具有1重量份的烷基磺酸乙烯酯单元 （C）乙烯氯化物单位重量的20％至70％，（D）含有1至8个碳原子的甲基丙烯酸甲酯的甲基丙烯酸甲酯重量的5％至30％ 阿尔科 同样也是在5×5厘米薄膜干燥上述水溶性分散体上生产的耐水解胶片，其厚度为0.1 +/- 0.02毫米，如果在25％水溶液中储存四天后 解决方案，其重量损失低于10％。

公开(公告)号：US4035329A

公开(公告)日：1977-07-12

申请号：US633591

申请日：1975-11-19

申请人： Hubert Wiest ,  Josef Hanzalik ,  Wilhelm Lechner ,  Erwin Lieb

发明人： Hubert Wiest ,  Josef Hanzalik ,  Wilhelm Lechner ,  Erwin Lieb

IPC分类号： C08F2/00 ,  C08F2/22 ,  C08F2/24 ,  C08F4/00 ,  C08F4/40 ,  C08F10/00 ,  C08F210/00 ,  C08F210/02 ,  C08F218/00 ,  C08F218/02 ,  C08F218/08 ,  C08L31/04

CPC分类号： C08F218/08 ,  C08F210/02

摘要： A process for the continuous manufacture of an aqueous ethylene/vinyl acetate copolymer dispersion which comprises continuously copolymerizing ethylene and vinyl acetate and optionally other .alpha.-olefinically unsaturated monomers, in an aqueous emulsion in the presence of an emulsifier and/or a protective colloid, and in the presence of a free-radical-forming redox catalyst system of a reducing agent and an oxidizing agent as well, optionally, as a heavy metal salt, and recovering said ethylene/vinyl acetate copolymer dispersion, characterized by (a) the presence of a molar excess of at least 3 times, preferably from 3 to 10 times, said reducing agent over said oxidizing agent dosed into the reaction medium and (b) adding the monomers continuously to the reaction mixture at such a rate that the concentration of unreacted monomers at no place in the reaction zone exceeds 15% by weight of the total weight of the reaction mixture.

摘要翻译： 一种用于连续制造乙烯/乙酸乙烯酯共聚物分散体的方法，其包括在水乳液中在乳化剂和/或保护胶体的存在下连续共聚乙烯和乙酸乙烯酯和任选的其它α-烯烃不饱和单体，以及 在还原剂和氧化剂的自由基形成氧化还原催化剂体系的存在下，任选地，作为重金属盐，并回收所述乙烯/乙酸乙烯酯共聚物分散体，其特征在于（a）存在 摩尔过量为所述还原剂至少3倍，优选3至10倍，所述还原剂超过所述投入到反应介质中的氧化剂，和（b）将所述单体连续加入到反应混合物中，使得未反应单体的浓度 在反应区域的任何地方超过反应混合物总重量的15重量％。

公开(公告)号：US3954687A

公开(公告)日：1976-05-04

申请号：US511248

申请日：1974-10-02

申请人： Hubert Wiest ,  Wilhelm Lechner

发明人： Hubert Wiest ,  Wilhelm Lechner

IPC分类号： C08F2/00 ,  C08F2/22 ,  C08F2/24 ,  C08F18/04 ,  C08J3/02 ,  C08L31/00 ,  C08L31/04 ,  C08L3/02

CPC分类号： C08F18/04

摘要： An improvement in the production of polyvinyl ester dispersions by polymerization of vinyl esters or copolymerization of vinyl esters with up to 40% by weight of oil-soluble, mono-olefinically-unsaturated monomers in an aqueous emulsion in the presence of water-soluble radical-forming polymerization catalysts, protective colloids and optionally emulsifiers and polymerization aids, the improvement comprising using carboxymethyl celluloses having a substitution degree of at least 10 as said protective colloids; as well as stable mixtures of the said polyvinyl ester dispersions and dextrin.

摘要翻译： 通过乙烯基酯的聚合或乙烯基酯与水溶性单烯属不饱和单体在水溶性单烯属不饱和单体中的存在下，在水溶性基团 - 形成聚合催化剂，保护胶体和任选的乳化剂和聚合助剂，改进包括使用取代度至少为10的羧甲基纤维素作为所述保护胶体; 以及所述聚乙烯酯分散体和糊精的稳定混合物。