摘要:
The present invention generally relates to polyurethanes and polyurethane nanocomposites having improved mechanical, rheological, and thermal properties over ordinarily produced polyurethanes and polyurethane nanocomposites. Such polyurethanes and polyurethane nanocomposites include very small amounts of a small chain diol, such as glycerol, and more specifically, between 0.01 and 4 weight percent of the small chain diol, based on the total polymer composition.
摘要:
A vent cover assembly is disclosed, such as for a floating or fixed floor. Example vent cover assemblies may include a support plate configured to be secured over a duct, and a flush mount vent cover. The support plate may define a plurality of first airflow apertures configured to permit airflow from the duct through the support plate. The vent cover may define a second plurality of airflow apertures that are positioned in the vent cover such that the second plurality of airflow apertures are aligned with the first airflow apertures when the vent cover is in a first installed position overlying the support plate. The vent cover may obstruct the first airflow apertures when the vent cover is in a second installed position overlying the support plate.
摘要:
A vent cover assembly is disclosed, such as for a floating or fixed floor. Example vent cover assemblies may include a support plate configured to be secured over a duct, and a flush mount vent cover. The support plate may define a plurality of first airflow apertures configured to permit airflow from the duct through the support plate. The vent cover may define a second plurality of airflow apertures that are positioned in the vent cover such that the second plurality of airflow apertures are aligned with the first airflow apertures when the vent cover is in a first installed position overlying the support plate. The vent cover may obstruct the first airflow apertures when the vent cover is in a second installed position overlying the support plate.
摘要:
Sulfur containing, hydroxyl-telechelic PIBs, hydrolytically and oxidatively resistant, biocompatible and biostable polyurethanes (PUs) made therefrom, and methods for making both are disclosed. Well-defined hydroxyl telechelic PIBs are synthesized by a thiol-ene click photochemical reaction between PIBs carrying unsaturated end groups and 2-mercaptoethanol (HS—CH2CH2—OH). This regioselective process affords HO—CH2CH2—S-PIB-S—CH2CH2—OH (abbreviated herein as HO—S-PIB-S—OH) in high yield. In some embodiments, these HO—S-PIB-S—OH polymers may be reacted with diisocyanates and a chain extender to form sulfur containing PIB-based PUs. These sulfur containing PIB-based PUs have been found to have properties and chemical stability that are very similar to that of PUs made from di-hydroxyl terminated PIBs (OH-PIB-OHs) without sulfur, but have surprisingly increased creep resistance and are easier and less expensive to make.
摘要:
A PIB-based polymer network includes at least one sulfur containing segment and at least two PIB polymer segments. The at least two PIB polymer segments each include a core and at least two polyisobutylene polymer chains extending therefrom. The at least one sulfur containing segment includes at least one sulfur atom that is located between any two polyisobutylene polymer chains from two different PIB polymer segments, so that the sulfur containing segment connects those two different PIB polymer segments together. The PIB-based polymer network is produced by the thiol-ene reaction in the presence of light or heat. The reaction products include at least two polyisobutylene polymer precursor moieties, each polyisobutylene polymer precursor moiety having at least two end group selected from the end groups —CH2—CH(CH3)═CH2, —CH2═C(CH3)2, and —CH2—CH═CH2; and at least one multi-functional thiol.
摘要:
The present invention relates to novel hydroxyl-terminated polyisobutylenes and methods of making and using them. The hydroxyl-terminated polyisobutylenes contain a sulfur unit, —S—, within each terminal end group. The well-defined, sulfur containing, primary hydroxyl-terminated polyisobutylenes of the present invention can be simply, rapidly, and essentially quantitatively obtained by subjecting the unsaturated telechelic PIBs and mercapto alcohols to UV light-activated thiol-ene reactions. The resultant sulfur containing, primary hydroxyl-terminated polyisobutylenes can then be used in the production of polyurethanes and like materials.
摘要:
The present invention is generally directed to a new class of TPEs made from peptide terminated low Tg polymers and methods for making them. The middle block of these TPE is a telechelic polymer with a Tg that is below the intended service temperature of the TPE. The terminal peptide segments of these TPEs are short (from about 1 to about 10 amino acids long) and tend to from sheet type secondary structures through intermolecular hydrogen bonds, creating physical crosslinks between polymer chains. The dissimilarity of the peptide hard component and the elastomeric soft component results in very strong segregation between the microphase domains and a low plastic deformation for the resulting TPE. And since the Tm of the crystalline peptide phase can be adjusted, these new TPEs may be tailored to fit the intended service temperature and are melt-processable.
摘要:
A polymer conetwork formed from the polymerization reaction of octyl-cyanoacrylate and a tri-telechelic star polymer comprising polyisobutylene terminated with cyanoacrylate groups (Ø(PIB-CA)3), wherein the ratio of octyl cyanoacrylate to Ø(PIB-CA)3 is from about 10:1 to about 40:1.
摘要:
A polyurea or polyurea-urethane elastomer comprises a soft polymer segment and a hard polymer segment, wherein the hard polymer segment includes polyurea groups in combination with H-bond accepting chain extenders (HACEs) to reduce the flow temperature (Tflow) while maintaining the excellent mechanical properties such that the resulting polyurea elatomer is rendered melt-processable.
摘要:
For one disclosed embodiment, an integrated circuit may comprise an internal transmission line in one or more layers of the integrated circuit. The internal transmission line may be coupled to receive a signal from an external transmission line at a first end of the internal transmission line without use of termination circuitry. The internal transmission line may transmit the signal passively to a second end of the internal transmission line. The integrated circuit may also comprise first circuitry having an input coupled to the internal transmission line at a first location of the internal transmission line to receive the signal and second circuitry having an input coupled to the internal transmission line at a second location of the internal transmission line to receive the signal. The second location may be different from the first location. Other embodiments are also disclosed.