公开(公告)号：US09321973B2

公开(公告)日：2016-04-26

申请号：US13996762

申请日：2011-12-15

申请人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G47/00 ,  B01J27/186 ,  B01J27/19 ,  C10G47/12 ,  B01J29/04 ,  B01J35/00 ,  B01J35/10 ,  B01J37/10 ,  C10G65/12 ,  C10G3/00 ,  B01J27/188 ,  B01J27/195 ,  B01J27/198 ,  B01J37/20

CPC分类号： C10G47/12 ,  B01J27/186 ,  B01J27/19 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4018 ,  Y02P30/20

摘要： A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HhXxMmOy)q−, said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.

摘要翻译： 一种用于加氢裂化含烃原料的方法，其中至少50重量％的化合物的起始沸点高于340℃，最终沸点低于540℃，使用其氧化物中的催化剂 形成选自VIB族，VIII族和VB族金属中的至少一种金属，所述金属以至少一种式（HhXxMmOy）q-的多金属氧酸盐的形式存在，所述多金属氧酸盐存在于介孔结构基质中，基于 至少一个元素Y，所述基质的孔径在1.5至50nm之间并具有1至30nm厚度的非晶壁，所述催化剂在用于所述方法之前被硫化。

公开(公告)号：US20140183100A1

公开(公告)日：2014-07-03

申请号：US13995800

申请日：2011-12-15

申请人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G45/10 ,  C10G45/04

CPC分类号： C10G45/10 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/20 ,  C10G45/04 ,  C10G45/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2400/02

摘要： The invention relates to a process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus (P), silicon (Si), boron (B), nickel (Ni) and cobalt (Co), the said element being taken alone, M is one or more element(s) selected from molybdenum (Mo), tungsten (W), nickel (Ni) and cobalt (Co), O is oxygen, H is hydrogen, h is an integer within the range 0 to 12, x is an integer within the range 0 to 4, m is an integer equal to 5, 6, 7, 8, 9, 10, 11, 12 and 18, y is an integer within the range 17 to 72 and q is an integer within the range 1 to 20, the said polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size within the range 1.5 to 50 nm and having amorphous walls of thickness within the range 1 to 30 nm, the said catalyst being sulphured before being implemented in the said process.

摘要翻译： 本发明涉及至少一种汽油馏分的加氢脱硫方法，其实施催化剂，其以其氧化物形式包含至少一种来自元素周期表的VIB族金属和/或至少一种来自元素周期第Ⅷ族的金属，其形式为 的至少一种式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷（P），硅（Si），硼（B），镍（Ni）和钴（Co）的元素，所述元素为 单独使用时，M是选自钼（Mo），钨（W），镍（Ni）和钴（Co）中的一种或多种元素，O为氧，H为氢，h为0 至12，x为0至4范围内的整数，m为等于5,6,7,8,9,10,11,12和18的整数，y为17至72的整数，q为 是1至20范围内的整数，所述多金属氧酸盐存在于孔径在1.5至50nm范围内且具有厚度的无定形壁的介孔结构氧化硅基质中 s在1至30nm的范围内，所述催化剂在被实施在所述方法之前被硫化。

公开(公告)号：US20130334099A1

公开(公告)日：2013-12-19

申请号：US13996762

申请日：2011-12-15

申请人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G47/12

CPC分类号： C10G47/12 ,  B01J27/186 ,  B01J27/19 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4018 ,  Y02P30/20

摘要： A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HhXxMmOy)q−, said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.

摘要翻译： 一种用于加氢裂化含烃原料的方法，其中至少50重量％的化合物的起始沸点高于340℃，最终沸点低于540℃，使用其氧化物中的催化剂 形成选自VIB族，VIII族和VB族金属中的至少一种金属，所述金属以至少一种式（HhXxMmOy）q-的多金属氧酸盐的形式存在，所述多金属氧酸盐存在于介孔结构基质中，基于 至少一个元素Y，所述基质的孔径在1.5至50nm之间并具有1至30nm厚度的非晶壁，所述催化剂在用于所述方法之前被硫化。

公开(公告)号：US20130186806A1

公开(公告)日：2013-07-25

申请号：US13813016

申请日：2011-06-24

申请人： Fabrice Diehl ,  Elodie Devers ,  Karin Marchand ,  Bertrand Guichard

发明人： Fabrice Diehl ,  Elodie Devers ,  Karin Marchand ,  Bertrand Guichard

IPC分类号： B01J27/19 ,  C10G45/10 ,  C10G45/08

CPC分类号： B01J27/19 ,  B01J21/04 ,  B01J23/652 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/94 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/086 ,  B01J37/20 ,  B01J38/14 ,  C10G45/08 ,  C10G45/10 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04

摘要： Preparation of a catalyst having at least one metal from group VIII, at least one metal from group VIB and at least one support; in succession: i) one of i1) contacting a pre-catalyst with metal from group VIII, metal from group VIB and support with a cyclic oligosaccharide naming at least 6 α-(1,4)-bonded glucopyranose subunits; i2) contacting support with a solution containing a precursor of metal from group VIII, a precursor of said metal from group VIB and a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; or i3) contacting support with a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits followed by contacting solid derived therefrom with a precursor of metal from group VIII and a precursor of metal from group VIB.

摘要翻译： 制备具有至少一种来自第VIII族的金属的催化剂，至少一种来自VIB族的金属和至少一种载体; i）i）使预催化剂与VIII族金属，VIB族金属接触，并与至少6个α-（1,4）键的吡喃葡萄糖亚基命名的环状低聚糖进行支持; i2）使载体与含有VIII族金属的前体的溶液接触，所述VIB族的所述金属的前体和由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状寡糖; 或i3）使支持物与由至少6个α-（1,4） - 键合的吡喃葡萄糖亚基组成的环状寡糖接触，然后将从其衍生的固体与来自VIII族的金属前体和来自VIB族的金属前体接触。

公开(公告)号：US08435912B2

公开(公告)日：2013-05-07

申请号：US12375757

申请日：2007-07-06

申请人： Alexandra Chaumonnot ,  Denis Guillaume ,  Benoit Fremon ,  Karin Marchand ,  Renaud Revel

发明人： Alexandra Chaumonnot ,  Denis Guillaume ,  Benoit Fremon ,  Karin Marchand ,  Renaud Revel

IPC分类号： C10G45/00

CPC分类号： B01J31/0269 ,  B01J21/12 ,  B01J23/20 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  B01J23/882 ,  B01J31/0274 ,  B01J37/20 ,  C10G49/02

摘要： A supported and sulphur-containing catalyst is described, comprising; a porous support constituted by an organic-inorganic hybrid material for which the covalent bond between the organic and inorganic phases conforms to the formula M-O—Z—R where M represents at least one metal constituting the inorganic phase, Z at least one heteroelement from among phosphorus and silicon and R an organic fragment, at least one metal of group VIB and/or of group VB and/or of group VIII. The invention also relates to the use of this catalyst for the hydrorefining and the hydroconversion of hydrocarbon-containing feedstocks such as petroleum fractions, fractions from coal or biomass or hydrocarbons produced from natural gas.

摘要翻译： 描述了负载型和含硫催化剂，其包含： 由有机和无机相之间的共价键符合式MOZR，其中M表示至少一种构成无机相的金属，Z至少一种来自磷和硅的杂质元素和 R是有机片段，至少一种VIB族金属和/或VB族和/或VIII族金属。 本发明还涉及该催化剂用于加氢精制和加氢转化含烃原料如石油馏分，来自煤或生物质的馏分或天然气生产的烃。

公开(公告)号：US08110091B2

公开(公告)日：2012-02-07

申请号：US11963231

申请日：2007-12-21

申请人： Thierry Chapus ,  Karin Marchand

发明人： Thierry Chapus ,  Karin Marchand

IPC分类号： C10G65/12

CPC分类号： C10G65/12 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G3/54 ,  C10G45/02 ,  C10G45/08 ,  C10G2300/1003 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/04 ,  Y02P30/20

摘要： The invention relates to a process for the treatment of heavy petroleum feedstocks in order to produce a gas oil fraction having a sulphur content of less than 50 ppm and generally 10 ppm which comprises the following stages: e) mild hydrocracking in a catalyst fixed bed, f) separation of the hydrogen sulphide, of a distillate cut including a gas oil fraction and of a fraction which is heavier than the gas oil, g) hydrotreating, by contact with at least one catalyst, of at least a portion of the distillate cut obtained in stage b) including the gas oil fraction, as a mixture with a feedstock resulting from a crude or refined renewable source, h) separation of a gas oil cut comprising less than 50 ppm of sulphur. Advantageously, the heavy fraction is sent for catalytic cracking. Preferably, the process is carried out with makeup hydrogen introduced in stage c) and very advantageously all the makeup hydrogen for the process is introduced in stage c). The invention also relates to a plant which can be used for implementing this process.

摘要翻译： 本发明涉及一种用于处理重质石油原料的方法，以生产硫含量小于50ppm，通常为10ppm的瓦斯油馏分，其包括以下阶段：e）催化剂固定床中的轻度加氢裂化， f）硫化氢分离，包括粗柴油馏分和比瓦斯油重的馏分馏出物，g）通过与至少一种催化剂接触至少部分馏出物馏分进行加氢处理 在步骤b）中获得的，包括粗柴油馏分作为与原油或精制可再生来源产生的原料的混合物，h）分离包含少于50ppm硫的瓦斯油馏分。 有利地，将重馏分送入催化裂化。 优选地，通过在阶段c）中引入的补充氢来进行该方法，并且非常有利地，用于该方法的所有补充氢在阶段c）中引入。 本发明还涉及可用于实施该方法的设备。

公开(公告)号：US20080161614A1

公开(公告)日：2008-07-03

申请号：US11962760

申请日：2007-12-21

申请人： Fabrice Bertoncini ,  Karin Marchand

发明人： Fabrice Bertoncini ,  Karin Marchand

IPC分类号： C07C1/00

CPC分类号： C10G65/04 ,  C10G3/46 ,  C10G3/50 ,  C10G3/54 ,  C10G45/08 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1044 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/42 ,  Y02P30/20

摘要： The invention relates to a hydrotreating method (HDT) using two plants working under different operating conditions with an intermediate stripping for co-treating a mixture made up of oils of vegetable or animal origin and petroleum cuts (gas oil cuts (GO) and middle distillates) in order to produce gas oil fuel bases meeting specifications. The first plant (HDT1) is more particularly dedicated to the reactions concerning oils of vegetable or animal origin in comixture while pretreating the hydrocarbon feed, whereas the second plant (HDS2) works under more severe conditions to obtain diesel fuel according to standards, in particular in terms of effluent sulfur content, density and cold properties. The process economy, the activity and the stability of the catalyst of the second plant are greatly improved by the intermediate stripping.

摘要翻译： 本发明涉及使用两种在不同操作条件下工作的植物的加氢处理方法（HDT），其中间剥离剂用于共同处理由植物或动物来源的油组成的混合物和石油馏分（瓦斯油馏分（GO））和中间馏分 ），以生产满足规格的瓦斯油燃料基地。 第一种植物（HDT 1）更特别致力于在预处理烃类饲料的过程中，以混合物为原料的植物或动物来源的反应，而第二种植物（HDS 2）在更苛刻的条件下，按照标准获得柴油， 特别是在流出物硫含量，密度和冷特性方面。 第二工厂催化剂的工艺经济性，活性和稳定性大大提高。

公开(公告)号：US09376636B2

公开(公告)日：2016-06-28

申请号：US13995800

申请日：2011-12-15

申请人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G45/04 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  C10G45/10 ,  B01J29/03 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  C10G45/06 ,  B01J27/195 ,  B01J27/198

CPC分类号： C10G45/10 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/20 ,  C10G45/04 ,  C10G45/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2400/02

摘要： A process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus, silicon, boron, nickel and cobalt, M is one or more element(s) selected from molybdenum, tungsten, nickel and cobalt, h is an integer from 0-12, x is an integer from 0-4, m is an integer 5, 6, 7, 8, 9, 10, 11, 12 and/or 18, y is an integer of 17-72 and q is an integer of 1-20, the polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size of 1.5-50 nm and having amorphous walls of thickness 1-30 nm, the catalyst being sulphured before use in the process.

摘要翻译： 至少一种汽油切割加氢脱硫的方法，其实施催化剂，其以其氧化物形式包含至少一种以至少一种形式存在的来自VIB族组分和/或至少一种来自元素周期表Ⅷ族的金属的金属 式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷，硅，硼，镍和钴的元素，M是选自钼，钨，镍和钴的一种或多种元素，h是整数 从0-12，x是0-4的整数，m是整数5,6,7,8,9,10,11,12和/或18，y是17-72的整数，q是 整数为1-20，多金属氧酸盐存在于孔径为1.5-50nm的介孔结构的氧化硅基质中，并且具有厚度为1-30nm的无定形壁，催化剂在该方法使用前被硫化。

公开(公告)号：US07781629B2

公开(公告)日：2010-08-24

申请号：US11962770

申请日：2007-12-21

申请人： Karin Marchand ,  Fabrice Bertoncini

发明人： Karin Marchand ,  Fabrice Bertoncini

IPC分类号： C07C1/00 ,  C10G25/00

CPC分类号： C10G3/50 ,  C10G3/46 ,  C10G3/54 ,  C10G45/02 ,  C10G45/08 ,  C10G49/002 ,  C10G65/04 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1044 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/42 ,  Y02P30/20

摘要： A hydrotreating method uses two catalyst beds with the introduction, on the last catalyst bed, of oils of animal or vegetable origin for co-treating a mixture made up of oils of vegetable or animal origin and of petroleum cuts (gas oil cuts (GO) and middle distillates) in order to produce gas oil effluents meeting specifications with an improved cetane number. The first catalyst bed is dedicated to only the deep desulfurization reactions (HDS1) of a petroleum type feed. The effluents of the first catalyst bed having an effluent sulfur content below or equal to 50 mg/kg are separated into two streams. The first stream, which is predominant, is sent to the gas oil pool. The second stream is mixed with oils of vegetable or animal origin. The resultant oil-petroleum cut mixture is then subjected to a milder hydrotreatment (HDT2). The effluents obtained at the outlet of the second catalyst bed can optionally be mixed with the predominant stream from the first bed. The process economy, the tolerance to the specifications relative to oils of animal or vegetable origin and the quality of the products obtained are thus greatly improved.

摘要翻译： 加氢处理方法使用两个催化剂床，在最后的催化剂床上引入动物或植物来源的油，用于共同处理由植物或动物来源的油组成的混合物和油馏分（瓦斯油馏分（GO） 和中间馏分），以生产满足具有改进的十六烷值的规格的瓦斯油废水。 第一个催化剂床仅用于石油类饲料的深度脱硫反应（HDS1）。 流出物硫含量低于或等于50mg / kg的第一催化剂床的流出物被分成两股。 主要的第一流被送到瓦斯油池。 第二流与植物或动物来源的油混合。 然后将所得油 - 石油馏分混合物进行较温和的加氢处理（HDT2）。 在第二催化剂床的出口处获得的流出物可以任选地与来自第一床的主要流混合。 因此，过程经济性，相对于动植物来源的油的规格的容忍度和获得的产品的质量大大提高。

公开(公告)号：US07935244B2

公开(公告)日：2011-05-03

申请号：US12076237

申请日：2008-03-14

申请人： Magalie Roy-Auberger ,  Denis Guillaume ,  Karin Marchand

发明人： Magalie Roy-Auberger ,  Denis Guillaume ,  Karin Marchand

IPC分类号： C10G47/02

CPC分类号： B01J37/038 ,  B01J23/882 ,  B01J23/883 ,  B01J27/188 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/108 ,  B01J35/12 ,  B01J37/12 ,  B01J37/20 ,  C10G45/08 ,  C10G45/16 ,  C10G49/04 ,  C10G49/12

摘要： The invention concerns a process for slurry phase hydroconversion of liquid sulphur-containing heavy hydrocarbon feeds, in the presence of hydrogen and in the presence of a solid catalyst, said catalyst being obtained from an aqueous solution formed from at least one cobalt and/or nickel salt of at least one heteropolyanion combining molybdenum and cobalt or molybdenum and nickel in its structure. The aqueous solution is introduced into a hydrocarbon oil containing asphaltenes and/or resins to form an emulsion and said emulsion is then injected upstream or directly into the slurry reactor.

摘要翻译： 本发明涉及一种用于在氢存在下和在固体催化剂存在下，液体含硫重烃进料的淤浆相加氢转化的方法，所述催化剂由至少一种钴和/或镍形成的水溶液获得 至少一个结合钼和钴或钼和镍的杂多阴离子的盐。 将水溶液引入含有沥青质和/或树脂的烃油中以形成乳液，然后将所述乳液上游或直接注入到浆料反应器中。