公开(公告)号：US20100133147A1

公开(公告)日：2010-06-03

申请号：US12375757

申请日：2007-07-06

申请人： Alexandra Chaumonnot ,  Denis Guillaume ,  Benoit Fremon ,  Karin Marchand ,  Renaud Revel

发明人： Alexandra Chaumonnot ,  Denis Guillaume ,  Benoit Fremon ,  Karin Marchand ,  Renaud Revel

IPC分类号： C10G45/00 ,  B01J31/12 ,  B01J31/02

CPC分类号： B01J31/0269 ,  B01J21/12 ,  B01J23/20 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  B01J23/882 ,  B01J31/0274 ,  B01J37/20 ,  C10G49/02

摘要： A supported and sulphur-containing catalyst is described, comprising; a porous support constituted by an organic-inorganic hybrid material for which the covalent bond between the organic and inorganic phases conforms to the formula M-O—Z—R where M represents at least one metal constituting the inorganic phase, Z at least one heteroelement from among phosphorus and silicon and R an organic fragment, at least one metal of group VIB and/or of group VB and/or of group VIII. The invention also relates to the use of this catalyst for the hydrorefining and the hydroconversion of hydrocarbon-containing feedstocks such as petroleum fractions, fractions from coal or biomass or hydrocarbons produced from natural gas.

摘要翻译： 描述了负载型和含硫催化剂，其包含： 由有机和无机相之间的共价键符合式MO-Z-R的有机 - 无机杂化材料构成的多孔载体，其中M表示构成无机相的至少一种金属，Z至少一种来自 磷和硅，R是有机片段，至少一种VIB族金属和/或VB族和/或VIII族金属。 本发明还涉及该催化剂用于加氢精制和加氢转化含烃原料如石油馏分，来自煤或生物质的馏分或天然气生产的烃。

公开(公告)号：US08435912B2

公开(公告)日：2013-05-07

申请号：US12375757

申请日：2007-07-06

申请人： Alexandra Chaumonnot ,  Denis Guillaume ,  Benoit Fremon ,  Karin Marchand ,  Renaud Revel

发明人： Alexandra Chaumonnot ,  Denis Guillaume ,  Benoit Fremon ,  Karin Marchand ,  Renaud Revel

IPC分类号： C10G45/00

CPC分类号： B01J31/0269 ,  B01J21/12 ,  B01J23/20 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  B01J23/882 ,  B01J31/0274 ,  B01J37/20 ,  C10G49/02

摘要： A supported and sulphur-containing catalyst is described, comprising; a porous support constituted by an organic-inorganic hybrid material for which the covalent bond between the organic and inorganic phases conforms to the formula M-O—Z—R where M represents at least one metal constituting the inorganic phase, Z at least one heteroelement from among phosphorus and silicon and R an organic fragment, at least one metal of group VIB and/or of group VB and/or of group VIII. The invention also relates to the use of this catalyst for the hydrorefining and the hydroconversion of hydrocarbon-containing feedstocks such as petroleum fractions, fractions from coal or biomass or hydrocarbons produced from natural gas.

摘要翻译： 描述了负载型和含硫催化剂，其包含： 由有机和无机相之间的共价键符合式MOZR，其中M表示至少一种构成无机相的金属，Z至少一种来自磷和硅的杂质元素和 R是有机片段，至少一种VIB族金属和/或VB族和/或VIII族金属。 本发明还涉及该催化剂用于加氢精制和加氢转化含烃原料如石油馏分，来自煤或生物质的馏分或天然气生产的烃。

公开(公告)号：US09376636B2

公开(公告)日：2016-06-28

申请号：US13995800

申请日：2011-12-15

申请人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G45/04 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  C10G45/10 ,  B01J29/03 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  C10G45/06 ,  B01J27/195 ,  B01J27/198

CPC分类号： C10G45/10 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/20 ,  C10G45/04 ,  C10G45/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2400/02

摘要： A process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus, silicon, boron, nickel and cobalt, M is one or more element(s) selected from molybdenum, tungsten, nickel and cobalt, h is an integer from 0-12, x is an integer from 0-4, m is an integer 5, 6, 7, 8, 9, 10, 11, 12 and/or 18, y is an integer of 17-72 and q is an integer of 1-20, the polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size of 1.5-50 nm and having amorphous walls of thickness 1-30 nm, the catalyst being sulphured before use in the process.

摘要翻译： 至少一种汽油切割加氢脱硫的方法，其实施催化剂，其以其氧化物形式包含至少一种以至少一种形式存在的来自VIB族组分和/或至少一种来自元素周期表Ⅷ族的金属的金属 式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷，硅，硼，镍和钴的元素，M是选自钼，钨，镍和钴的一种或多种元素，h是整数 从0-12，x是0-4的整数，m是整数5,6,7,8,9,10,11,12和/或18，y是17-72的整数，q是 整数为1-20，多金属氧酸盐存在于孔径为1.5-50nm的介孔结构的氧化硅基质中，并且具有厚度为1-30nm的无定形壁，催化剂在该方法使用前被硫化。

公开(公告)号：US20140005031A1

公开(公告)日：2014-01-02

申请号：US13995508

申请日：2011-12-15

申请人： Alexandra Chaumonnot ,  Clement Sanchez ,  Cedric Boissiere ,  Frederic Colbeau-Justin ,  Karin Marchand ,  Elodie Devers ,  Audrey Bonduelle ,  Denis Uzio ,  Antoine Daudin ,  Bertrand Guichard ,  Denis Uzio ,  Antoine Daudin

发明人： Alexandra Chaumonnot ,  Clement Sanchez ,  Cedric Boissiere ,  Frederic Colbeau-Justin ,  Karin Marchand ,  Elodie Devers ,  Audrey Bonduelle ,  Denis Uzio ,  Antoine Daudin ,  Bertrand Guichard ,  Denis Uzio ,  Antoine Daudin

IPC分类号： B01J27/199 ,  B01J27/19 ,  B01J27/188 ,  B01J23/882

CPC分类号： B01J27/199 ,  B01J23/882 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  C01B37/00 ,  C01B37/005 ,  C01B37/02 ,  C01B39/04 ,  C01B39/06 ,  C10G3/45 ,  C10G3/46 ,  C10G3/48 ,  C10G3/49 ,  C10G3/50 ,  C10G45/06 ,  C10G47/12 ,  C10G2300/1011 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/06 ,  C10L1/04 ,  C10L1/06 ,  C10L1/08 ,  Y02P30/10 ,  Y02P30/20

摘要： Inorganic material having at least two elementary spherical particles, each of said spherical metallic particles: a polyoxometallate with formula (XxMmOyHh)q−, where H is hydrogen, O is oxygen, X is phosphorus, silicon, boron, nickel or cobalt and M is one or more vanadium, niobium, tantalum, molybdenum, tungsten, iron, copper, zinc, cobalt and nickel, x is 0, 1, 2 or 4, m is 5, 6, 7, 8, 9, 10, 11, 12 or 18, y is 17 to 72, h is 0 to 12 and q is 1 to 20.

摘要翻译： 具有至少两个基本球形颗粒的无机材料，每个所述球形金属颗粒：具有式（XxMmOyHh）q-的多金属氧酸盐，其中H是氢，O是氧，X是磷，硅，硼，镍或钴，M是 一种或多种钒，铌，钽，钼，钨，铁，铜，锌，钴和镍，x为0,1,2或4，m为5,6,7,8,9,10,11,12 或18，y为17〜72，h为0〜12，q为1〜20。

公开(公告)号：US09321973B2

公开(公告)日：2016-04-26

申请号：US13996762

申请日：2011-12-15

申请人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G47/00 ,  B01J27/186 ,  B01J27/19 ,  C10G47/12 ,  B01J29/04 ,  B01J35/00 ,  B01J35/10 ,  B01J37/10 ,  C10G65/12 ,  C10G3/00 ,  B01J27/188 ,  B01J27/195 ,  B01J27/198 ,  B01J37/20

CPC分类号： C10G47/12 ,  B01J27/186 ,  B01J27/19 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4018 ,  Y02P30/20

摘要： A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HhXxMmOy)q−, said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.

摘要翻译： 一种用于加氢裂化含烃原料的方法，其中至少50重量％的化合物的起始沸点高于340℃，最终沸点低于540℃，使用其氧化物中的催化剂 形成选自VIB族，VIII族和VB族金属中的至少一种金属，所述金属以至少一种式（HhXxMmOy）q-的多金属氧酸盐的形式存在，所述多金属氧酸盐存在于介孔结构基质中，基于 至少一个元素Y，所述基质的孔径在1.5至50nm之间并具有1至30nm厚度的非晶壁，所述催化剂在用于所述方法之前被硫化。

公开(公告)号：US20140183100A1

公开(公告)日：2014-07-03

申请号：US13995800

申请日：2011-12-15

申请人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G45/10 ,  C10G45/04

CPC分类号： C10G45/10 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/20 ,  C10G45/04 ,  C10G45/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2400/02

摘要： The invention relates to a process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus (P), silicon (Si), boron (B), nickel (Ni) and cobalt (Co), the said element being taken alone, M is one or more element(s) selected from molybdenum (Mo), tungsten (W), nickel (Ni) and cobalt (Co), O is oxygen, H is hydrogen, h is an integer within the range 0 to 12, x is an integer within the range 0 to 4, m is an integer equal to 5, 6, 7, 8, 9, 10, 11, 12 and 18, y is an integer within the range 17 to 72 and q is an integer within the range 1 to 20, the said polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size within the range 1.5 to 50 nm and having amorphous walls of thickness within the range 1 to 30 nm, the said catalyst being sulphured before being implemented in the said process.

摘要翻译： 本发明涉及至少一种汽油馏分的加氢脱硫方法，其实施催化剂，其以其氧化物形式包含至少一种来自元素周期表的VIB族金属和/或至少一种来自元素周期第Ⅷ族的金属，其形式为 的至少一种式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷（P），硅（Si），硼（B），镍（Ni）和钴（Co）的元素，所述元素为 单独使用时，M是选自钼（Mo），钨（W），镍（Ni）和钴（Co）中的一种或多种元素，O为氧，H为氢，h为0 至12，x为0至4范围内的整数，m为等于5,6,7,8,9,10,11,12和18的整数，y为17至72的整数，q为 是1至20范围内的整数，所述多金属氧酸盐存在于孔径在1.5至50nm范围内且具有厚度的无定形壁的介孔结构氧化硅基质中 s在1至30nm的范围内，所述催化剂在被实施在所述方法之前被硫化。

公开(公告)号：US20130334099A1

公开(公告)日：2013-12-19

申请号：US13996762

申请日：2011-12-15

申请人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G47/12

CPC分类号： C10G47/12 ,  B01J27/186 ,  B01J27/19 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4018 ,  Y02P30/20

摘要： A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HhXxMmOy)q−, said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.

摘要翻译： 一种用于加氢裂化含烃原料的方法，其中至少50重量％的化合物的起始沸点高于340℃，最终沸点低于540℃，使用其氧化物中的催化剂 形成选自VIB族，VIII族和VB族金属中的至少一种金属，所述金属以至少一种式（HhXxMmOy）q-的多金属氧酸盐的形式存在，所述多金属氧酸盐存在于介孔结构基质中，基于 至少一个元素Y，所述基质的孔径在1.5至50nm之间并具有1至30nm厚度的非晶壁，所述催化剂在用于所述方法之前被硫化。

公开(公告)号：US07935244B2

公开(公告)日：2011-05-03

申请号：US12076237

申请日：2008-03-14

申请人： Magalie Roy-Auberger ,  Denis Guillaume ,  Karin Marchand

发明人： Magalie Roy-Auberger ,  Denis Guillaume ,  Karin Marchand

IPC分类号： C10G47/02

CPC分类号： B01J37/038 ,  B01J23/882 ,  B01J23/883 ,  B01J27/188 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/108 ,  B01J35/12 ,  B01J37/12 ,  B01J37/20 ,  C10G45/08 ,  C10G45/16 ,  C10G49/04 ,  C10G49/12

摘要： The invention concerns a process for slurry phase hydroconversion of liquid sulphur-containing heavy hydrocarbon feeds, in the presence of hydrogen and in the presence of a solid catalyst, said catalyst being obtained from an aqueous solution formed from at least one cobalt and/or nickel salt of at least one heteropolyanion combining molybdenum and cobalt or molybdenum and nickel in its structure. The aqueous solution is introduced into a hydrocarbon oil containing asphaltenes and/or resins to form an emulsion and said emulsion is then injected upstream or directly into the slurry reactor.

摘要翻译： 本发明涉及一种用于在氢存在下和在固体催化剂存在下，液体含硫重烃进料的淤浆相加氢转化的方法，所述催化剂由至少一种钴和/或镍形成的水溶液获得 至少一个结合钼和钴或钼和镍的杂多阴离子的盐。 将水溶液引入含有沥青质和/或树脂的烃油中以形成乳液，然后将所述乳液上游或直接注入到浆料反应器中。

公开(公告)号：US20080020926A1

公开(公告)日：2008-01-24

申请号：US11878308

申请日：2007-07-23

申请人： Denis Guillaume ,  Edmond Payen ,  Carole Lamonier ,  Karin Marchand

发明人： Denis Guillaume ,  Edmond Payen ,  Carole Lamonier ,  Karin Marchand

IPC分类号： B01J23/28

CPC分类号： B01J23/882 ,  B01J21/04 ,  B01J23/002 ,  B01J23/883 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0213 ,  B01J37/08 ,  B01J37/12 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G45/12 ,  B01J2523/68 ,  B01J2523/845 ,  B01J2523/847

摘要： A process is described for preparing a solution formed by at least one cobalt and/or nickel salt of at least one heteropolyanion combining molybdenum and cobalt or molybdenum and nickel in its structure, said process comprising: a) mixing at least one source of molybdenum and at least one oxidizing compound in aqueous solution to synthesize peroxomolybdate ions at an acidic pH, the (oxidizing compound/molybdenum source) mole ratio being in the range 0.1 to 20; b) introducing at least one cobalt precursor and/or at least one nickel precursor into the solution from step a) to form a solution comprising at least said salt in which the (Co+Ni)/Mo mole ratio is in the range 0.25 to 0.85.

摘要翻译： 描述了一种制备由至少一种结合钼和钴或钼和镍的杂多阴离子的至少一种钴和/或镍盐形成的溶液的方法，所述方法包括：a）将至少一种钼源和 至少一种氧化性化合物在水溶液中，在酸性pH下合成过氧钼酸根离子，（氧化化合物/钼源）的摩尔比在0.1至20的范围内; b）将至少一种钴前体和/或至少一种镍前体引入到步骤a）的溶液中以形成至少包含所述盐的溶液，其中（Co + Ni）/ Mo摩尔比在0.25至 0.85。

公开(公告)号：US07687430B2

公开(公告)日：2010-03-30

申请号：US11878308

申请日：2007-07-23

申请人： Denis Guillaume ,  Edmond Payen ,  Carole Lamonier ,  Karin Marchand

发明人： Denis Guillaume ,  Edmond Payen ,  Carole Lamonier ,  Karin Marchand

IPC分类号： B01J23/00

CPC分类号： B01J23/882 ,  B01J21/04 ,  B01J23/002 ,  B01J23/883 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0213 ,  B01J37/08 ,  B01J37/12 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G45/12 ,  B01J2523/68 ,  B01J2523/845 ,  B01J2523/847

摘要： A process is described for preparing a solution formed by at least one cobalt and/or nickel salt of at least one heteropolyanion combining molybdenum and cobalt or molybdenum and nickel in its structure, said process comprising: a) mixing at least one source of molybdenum and at least one oxidizing compound in aqueous solution to synthesize peroxomolybdate ions at an acidic pH, the (oxidizing compound/molybdenum source) mole ratio being in the range 0.1 to 20; b) introducing at least one cobalt precursor and/or at least one nickel precursor into the solution from step a) to form a solution comprising at least said salt in which the (Co+Ni)/Mo mole ratio is in the range 0.25 to 0.85.

摘要翻译： 描述了一种制备由至少一种结合钼和钴或钼和镍的杂多阴离子的至少一种钴和/或镍盐形成的溶液的方法，所述方法包括：a）将至少一种钼源和 至少一种氧化性化合物在水溶液中，在酸性pH下合成过氧钼酸根离子，（氧化化合物/钼源）的摩尔比在0.1至20的范围内; b）将至少一种钴前体和/或至少一种镍前体引入到步骤a）的溶液中以形成至少包含所述盐的溶液，其中（Co + Ni）/ Mo摩尔比在0.25至 0.85。