摘要:
The present invention provides a supported osmate useful as a reusable catalyst in the preparation of vicinal diols. The present invention also relates to a process for the preparation of supported osmates of the formula (S—NR3)2OsO4.nH2O wherein S is a support, R is an alkyl group, n is the number of water molecules and use thereof in the preparation of vicinal diols by asymmetric dihydroxylation (AD) of olefins in presence of cinchona alkaloid compounds.
摘要:
The present invention provides an ecofriendly method for preparing dinitramidic acid and its salts by nitration of ammonium sulfamate with fuming nitric acid as a nitrating agent using solid acid catalysts selected from the group consisting of a montmorillonite clay catalyst and metal ion exchanged K10 montmorillonite clay catalysts and surface supported catalysts and preparation of ammonium dinitramide by neutralization of the dinitramidic acid with ammonia and separation of ammonium dinitramide.
摘要:
The present invention provides a process for the preparation of amine oxide by reacting a tertiary or a secondary amine with hydrogen peroxide as an oxidant in the presence of a recyclable heterogeneous catalyst comprising a layered double hydroxide exchanged with an anion in the presence of an additive selected from the group consisting of benzonitrile, propionitrile, isobutyronitrile, benzamide and isobutyraride.
摘要:
An improved process for the preparation of acyl aromatic ethers useful as important intermediates for drugs and pharmaceuticals by reacting an aromatic ether with an acylating agent selected from a C2-C8 acid anhydrides, employing nano- and microcrystalline zeolite beta as catalyst is disclosed.
摘要:
The invention relates to a process for the preparation of high quality tetrabromobisphenol-A by reacting bisphenol-A with bromine and hydrogen peroxide as an oxidant in the presence of a heterogeneous catalyst in a biphase system consisting of water and water immiscible organic solvents.
摘要:
The present invention provides novel diazonaphthoquinonesulfonic acid bisphenol derivatives. More particularly, the present invention relates to photo restive coating comprising alkali-soluble resin, a photoactive compound and a surfactant. The photoresist film prepared has less then one micron. The photoactive compound is soluble or swellable in aqueous alkaline solutions and is diazonaphthoquinonesulfonic bisphenol esters of the general formula (A), wherein DNQ represents a 2-Diazo-1-naphthoquinone-4-sulfonyl, 2-Diazo-1-naphthoquinone-5-sulfonyl, 1-Diazo-2-naphthoquinone-4-sulfonyl groups and R1 R1 represents an alkyl, aryl and substituted aryl groups. The invention also provides a process for coating and imaging the light-sensitive composition.
摘要翻译:本发明提供新的重氮萘醌磺酸双酚衍生物。 更具体地,本发明涉及包含碱溶性树脂,光活性化合物和表面活性剂的光复制涂层。 制备的光致抗蚀剂膜具有小于1微米。 光活性化合物在碱性水溶液中是可溶的或可溶胀的,是通式(A)的重氮萘醌磺酸双酚酯,其中DNQ表示2-重氮-1-萘醌-4-磺酰基,2-重氮-1-萘醌-5- 磺酰基,1-重氮-2-萘醌-4-磺酰基,R 1 R 1表示烷基,芳基和取代的芳基。 本发明还提供了一种用于涂覆和成像光敏组合物的方法。
摘要:
The present invention provides a novel sensor for the estimation of total cholesterol in human blood serum using molecular imprint of cholesterol. Human blood serum contains 150-250 mg/dl cholesterol. The present invention provides a sensor device and a process for the fabrication of ISFET (Ion Selective Field Effect Transister) coated with molecular imprint of cholesterol on the SiO2+Si3N4 dielectric gate of the said electrode. The molecular imprint of cholesterol (MIPC) anchored in to a silica matrix sensing material is identified as a sensing material which has specific selectivity towards the cholesterol in presence of other organic constituents in human blood serum.
摘要翻译:本发明提供了一种用于使用胆固醇分子印记估计人血清中总胆固醇的新型传感器。 人血清含有150-250 mg / dl胆固醇。 本发明提供一种用于制造在所述电极的SiO 2 + Si 3 N 4电介质栅极上涂覆有胆固醇分子印迹的ISFET(离子选择性场效应转移)的传感器装置和方法。 锚定在二氧化硅基质感测材料中的胆固醇(MIPC)的分子印记被鉴定为在人血清中存在其它有机成分时对胆固醇具有特异性选择性的感测材料。
摘要:
The present invention provides novel diazonaphthoquinonesulfonic acid bisphenol derivatives. More particularly, the present invention relates to photo restive coating comprising alkali-soluble resin, a photoactive compound and a surfactant. The photoresist film prepared has less then one micron. The photoactive compound is soluble or swellable in aqueous alkaline solutions and is diazonaphthoquinonesulfonic bisphenol esters of the general formula (A), wherein DNQ represents a 2-Diazo-1-naphthoquinone-4-sulfonyl, 2-Diazo-1-naphthoquinone-5-sulfonyl, 1-Diazo-2-naphthoquinone-4-sulfonyl groups and R1 R1 represents an alkyl, aryl and substituted aryl groups. The invention also provides a process for coating and imaging the light-sensitive composition.
摘要翻译:本发明提供新的重氮萘醌磺酸双酚衍生物。 更具体地,本发明涉及包含碱溶性树脂,光活性化合物和表面活性剂的光复制涂层。 制备的光致抗蚀剂膜具有小于1微米。 光活性化合物在碱性水溶液中是可溶的或可溶胀的,是通式(A)的重氮萘醌磺酸双酚酯,其中DNQ表示2-重氮-1-萘醌-4-磺酰基,2-重氮-1-萘醌-5- 磺酰基,1-重氮-2-萘醌-4-磺酰基,R 1 R 1表示烷基,芳基和取代的芳基。 本发明还提供了一种用于涂覆和成像光敏组合物的方法。
摘要:
The invention concerns the use of a solid basic catalyst comprising a hydrotalcite structure wherein part at least of the compensating anions are fluoride anions F− for producing Knoevenagel of Michael condensation reactions. The invention also concerns novel solid basic catalysts comprising a hydrotalcite structure characterized by a Mg/Al molar ratio ranging between 2.5 and 3.8 wherein at least part of the compensating anions are fluoride anions F−, and methods for preparing said novel catalysts.
摘要:
The present invention relates to design and preparation of LDH-diisopropylamide through simple exchange process for the first time and its use in catalytic amounts for preparing aldols/&agr;,&bgr;-unsaturated nitriles/&agr;,&bgr;-unsaturated esters/transesterified products/&bgr;-nitroalkanols/Michael adducts and epoxide, resulting in higher yields.