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公开(公告)号：US08133417B2
公开(公告)日：2012-03-13
申请号：US13097348
申请日：2011-04-29
申请人： Marcus David Shelby , Wesley Raymond Hale , Thomas Joseph Pecorini , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Mark Edward Stewart
发明人： Marcus David Shelby , Wesley Raymond Hale , Thomas Joseph Pecorini , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Mark Edward Stewart
CPC分类号： B29B17/0042 , C08K3/08 , C08L67/00 , C08L67/02 , C08L69/00 , C08L77/00 , C08L2205/02 , Y02W30/62 , Y10T428/13 , Y10T428/1334 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/31725 , Y10T428/31736 , Y10T428/31739 , C08L2666/20 , C08L2666/14
摘要： Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enables the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.
摘要翻译： 公开了一种制备成形制品的方法，例如片材，膜，管，瓶，预成型件和型材，具有高透明度和低雾度，包括一种或多种选自聚酯，聚碳酸酯和/或其中的热塑性聚合物的不混溶共混物 聚芳酯，以及至少两种聚酰胺的共聚酰胺或酰胺化的均匀共混物。 不混溶共混物的组分具有约0.006至约-0.0006的折射率。 折射率的小差异使得能够将再研磨物掺入聚合物组合物中以产生透明成型制品。 这些制品可以具有一层或多层，并且可以表现出优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。 可以将金属催化剂引入到组合物中以产生具有除氧性能的成形制品。
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公开(公告)号：US20110200774A1
公开(公告)日：2011-08-18
申请号：US13097334
申请日：2011-04-29
申请人： Wesley Raymond Hale , Thomas Joseph Pecorini , Spencer Allen Gilliam , Marcus David Shelby , Martin Emerson Rogers , Michael Duane Cliffton , Mark Edward Stewart
发明人： Wesley Raymond Hale , Thomas Joseph Pecorini , Spencer Allen Gilliam , Marcus David Shelby , Martin Emerson Rogers , Michael Duane Cliffton , Mark Edward Stewart
CPC分类号： C08L69/00 , C08K3/08 , C08L67/00 , C08L67/02 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2205/02 , C08L2205/03 , Y10T428/13 , Y10T428/1334 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/31725 , Y10T428/31736 , Y10T428/31739 , C08L2666/20 , C08L2666/14 , C08L2666/18 , C08L2666/02
摘要： Disclosed are polymer compositions having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce oxygen-scavenging compositions.
摘要翻译： 公开了具有高透明度和低雾度的聚合物组合物，其包含一种或多种选自聚酯，聚碳酸酯和聚芳酯的热塑性聚合物的不混溶共混物，以及至少两种聚酰胺的共聚酰胺或酰胺化均匀共混物。 不混溶共混物的组分具有约0.006至约-0.0006的折射率。 折射率的小差异使得能够将再研磨物掺入聚合物组合物中以产生透明成型制品。 本发明的共混物可用于生产成形制品，例如片材，薄膜，管，瓶，预型件和型材。 这些制品可以具有一层或多层，并且可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。 金属催化剂可以并入组合物中以产生除氧组合物。
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3.发明授权Polyesters with low molecular weight additives for improved gas barrier properties 有权具有低分子量添加剂的聚酯以改善气体阻隔性能公开(公告)号：US08377530B2
公开(公告)日：2013-02-19
申请号：US13023184
申请日：2011-02-08
CPC分类号： B29C47/1036 , B29C47/0004 , B29C47/0009 , B29C47/92 , B29C49/0005 , B29C49/04 , B29C49/06 , B29C51/002 , B29K2105/16 , Y10T428/1352 , Y10T428/139
摘要： Disclosed is a polyester polymer composition comprising at least one polyethylene terephthalate polyester in an amount ranging from 94.0 weight percent to 99.5 weight percent and at least one additive in an amount ranging from 0.5 weight percent to 6 weight percent, each based on the total weight of the polyester composition. The at least one additive comprises a diamide molecule. The composition of the present invention is useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms, and profiles. These articles can exhibit improved gas barrier properties. The process for making the polymer composition and the shaped articles is also disclosed.
摘要翻译： 公开了一种聚酯聚合物组合物，其包含至少一种量为94.0重量％至99.5重量％的聚对苯二甲酸乙二醇酯聚酯和至少一种量为0.5重量％至6重量％的添加剂，各自基于 聚酯组合物。 所述至少一种添加剂包含二酰胺分子。 本发明的组合物可用于制造成形制品，例如片材，薄膜，管，瓶，预成型件和型材。 这些制品可以表现出改进的阻气性能。 还公开了制备聚合物组合物和成型制品的方法。
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公开(公告)号：US08304499B2
公开(公告)日：2012-11-06
申请号：US13097334
申请日：2011-04-29
申请人： Marcus David Shelby , Wesley Raymond Hale , Thomas Joseph Pecorini , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Mark Edward Stewart
发明人： Marcus David Shelby , Wesley Raymond Hale , Thomas Joseph Pecorini , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Mark Edward Stewart
CPC分类号： C08L69/00 , C08K3/08 , C08L67/00 , C08L67/02 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2205/02 , C08L2205/03 , Y10T428/13 , Y10T428/1334 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/31725 , Y10T428/31736 , Y10T428/31739 , C08L2666/20 , C08L2666/14 , C08L2666/18 , C08L2666/02
摘要： Disclosed are polymer compositions having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce oxygen-scavenging compositions.
摘要翻译： 公开了具有高透明度和低雾度的聚合物组合物，其包含一种或多种选自聚酯，聚碳酸酯和聚芳酯的热塑性聚合物的不混溶共混物，以及至少两种聚酰胺的共聚酰胺或酰胺化均匀共混物。 不混溶共混物的组分具有约0.006至约-0.0006的折射率。 折射率的小差异使得能够将再研磨物掺入聚合物组合物中以产生透明成型制品。 本发明的共混物可用于生产成形制品，例如片材，薄膜，管，瓶，预型件和型材。 这些制品可以具有一层或多层，并且可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。 金属催化剂可以并入组合物中以产生除氧组合物。
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公开(公告)号：US20110201703A1
公开(公告)日：2011-08-18
申请号：US13097348
申请日：2011-04-29
申请人： Wesley Raymond Hale , Thomas Joseph Pecorini , Mark Edward Stewart , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Marcus David Shelby
发明人： Wesley Raymond Hale , Thomas Joseph Pecorini , Mark Edward Stewart , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Marcus David Shelby
CPC分类号： B29B17/0042 , C08K3/08 , C08L67/00 , C08L67/02 , C08L69/00 , C08L77/00 , C08L2205/02 , Y02W30/62 , Y10T428/13 , Y10T428/1334 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/31725 , Y10T428/31736 , Y10T428/31739 , C08L2666/20 , C08L2666/14
摘要： Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enables the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.
摘要翻译： 公开了一种制备成形制品的方法，例如片材，膜，管，瓶，预成型件和型材，具有高透明度和低雾度，包括一种或多种选自聚酯，聚碳酸酯和/或其中的热塑性聚合物的不混溶共混物 聚芳酯，以及至少两种聚酰胺的共聚酰胺或酰胺化的均匀共混物。 不混溶共混物的组分具有约0.006至约-0.0006的折射率。 折射率的小差异使得能够将再研磨物掺入聚合物组合物中以产生透明成型制品。 这些制品可以具有一层或多层，并且可以表现出优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。 可以将金属催化剂引入到组合物中以产生具有除氧性能的成形制品。
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6.发明授权公开(公告)号：US07959836B2
公开(公告)日：2011-06-14
申请号：US11390812
申请日：2006-03-28
申请人： Wesley Raymond Hale , Thomas Joseph Pecorini , Mark Edward Stewart , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Emmett Dudley Crawford , David Scott Porter , Gary Wayne Connell , Marcus David Shelby
发明人： Wesley Raymond Hale , Thomas Joseph Pecorini , Mark Edward Stewart , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Emmett Dudley Crawford , David Scott Porter , Gary Wayne Connell , Marcus David Shelby
CPC分类号： C08L77/00 , C08K3/08 , C08L67/02 , C08L69/00 , C08L2205/02 , C08L2205/03 , Y10T428/13 , Y10T428/1334 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/31725 , Y10T428/31736 , Y10T428/31739 , C08L2666/14 , C08L2666/20 , C08L2666/18
摘要： Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze, and comprising immiscible blends of at least one polyester comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.
摘要翻译： 公开了一种制备成形制品的方法，例如片状，薄膜，管，瓶，预成型件和型材，具有高透明度和低雾度，并且包括至少一种聚酯的不混溶共混物，包括2,2,4 ，4-四甲基-1,3-环丁二醇，以及共聚酰胺或至少两种聚酰胺的酰胺化均匀共混物。 不混溶共混物的组分具有约0.006至约-0.0006的折射率。 折射率的小差异使得能够将再研磨物掺入聚合物组合物中以产生透明成型制品。 这些制品可以具有一层或多层，并且可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。 可以将金属催化剂引入到组合物中以产生具有除氧性能的成形制品。
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公开(公告)号：US07786252B2
公开(公告)日：2010-08-31
申请号：US11363481
申请日：2006-02-27
申请人： Wesley Raymond Hale , Thomas Joseph Pecorini , Mark Edward Stewart , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Marcus David Shelby
发明人： Wesley Raymond Hale , Thomas Joseph Pecorini , Mark Edward Stewart , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Marcus David Shelby
CPC分类号： C08L69/00 , B32B2272/00 , B32B2305/70 , B32B2307/412 , C08K3/08 , C08L67/00 , C08L67/02 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2205/02 , C08L2666/20 , C08L2666/14
摘要： Disclosed is a process for the preparation of multilayered, shaped articles having high transparency and low haze having at least one layer contains one or more thermoplastic polymers selected from polyesters, polycarbonates, and homogeneous blends thereof, and a separate layer which contains a transamidized, homogeneous blend of a least two polyamides. The thermoplastic polymer components and the polyamide components have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.
摘要翻译： 公开了一种制备具有高透明度和低雾度的多层成形制品的方法，其具有至少一层包含一种或多种选自聚酯，聚碳酸酯及其均匀共混物的热塑性聚合物，以及含有酰胺化均匀的单独层 混合至少两种聚酰胺。 热塑性聚合物组分和聚酰胺组分的折射率相差约0.006至约-0.0006。 折射率的小差异使得可以将再研磨物掺入制品的一层或多层中同时保持高透明度。 这些制品可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。 可以将金属催化剂并入一个或多个层中以赋予氧气清除性能。
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8.发明授权公开(公告)号：US07462684B2
公开(公告)日：2008-12-09
申请号：US11390908
申请日：2006-03-28
申请人： Wesley Raymond Hale , Thomas Joseph Pecorini , Mark Edward Stewart , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Emmett Dudley Crawford , David Scott Porter , Gary Wayne Connell , Marcus David Shelby
发明人： Wesley Raymond Hale , Thomas Joseph Pecorini , Mark Edward Stewart , Martin Emerson Rogers , Spencer Allen Gilliam , Michael Duane Cliffton , Emmett Dudley Crawford , David Scott Porter , Gary Wayne Connell , Marcus David Shelby
CPC分类号： B29B17/0042 , B29B11/08 , B29B11/14 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/14106 , B29B2911/14113 , B29B2911/1412 , B29B2911/14126 , B29B2911/14133 , B29B2911/1414 , B29B2911/14146 , B29B2911/14153 , B29B2911/14906 , B29C45/0001 , B29C47/0004 , B29C47/0023 , B29C47/0026 , B29C47/043 , B29C47/061 , B29C47/065 , B29C49/0005 , B29C49/04 , B29C49/06 , B29C49/22 , B29C51/002 , B29C51/14 , B29K2067/00 , B29K2069/00 , B29K2077/00 , B29K2105/0008 , B29K2105/0026 , B29K2105/0032 , B29K2105/0044 , B29K2105/256 , B29K2105/258 , B29K2105/26 , B29K2995/0025 , B29L2031/7158 , B32B1/08 , B32B7/02 , B32B27/08 , B32B27/16 , B32B27/18 , B32B27/34 , B32B27/36 , B32B2250/02 , B32B2250/24 , B32B2264/105 , B32B2270/00 , B32B2272/00 , B32B2274/00 , B32B2307/412 , B32B2307/50 , B32B2307/7242 , B32B2307/74 , B32B2439/60 , B32B2439/62 , B32B2439/70 , B32B2597/00 , C08J11/06 , Y02P70/279 , Y02W30/62 , Y02W30/701
摘要： Disclosed is a process for the preparation of multilayered, shaped articles having high transparency and low haze and in which at least one layer contains at least one polyester comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol and a separate layer which contains a transamidized, homogeneous blend of a least two polyamides. The polyester component and the polyamide component have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.
摘要翻译： 公开了一种制备具有高透明度和低雾度的多层成型制品的方法，其中至少一层包含至少一种包含2,2,4,4-四甲基-1,3-环丁二醇的聚酯和分开的层 其包含至少两种聚酰胺的酰胺化均匀共混物。 聚酯组分和聚酰胺组分的折射率相差约0.006至约-0.0006。 折射率的小差异使得可以将再研磨物掺入制品的一层或多层中同时保持高透明度。 这些制品可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。 可以将金属催化剂并入一个或多个层中以赋予氧气清除性能。
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公开(公告)号：US06300462B1
公开(公告)日：2001-10-09
申请号：US09521758
申请日：2000-03-09
IPC分类号： C08G6400
CPC分类号： C08G63/78 , C08G63/189 , C08G63/83 , C08G63/866
摘要： There is disclosed a process for producing poly(ethylene-2,6-naphthalenedicarboxylate) and copolymers thereof having high molecular weight, low methyl end-group content, low diethylene glycol content and low carboxyl end-group content in the presence of water.
摘要翻译： 公开了一种在水存在下具有高分子量，低甲基端基含量，低二甘醇含量和低羧基端基含量的聚（乙烯-2,6-萘二甲酸酯）及其共聚物的方法。
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10.发明申请POLYESTERS WITH LOW MOLECULAR WEIGHT ADDITIVES FOR IMPROVED GAS BARRIER PROPERTIES 有权用于改进气体阻隔性能的低分子量添加剂的聚酯公开(公告)号：US20120199515A1
公开(公告)日：2012-08-09
申请号：US13023184
申请日：2011-02-08
IPC分类号： B65D23/00 , B29C49/04 , B29C49/08 , B29B7/00 , B29C51/00 , B29C45/46 , B29C39/00 , C08L35/02 , B29C47/00
CPC分类号： B29C47/1036 , B29C47/0004 , B29C47/0009 , B29C47/92 , B29C49/0005 , B29C49/04 , B29C49/06 , B29C51/002 , B29K2105/16 , Y10T428/1352 , Y10T428/139
摘要： Disclosed is a polyester polymer composition comprising at least one polyethylene terephthalate polyester in an amount ranging from 94.0 weight percent to 99.5 weight percent and at least one additive in an amount ranging from 0.5 weight percent to 6 weight percent, each based on the total weight of the polyester composition. The at least one additive comprises a diamide molecule. The composition of the present invention is useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms, and profiles. These articles can exhibit improved gas barrier properties. The process for making the polymer composition and the shaped articles is also disclosed.
摘要翻译： 公开了一种聚酯聚合物组合物，其包含至少一种量为94.0重量％至99.5重量％的聚对苯二甲酸乙二醇酯聚酯和至少一种量为0.5重量％至6重量％的添加剂，各自基于 聚酯组合物。 所述至少一种添加剂包含二酰胺分子。 本发明的组合物可用于制造成形制品，例如片材，薄膜，管，瓶，预成型件和型材。 这些制品可以表现出改进的阻气性能。 还公开了制备聚合物组合物和成型制品的方法。
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