Nucleating agents for polyhydroxyalkanoates

    公开(公告)号:US07301000B2

    公开(公告)日:2007-11-27

    申请号:US11224805

    申请日:2005-09-13

    IPC分类号: C08G63/02

    摘要: The present invention provides a process for crystallizing a polymer having at least 20 mole percent of hydroxyalkanoate repeat units, comprising admixing the polymer and a compound of the formula R1—C(O)N(R2)2, R1—C(O)NH—(R3)—NHC(O)—R1, R1—NHC(O)NH—(R3)—NHC(O)NH—R1, R1—NHC(O)—R2, R1—NHC(O)—(R3)—C(O)NH—R1, R1—C(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—NHC(O)—R1, or a combination thereof, at a first temperature, which is from about 5° C. to about 15° C. above the melting point of the polymer; and cooling the polymer at a second temperature, which is from about the glass transition temperature of the polymer to about the melting point of the compound. The present invention also provides a composition comprising a polymer having at least about 20 mole percent of hydroxyalkanoate repeat units, and a compound of the formula R1—C(O)N(R2)2, R1—C(O)NH—(R3)—NHC(O)—R1, R1—NHC(O)NH—(R3)—NHC(O)NH—R1, R1—NHC(O)—R2, R1—NHC(O)—(R3)—C(O)NH—R1, R1—C(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—NHC(O)—R1, or a combination thereof.

    Agricultural items and agricultural methods comprising biodegradable copolymers
    10.
    发明授权
    Agricultural items and agricultural methods comprising biodegradable copolymers 失效
    包括可生物降解共聚物的农产品和农业方法

    公开(公告)号:US06903053B2

    公开(公告)日:2005-06-07

    申请号:US10309997

    申请日:2002-12-04

    IPC分类号: A01N25/10 C05G5/00

    摘要: An agricultural item comprising a biodegradable polyhydroxyalkanoate copolymer comprising two randomly repeating monomer units. The first randomly repeating monomer unit has the structure: wherein R1 is H or a C1-2 alkyl, and n is 1 or 2; and the second randomly repeating monomer unit has the structure: wherein R2 is a C3-19 alkyl or a C3-19 alkenyl. At least 50% of the randomly repeating monomer units have the structure of the first randomly repeating monomer unit.

    摘要翻译: 一种农业物品,其包含可生物降解的聚羟基链烷酸酯共聚物,其包含两个随机重复的单体单元。 第一个随机重复的单体单元具有以下结构:其中R 1是H或C 1-12烷基,n是1或2; 并且第二个随机重复的单体单元具有以下结构:其中R 2是C 3〜19 - 烷基或C 3〜19 - 烯基。 至少50%的随机重复单体单元具有第一个无规重复的单体单元的结构。