摘要:
Reactive compositions are formed into melt processable reactive pellets. The reactive compositions include at least one filler such as talc, clay, pulp, etc. and a reactive mixture comprising at least one polyhydric alcohol and a reactant selected from the group consisting of at least one organic polyacid; at least one organic anhydride; and combinations thereof. Alternatively, the reactive compositions comprise at least one filler and a prepolymer formed from the reactive mixture.
摘要:
Methods of reducing exposure to latex comprise forming an item comprising a biodegradable polyhydroxyalkanoate copolymer comprising two randomly repeating monomer units. The first randomly repeating monomer unit has the structure: wherein R1 is H, or C1-2 alkyl, and n is 1 or 2; and the second randomly repeating monomer unit has the structure: wherein R2 is a C3-19 alkyl or C3-19 alkenyl. At least 50% of the randomly repeating monomer units have the structure of the first randomly repeating monomer unit.
摘要:
The invention relates to processes for extracting polyhydroxyalkanoate from a biomass, comprising admixing the biomass with an organic solvent for from 1 second to 15 minutes at a first temperature of from 5° C. below the melting point of the polyhydroxyalkanoate to 10° C. above the melting point of the polyhydroxyalkanoate and at a pressure of from 1 bar to 10 bar to provide a composition comprising the organic solvent and polyhydroxyalkanoate.
摘要:
Reactive compositions are formed into melt processable reactive pellets. The reactive compositions include at least one filler such as talc, clay, pulp, etc. and a reactive mixture comprising at least one polyhydric alcohol and a reactant selected from the group consisting of at least one organic polyacid; at least one organic anhydride; and combinations thereof. Alternatively, the reactive compositions comprise at least one filler and a prepolymer formed from the reactive mixture.
摘要:
A process is provided for coating a surface of a substrate using a coating precursor comprising a reactive mixture which is reacted to form a coating as a product of ester condensation. The reactive mixture includes a monomer mixture comprising at least one polyhydric alcohol and a reactant selected from the group consisting of at least one organic polyacid; at least one organic anhydride; and combinations thereof. Alternatively, the reactive mixture comprises a prepolymer formed from the monomer mixture; a combination of the prepolymer and the monomer mixture; or a combination of the prepolymer and reactants such as polyhydric alcohol, organic polyacid, organic anhydride, and combinations thereof.
摘要:
A process is provided for bonding a substrate to a material using an adhesive precursor comprising a reactive mixture which is reacted to form an adhesive as a product of ester condensation. The reactive mixture includes a monomer mixture comprising at least one polyhydric alcohol and a reactant selected from the group consisting of at least one organic polyacid; at least one organic anhydride; and combinations thereof. Alternatively, the reactive mixture comprises a prepolymer formed from the monomer mixture; a combination of the prepolymer and the monomer mixture; or a combination of the prepolymer and reactants such as polyhydric alcohol, organic polyacid, organic anhydride, and combinations thereof.
摘要:
Fibers are formed from ester condensates of polyhydric alcohols and organic polyacids or anhydrides. The process for making the fibers comprises forming a reactive mixture from a polyhydric alcohol and organic polyacid mixture heated to produce a low molecular weight ester condensation product which is subsequently pumped through a spinneret causing additional ester condensation reaction in situ with fiber formation.
摘要:
The present invention comprises processes for preparing biodegradable fibrils from one or more biodegradable homopolymeric or copolymeric resins, said process comprising: a) forming a liquid resin mixture by melting or solvating the resin or resins; and b) introducing the liquid resin mixture to a flow of a gaseous substance. The present invention further comprises biodegradable fibrils made according to the processes of the present invention. The invention further comprises nonwoven fabrics comprising biodegradable fibrils. The invention further comprises disposable absorbent articles comprising a water-permeable topsheet, an absorbent core, and a water-impermeable backsheet, wherein the topsheet comprises a nonwoven substrate comprising biodegradable fibrils. The invention further comprises disposable articles comprising biodegradable fibrils.
摘要:
The present invention provides a process for crystallizing a polymer having at least 20 mole percent of hydroxyalkanoate repeat units, comprising admixing the polymer and a compound of the formula R1—C(O)N(R2)2, R1—C(O)NH—(R3)—NHC(O)—R1, R1—NHC(O)NH—(R3)—NHC(O)NH—R1, R1—NHC(O)—R2, R1—NHC(O)—(R3)—C(O)NH—R1, R1—C(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—NHC(O)—R1, or a combination thereof, at a first temperature, which is from about 5° C. to about 15° C. above the melting point of the polymer; and cooling the polymer at a second temperature, which is from about the glass transition temperature of the polymer to about the melting point of the compound. The present invention also provides a composition comprising a polymer having at least about 20 mole percent of hydroxyalkanoate repeat units, and a compound of the formula R1—C(O)N(R2)2, R1—C(O)NH—(R3)—NHC(O)—R1, R1—NHC(O)NH—(R3)—NHC(O)NH—R1, R1—NHC(O)—R2, R1—NHC(O)—(R3)—C(O)NH—R1, R1—C(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—NHC(O)—R1, or a combination thereof.
摘要:
An agricultural item comprising a biodegradable polyhydroxyalkanoate copolymer comprising two randomly repeating monomer units. The first randomly repeating monomer unit has the structure: wherein R1 is H or a C1-2 alkyl, and n is 1 or 2; and the second randomly repeating monomer unit has the structure: wherein R2 is a C3-19 alkyl or a C3-19 alkenyl. At least 50% of the randomly repeating monomer units have the structure of the first randomly repeating monomer unit.