公开(公告)号：US20130296625A1

公开(公告)日：2013-11-07

申请号：US13462230

申请日：2012-05-02

Applicant: Ashim K. Ghosh ,  Scott A. Stevenson ,  Neeta Kulkarni ,  Mike Mier ,  Balamurali K. Nair ,  Dustin Farmer

Inventor： Ashim K. Ghosh ,  Scott A. Stevenson ,  Neeta Kulkarni ,  Mike Mier ,  Balamurali K. Nair ,  Dustin Farmer

IPC: C07C2/76 ,  B01J37/08 ,  B01J29/068

CPC classification number: B01J29/047 ,  B01J29/068 ,  B01J29/405 ,  B01J29/44 ,  B01J29/62 ,  B01J29/67 ,  B01J29/7461 ,  B01J29/7469 ,  B01J29/7476 ,  B01J29/7484 ,  B01J29/7492 ,  B01J37/0009 ,  B01J2229/186 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/40 ,  C10G35/065 ,  C10G35/09

Abstract: Methods for preparing bound non-acidic germanium zeolite catalysts arc disclosed, where the preparation is reproducible and scalable and where the catalysts have similar or the same activity and selectivities of a standard naphtha aromatization catalyst and methods for aromatizing naphtha.

Abstract translation: 公开了制备结合的非酸性锗沸石催化剂的方法，其中制备是可重复和可扩展的，其中催化剂具有与标准石脑油芳构化催化剂相似或相同的活性和选择性以及芳烃化石脑油的方法。

公开(公告)号：US20160362349A1

公开(公告)日：2016-12-15

申请号：US15120780

申请日：2015-06-30

Applicant: Ashim Kumar GHOSH ,  Neeta KULKARNI ,  Mike MIER ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Ashim Kumar Ghosh ,  Neeta Kulkarni ,  Mike Mier

IPC: C07C1/30 ,  B01J35/10 ,  B01J37/28 ,  B01J29/85

CPC classification number: C07C1/30 ,  B01J29/85 ,  B01J35/002 ,  B01J35/1019 ,  B01J37/28 ,  B01J2229/186 ,  C07C1/26 ,  C07C2529/85 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06

Abstract: Disclosed are stable catalysts, and methods for their use, that are capable of producing an olefin from an alkyl halide. The catalysts include a phosphorus-treated silicoalummophosphate (SAPO) having a structure of X/SAPO or X/Z-SAPO, where X includes a non-framework phosphorus and Z is one or more elements from Groups 2A, 3A, IVB, VIB, VIIB, VIII, IB of the Periodic Table, or compounds thereof comprised in the SAPO framework.

Abstract translation: 公开了能够从烷基卤生产烯烃的稳定的催化剂及其使用方法。 催化剂包括具有X / SAPO或X / Z-SAPO结构的磷处理的磷硅酸钠（SAPO），其中X包括非骨架磷，Z是来自2A，3A，IVB，VIB， VIIB，VIII，IB，或其化合物包含在SAPO框架中。

公开(公告)号：US20160271597A1

公开(公告)日：2016-09-22

申请号：US14907598

申请日：2015-07-28

Applicant: Ashim Kumar GHOSH ,  Alla KHANMAMEDOVA ,  Mike MIER ,  Jonathan BANKE ,  SABIC Global Technologies B.V.

Inventor： Ashim Kumar Ghosh ,  Alla Khanmamedova ,  Mike Mier ,  Jonathan Banke

IPC: B01J29/85 ,  C07C1/26 ,  B01J7/00 ,  C01B39/54 ,  B01J35/10

CPC classification number: B01J29/85 ,  B01J7/00 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1061 ,  B01J2229/37 ,  C01B39/54 ,  C07C1/26 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

Abstract: Disclosed is a method for converting an alkyl halide to an olefin. The method includes contacting a silicoaluminophosphate (SAPO) catalyst with a feed that includes an alkyl halide under reaction conditions sufficient to produce an olefin hydrocarbon product that includes C2 to C4 olefins. The SAPO catalyst has bimodal acidity designated as weak acid sites and strong acid sites. The weak acid concentration is less than 0.55 mmol/g-cat and the total acid concentration is less than 1.5 mmol/g-cat.

Abstract translation: 公开了将烷基卤转化为烯烃的方法。 该方法包括在足以产生包括C 2至C 4烯烃的烯烃产物的反应条件下使硅铝磷酸盐（SAPO）催化剂与包含烷基卤的进料接触。 SAPO催化剂具有指定为弱酸性位点和强酸性位点的双峰酸性。 弱酸浓度小于0.55 mmol / g-cat，总酸浓度小于1.5 mmol / g-cat。

公开(公告)号：US20160200642A1

公开(公告)日：2016-07-14

申请号：US14899003

申请日：2015-06-29

Applicant: Ashim Kumar GHOSH ,  Mike MIER ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Ashim Kumar Ghosh ,  Mike Mier

IPC: C07C1/30 ,  C01B39/38 ,  C08F10/00 ,  B01J29/40

CPC classification number: B01J29/40 ,  B01J29/90 ,  C01B39/38 ,  C07C1/26 ,  C07C2529/40 ,  C08F10/00 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

Abstract: Disclosed is a method for converting an alkyl halide to an olefin. The method can include contacting a zeolite catalyst comprising HZSM-5 having a silica to alumina (SAR) ratio of at least 30 with a feed that includes an alkyl halide under reaction conditions sufficient to produce an olefin hydrocarbon product comprising C2 to C4 olefins, wherein the selectivity of the C2 to C4 olefins is at least 85% at 20% alkyl halide conversion.

Abstract translation: 公开了将烷基卤转化为烯烃的方法。 该方法可以包括使包含至少30的二氧化硅与氧化铝（SAR）比率的HZSM-5的沸石催化剂与足以产生包含C 2 -C 4烯烃的烯烃产物的反应条件下的包含烷基卤的进料接触，其中 在20％烷基卤转化时，C2至C4烯烃的选择性至少为85％。

公开(公告)号：US08772192B2

公开(公告)日：2014-07-08

申请号：US13537184

申请日：2012-06-29

Applicant: Alla Khanmamedova ,  Scott Stevenson ,  Dustin Farmer ,  Mike Mier

Inventor： Alla Khanmamedova ,  Scott Stevenson ,  Dustin Farmer ,  Mike Mier

IPC: B01J29/06

CPC classification number: B01J23/42 ,  B01J29/047 ,  C07C2/76 ,  C07C2523/42 ,  C07C2529/035 ,  Y02P20/52 ,  C07C15/04 ,  C07C15/06 ,  C07C15/08 ,  C07C15/073

Abstract: A catalyst and its preparation and use are disclosed. The catalyst is a silicalite having germanium (Ge) included within the framework of the silicalite prepared in a particular manner. The catalyst may be used in a method of converting hydrocarbons wherein a hydrocarbon feed is contacted with the catalyst. The catalyst may be formed by preparing an aqueous reaction mixture of a silica-containing silicalite precursor material and a germanium source. The reactants of the reaction mixture are allowed to react. The reacted reaction mixture is heated under conditions to form crystals of a silicalite having germanium included within the framework of the silicalite. The crystals are then calcined to form the catalyst. In certain embodiments, a noble metal may be deposited upon the germanium-containing silicalite.

Abstract translation: 公开了催化剂及其制备和用途。 该催化剂是在特定方式制备的硅沸石的框架内包含锗（Ge）的硅沸石。 催化剂可用于转化烃的方法，其中烃进料与催化剂接触。 可以通过制备含二氧化硅的硅沸石前体材料和锗源的含水反应混合物来形成催化剂。 使反应混合物的反应物反应。 将反应的反应混合物在条件下加热以形成包含在硅沸石框架内的锗的硅沸石晶体。 然后将晶体煅烧以形成催化剂。 在某些实施方案中，贵金属可沉积在含锗硅沸石上。

公开(公告)号：US20110132804A1

公开(公告)日：2011-06-09

申请号：US12592883

申请日：2009-12-04

Applicant: Scott Stevenson ,  Paul E. Ellis ,  Mike Mier ,  Dustin Farmer ,  Alla Khanmamedova ,  Scott Mitchell

Inventor： Scott Stevenson ,  Paul E. Ellis ,  Mike Mier ,  Dustin Farmer ,  Alla Khanmamedova ,  Scott Mitchell

IPC: C10G35/06

CPC classification number: C10G35/065 ,  B01J29/047 ,  B01J29/44 ,  B01J2229/20 ,  C10G35/085 ,  C10G2300/1044 ,  C10G2300/1081 ,  C10G2300/1096 ,  C10G2300/202 ,  C10G2300/305 ,  C10G2300/4018

Abstract: This invention relates to a process for the increasing the octane number of a naphtha hydrocarbon feed having a predominantly paraffin content with a germanium-containing zeolite catalyst. The catalyst is a non-acidic germanium zeolite on which a noble metal, such as platinum, has been deposited. The zeolite structure may be of MTW, MWW, MEL, TON, MRE, FER, MFI, BEA, MOR, LTL or MTT. The zeolite is made non-acidic by being base-exchanged with an alkali metal or alkaline earth metal, such as cesium, potassium, sodium, rubidium, barium, calcium, magnesium and mixtures thereof, to reduce acidity. The catalyst is sulfur tolerant. The hydrocarbon feed may contain sulfur up to 1000 ppm. The present invention could be applicable to a feedstream which is predominantly naphthenes and paraffins.

Abstract translation: 本发明涉及一种用含锗沸石催化剂提高主要为石蜡含量的石脑油烃进料的辛烷值的方法。 催化剂是其上沉积有贵金属如铂的非酸性锗沸石。 沸石结构可以是MTW，MWW，MEL，TON，MRE，FER，MFI，BEA，MOR，LTL或MTT。 沸石通过与碱金属或碱土金属如铯，钾，钠，铷，钡，钙，镁及其混合物进行碱交换而制成非酸性，以降低酸度。 催化剂是耐硫的。 烃进料可含有高达1000ppm的硫。 本发明可以应用于主要是环烷烃和链烷烃的进料流。

公开(公告)号：US09242233B2

公开(公告)日：2016-01-26

申请号：US13462230

申请日：2012-05-02

Applicant: Ashim K. Ghosh ,  Scott A. Stevenson ,  Neeta Kulkarni ,  Mike Mier ,  Balamurali K. Nair ,  Dustin Farmer

Inventor： Ashim K. Ghosh ,  Scott A. Stevenson ,  Neeta Kulkarni ,  Mike Mier ,  Balamurali K. Nair ,  Dustin Farmer

IPC: B01J29/06 ,  B01J29/04 ,  B01J29/62 ,  B01J29/67 ,  B01J29/74 ,  B01J29/068 ,  B01J29/40 ,  B01J29/44 ,  B01J37/00 ,  C01B39/02 ,  C01B39/40 ,  C10G35/06 ,  C10G35/09

CPC classification number: B01J29/047 ,  B01J29/068 ,  B01J29/405 ,  B01J29/44 ,  B01J29/62 ,  B01J29/67 ,  B01J29/7461 ,  B01J29/7469 ,  B01J29/7476 ,  B01J29/7484 ,  B01J29/7492 ,  B01J37/0009 ,  B01J2229/186 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/40 ,  C10G35/065 ,  C10G35/09

Abstract: Methods for preparing bound non-acidic germanium zeolite catalysts are disclosed, where the preparation is reproducible and scalable and where the catalysts have similar or the same activity and selectivities of a standard naphtha aromatization catalyst and methods for aromatizing naphtha.

Abstract translation: 公开了制备结合的非酸性锗沸石催化剂的方法，其中制备是可重复和可扩展的，其中催化剂具有与标准石脑油芳构化催化剂相似或相同的活性和选择性以及芳烃化石脑油的方法。

公开(公告)号：US20140005453A1

公开(公告)日：2014-01-02

申请号：US13537184

申请日：2012-06-29

Applicant: Alla Khanmamedova ,  Scott Stevenson ,  Dustin Farmer ,  Mike Mier

Inventor： Alla Khanmamedova ,  Scott Stevenson ,  Dustin Farmer ,  Mike Mier

IPC: B01J29/04 ,  C07C5/367 ,  C01B39/00

CPC classification number: B01J23/42 ,  B01J29/047 ,  C07C2/76 ,  C07C2523/42 ,  C07C2529/035 ,  Y02P20/52 ,  C07C15/04 ,  C07C15/06 ,  C07C15/08 ,  C07C15/073

Abstract: A catalyst and its preparation and use are disclosed. The catalyst is a silicalite having germanium (Ge) included within the framework of the silicalite prepared in a particular manner. The catalyst may be used in a method of converting hydrocarbons wherein a hydrocarbon feed is contacted with the catalyst. The catalyst may be formed by preparing an aqueous reaction mixture of a silica-containing silicalite precursor material and a germanium source. The reactants of the reaction mixture are allowed to react. The reacted reaction mixture is heated under conditions to form crystals of a silicalite having germanium included within the framework of the silicalite. The crystals are then calcined to form the catalyst. In certain embodiments, a noble metal may be deposited upon the germanium-containing silicalite.

Abstract translation: 公开了催化剂及其制备和用途。 该催化剂是在特定方式制备的硅沸石的框架内包含锗（Ge）的硅沸石。 催化剂可用于转化烃的方法，其中烃进料与催化剂接触。 可以通过制备含二氧化硅的硅沸石前体材料和锗源的含水反应混合物来形成催化剂。 使反应混合物的反应物反应。 将反应的反应混合物在条件下加热以形成包含在硅沸石框架内的锗的硅沸石晶体。 然后将晶体煅烧以形成催化剂。 在某些实施方案中，贵金属可沉积在含锗硅沸石上。