摘要:
A polymer composition comprises a low-molecular-weight (LMW) ethylene polymer component and a high-molecular-weight (HMW) ethylene polymer component coupled with a polysulfonyl azide. Preferably, the LMW polyethylene component and the HMW polyethylene component co-crystallize in the composition such that it exhibits a single or substantially single peak in a lamella thickness distribution (LTD) curve. The ethylene polymer for the LMW and the HMW polyethylene components can be either homopolymer or ethylene copolymer. Preferably, both components are an ethylene copolymer of the same, or different, composition (that is, with the same or different comonomers). A method of making a pipe that includes selecting a polymer composition having a substantially single peak in the LTD curve is described. Compositions comprising a chromium-catalyzed ethylene polymer, coupled with a polysulfonyl azide are also described herein.
摘要:
The invention provides a process for injection blow molding an article, said process comprising injecting into a mold cavity a composition, comprising at least one ethylene-based polymer and less than, or equal to, 1000 ppm of a mold release agent, based on the total weight of the composition. The invention also provides a composition comprising a blend, wherein the blend comprises at least one high molecular weight (HMW) ethylene-based polymer, and at least one low molecular weight (LMW) ethylene-based polymer, and wherein the blend has an unsaturation level, as determined by IR, and expressed as vinyls per 1000 carbon atoms, less than, or equal to, 0.5 vinyls per 1000 carbon atoms, and wherein the high molecular weight (HMW) ethylene-based polymer has a density from 0.925 to 0.950 g/cc.
摘要翻译:本发明提供了一种用于注射吹塑成型物品的方法,所述方法包括将包含至少一种基于乙烯的聚合物和小于或等于1000ppm的脱模剂的组合物注入模腔中,基于 组合物的总重量。 本发明还提供包含共混物的组合物,其中所述共混物包含至少一种高分子量(HMW)基于乙烯的聚合物和至少一种低分子量(LMW)乙烯基聚合物,并且其中所述共混物具有不饱和键 水平,由IR确定,并且每1000个碳原子表示为乙烯基,每1000个碳原子小于或等于0.5个乙烯基,其中高分子量(HMW)乙烯类聚合物的密度为0.925-0.950 g / cc。
摘要:
The instant invention is a polyethylene composition, method of producing the same, fibers made therefrom, and method of making the same. The polyethylene composition according to instant invention comprises: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers. The polyethylene composition according to instant invention has a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I2) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition. The process for producing the inventive polyethylene composition comprises the steps of: (1) (co)polymerizing ethylene and optionally one or more α-olefin comonomers in the presence of a hafnium based metallocene catalyst via a gas phase (co)polymerization process in a single stage reactor; and (2) thereby producing the polyethylene composition having a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I2) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition. The fibers according to the instant invention comprise a polyethylene composition comprising: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers; wherein the polyethylene composition has a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I2) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition. The process for making a fiber according to instant invention comprises the steps of: (1) selecting a polyethylene composition comprising: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers; wherein the polyethylene composition has a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I2) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition; (2) spinning the polyethylene composition into a fiber; and (3) thereby forming the fiber.
摘要:
Compositions having good impact performance can be made from a thermoplastic (e.g., a polyolefin such as polypropylene or HDPE) and an ethylene multi-block copolymer. The compositions are easily molded and often have particular utility in making, for example, automotive facia, parts and other household articles.
摘要:
Compositions having good impact performance can be made from a thermoplastic (e.g., a polyolefin such as polypropylene or HDPE) and an ethylene multi-block copolymer. The compositions are easily molded and often have particular utility in making, for example, automotive facia, parts and other household articles.
摘要:
Novel hydrogenated amorphous silicon alloys are disclosed. Hydrogenated amorphous silicon alloys produced by PECVD are disclosed. A method is also disclosed for the preparation of novel hydrogenated amorphous silicon alloys for use as thin films. The method comprises subjecting a mixed gas of gas-phase silicon compounds and other gas-phase alloy element compounds to plasma enhanced chemical vapor deposition in a reaction zone such that the alloy formed is deposited on a substrate.
摘要:
The instant invention discloses fibers. The fibers according to the instant invention comprise a polyethylene composition comprising: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers; wherein the polyethylene composition has a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I2) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition.
摘要:
Impact modified compositions having good impact performance can be made from a thermoplastic (e.g., a polyolefin such as polypropylene or HDPE) and a multi-block ethylene/α-olefin interpolymer. The compositions are easily molded and often have particular utility in making, for example, automotive facia, parts and other household articles.
摘要:
Solid state draw a polymer billet, wherein at least 50 percent of all polymers in the billet is a continuous phase of polyethylene polymer having a density of 0.941-0.959 grams per cubic centimeter and a weight-average molecular weight that is 110,000 grams per mole or greater, at a drawing rate of 1.2 meters per minute or faster using a tensile force to create an oriented and cavitated polymer composition whose cross section dimensions all exceed two millimeters.
摘要:
The invention provides compositions for blow molding applications and other applications, where such compositions comprise a high molecular weight ethylene interpolymer and a low molecular weight ethylene polymer, and where the high molecular weight ethylene interpolymer has a density from 0.920 g/cm3 to 0.950 g/cm3, and an I21 from 0.05 to 1 dg/min, and where the low molecular weight ethylene polymer has density from 0.965 g/cm3 to 0.985 g/cm3, and an I2 from 600 to 2000 dg/min. The composition has a density from 0.950 g/cm3 to 0.970 g/cm3, and comprises greater from 45 to 80 weight percent of the high molecular component, and from 20 to 55 weight percent of the low molecular weight component, based on the sum weight of the high molecular weight component and the low molecular weight component. The invention also provides for methods of preparing said compositions and for articles prepared from the same.
摘要翻译:本发明提供用于吹塑应用和其它应用的组合物,其中这种组合物包含高分子量乙烯互聚物和低分子量乙烯聚合物,并且其中高分子量乙烯互聚物的密度为0.920g / cm 3至0.950g / cm3,I21为0.05〜1dg / min,低分子量乙烯聚合物的密度为0.965g / cm 3〜0.985g / cm 3,I2为600〜2000dg / min。 该组合物的密度为0.950g / cm 3至0.970g / cm 3,并且包含较高分子组分的45至80重量%和低分子量组分的20至55重量%,基于总重量 的高分子量组分和低分子量组分。 本发明还提供了制备所述组合物和由其制备的制品的方法。