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1.发明授权Thermoplastic resin composition including an amorphous resin, an epoxy group-containing ethylene copolymer, and a polyfunctional compound or a carboxylic acid metal salt 失效包含无定形树脂，含环氧基的乙烯共聚物和多官能化合物或羧酸金属盐的热塑性树脂组合物
公开(公告)号：US5623018A
公开(公告)日：1997-04-22
申请号：US487512
申请日：1995-06-07
IPC分类号： C08L23/08 , C08L25/06 , C08L51/04 , C08L55/02 , C08L69/00 , C08L101/00 , C08K5/098 , C08L25/12
CPC分类号： C08L51/04 , C08L101/00 , C08L25/06 , C08L55/02 , C08L69/00 , C08L23/08 , C08L2555/40
摘要： Disclosed is a thermoplastic resin composition comprising (A) an amorphous resin and further comprising, per 100 parts by weight of the amorphous resin,0.01 to 20 parts by weight of (B) an epoxy group-containing ethylene copolymer, and0.01 to 20 parts by weight of at least one member selected from the group consisting of (C) a polyfunctional compound and (D) a carboxylic acid metal salt, wherein the polyfunctional compound contains, per molecule, at least two identical or different functional groups selected from the group consisting of carboxyl group, amino group, carboxylic acid anhydride group and a unit represented by the formula (1) ##STR1## wherein X and Y are identical and each represents oxygen atom or sulfur atom, or one of X and Y is an oxygen atom and the other is a sulfur atom, or wherein the polyfunctional compound contains, per molecule, at least one unit represented by the formula (2) ##STR2## wherein Z represents oxygen atom or sulfur atom.
摘要翻译： 公开了一种热塑性树脂组合物，其包含（A）无定形树脂，并且每100重量份的无定形树脂还包含0.01至20重量份的（B）含环氧基的乙烯共聚物和0.01至20重量份 的至少一种选自（C）多官能化合物和（D）羧酸金属盐的成员，其中所述多官能化合物每分子含有至少两个相同或不同的选自以下的官能团： 由羧基，氨基，羧酸酐基和式（1）表示的单元各自表示氧原子或硫原子，或者X和Y中的一个为氧原子，另一个为硫原子，或者 多官能化合物每分子含有至少一个由式（2）表示的单元，其中Z表示氧原子或硫原子。
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公开(公告)号：US5508347A
公开(公告)日：1996-04-16
申请号：US260742
申请日：1994-06-15
CPC分类号： C08L51/04 , C08L101/00 , C08L25/06 , C08L55/02 , C08L69/00 , C08L23/08 , C08L2555/40
摘要： Disclosed is a thermoplastic resin composition comprising (A) an amorphous resin and further comprising, per 100 parts by weight of the amorphous resin,0.01 to 20 parts by weight of (B) an epoxy group containing ethylene copolymer, and0.01 to 20 parts by weight of at least one member selected from the group consisting of (C) a polyfunctional compound and (D) a carboxylic acid metal salt, wherein the polyfunctional compound contains, per molecule, at least two identical or different functional groups selected from the group consisting of carboxyl group, amino group, carboxylic acid anhydride group and a unit represented by the formula (1) ##STR1## wherein X and Y are identical and each represents oxygen atom or sulfur atom, or one of X and Y is an oxygen atom and the other is a sulfur atom, or wherein the polyfunctional compound contains, per molecule, at least one unit represented by the formula (2) ##STR2## wherein Z represents oxygen atom or sulfur atom.
摘要翻译： 公开了一种热塑性树脂组合物，其包含（A）无定形树脂，并且每100重量份的无定形树脂还包含0.01至20重量份的（B）含环氧基的乙烯共聚物和0.01至20重量份的 至少一种选自（C）多官能化合物和（D）羧酸金属盐的成员的重量，其中所述多官能化合物每分子含有至少两个相同或不同的选自以下的官能团： 的羧基，氨基，羧酸酐基和式（1）所示的单元ach表示氧原子或硫原子，或者X和Y中的一个为氧原子，另一个为硫原子，或者其中 多官能化合物每分子含有至少一个由式（2）表示的单元，其中Z表示氧原子或硫原子。
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公开(公告)号：US5405909A
公开(公告)日：1995-04-11
申请号：US147466
申请日：1993-10-26
IPC分类号： C08K5/00 , C08G59/00 , C08G81/00 , C08K5/053 , C08K5/092 , C08K5/17 , C08K5/21 , C08K5/405 , C08L23/08 , C08L37/00 , C08L53/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L71/00
CPC分类号： C08L23/0884 , C08L63/00 , C08L67/02 , C08K5/053 , C08K5/092 , C08K5/17 , C08K5/21 , C08K5/405 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L23/0869 , C08L2310/00 , C08L53/00
摘要： A thermoplastic elastomer composition which is useful for bumper, boot, sound absorbing gear, sports shoes etc. is provided by mixing the following (A)-(D).A: 30-58 parts by wt of saturated polyester resin,B: 42-70 parts by wt of an epoxy group-containing ethylene copolymer ofa) 50-99% by wt of ethylene unit,b) 0.1-30% by wt of unsaturated carboxylic acid glycidyl ester unit or unsaturated glycidyl ether unit andc) 0-49% by wt of ethylenically unsaturated ester unitC: 0.01-20 parts by wt of specific polyfunctional compound containing two or more functional groups, andD: 1-30 parts by wt of block copolyether ester elastomer.The amounts of C and D are based on 100 parts of A and B.
摘要翻译： 通过混合以下（A） - （D）来提供用于保险杠，靴子，吸音齿轮，运动鞋等的热塑性弹性体组合物。 A：30-58重量份的饱和聚酯树脂，B：42-70重量份的a）50-99重量％的乙烯单元的含环氧基的乙烯共聚物，b）0.1-30重量％ 的不饱和羧酸缩水甘油酯单元或不饱和缩水甘油醚单元，和c）0-49重量％的烯键式不饱和酯单元C：0.01-20重量份含有两个或更多个官能团的特定多官能化合物，D：1- 30重量份嵌段共聚醚酯弹性体。 C和D的量基于A和B的100份。
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4.发明授权Graft copolymer, process for production thereof, and plasticizer comprising said copolymer as active component 失效接枝共聚物，其制备方法和包含所述共聚物作为活性组分的增塑剂
公开(公告)号：US5385974A
公开(公告)日：1995-01-31
申请号：US91564
申请日：1993-07-15
申请人： Tadayuki Ohmae , Hisao Tanaka , Sumio Hara
发明人： Tadayuki Ohmae , Hisao Tanaka , Sumio Hara
CPC分类号： C08F8/14
摘要： A novel graft copolymer having a number-average molecular weight of about 1,500 to about 1,000,000, produced by graft-copolymerizing an alkylene oxide and a cyclic ester to a saponified ethylene-saturated carboxylic acid vinyl ester copolymer; a process for production thereof; and a plasticizer comprising said graft copolymer as the active component.
摘要翻译： 通过将烯化氧和环状酯接触共聚到皂化的乙烯 - 饱和羧酸乙烯基酯共聚物上制备的数均分子量为约1,500至约1,000,000的新型接枝共聚物; 其生产方法; 和包含所述接枝共聚物作为活性组分的增塑剂。
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5.发明授权
公开(公告)号：US5367013A
公开(公告)日：1994-11-22
申请号：US958727
申请日：1992-10-09
CPC分类号： C08L81/02 , C08L101/00 , C08L67/02 , C08L77/00 , C08L2205/06 , C08L23/08
摘要： A process for producing a reinforced crystalline engineering plastic composition is disclosed, comprising melt-kneading (A) from 60 to 97 parts by weight of a crystalline engineering plastic and (B) from 5 to 100 parts by weight, per 100 parts by weight of the sum of (A) and (C), of glass fibers and melt-kneading the resulting mixture with (C) from 3 to 40 parts by weight of an epoxy- or acid anhydride-containing ethylene copolymer. The composition obtained provides, with excellent moldability, a molded article having an improved appearance while exhibiting well-balanced mechanical and thermal properties.
摘要翻译： 公开了一种生产增强结晶工程塑料组合物的方法，包括将（A）60至97重量份的结晶工程塑料和（B）5至100重量份熔体捏合（A），相对于每100重量份 （A）和（C）的总和，并将得到的混合物与（C）熔融捏合3至40重量份的含环氧或含酸酐的乙烯共聚物。 获得的组合物具有优异的成型性，其具有改进外观的模制品，同时具有良好平衡的机械和热性能。
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公开(公告)号：US5296552A
公开(公告)日：1994-03-22
申请号：US840805
申请日：1992-02-25
IPC分类号： C08F8/00 , B29B7/46 , C08F255/00 , C08J3/00 , C08L23/26 , C09J151/00 , C09J151/06
CPC分类号： C09J151/06 , B29C47/366 , C08F255/00
摘要： An adhesive resin composition is obtained by mixing at least one member (C) selected from the group consisting of unsaturated carboxylic acids and the derivatives thereof, a free-radical initiator (D), and a mixture consisting of a crystalline polyolefin resin (A) and an amorphous or low crystalline olefin copolymer of ethylene and an .alpha.-olefin (B), to obtain a precursor mixture, melt-kneading the precursor mixture in the first half of an extruder having at least one side feeder, to obtain a modified precursor mixture, and feeding a crystalline polyolefin resin (E) from the side feeder of the extruder and mixing the resin (E) with the modified precursor mixture.The adhesive resin composition has good extrudability and exhibits high adhesive property to polar materials such as polar polymeric materials and the like.
摘要翻译： 通过混合至少一种选自不饱和羧酸及其衍生物的组分（C），自由基引发剂（D）和由结晶聚烯烃树脂（A）组成的混合物，得到粘合剂树脂组合物， 和乙烯与（α） - 烯烃（B）的无定形或低结晶烯烃共聚物，以获得前体混合物，在具有至少一个侧进料器的挤出机的前半部分中熔融捏合前体混合物，得到 并且从挤出机的侧进料器进料结晶聚烯烃树脂（E）并将树脂（E）与改性前体混合物混合。 粘合性树脂组合物具有良好的挤出性，并且对极性材料如极性聚合物材料等显示出高粘合性。
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7.发明授权Process for producing a lactam compound graft copolymer of ethylene copolymer 失效制备乙烯共聚物的内酰胺化合物接枝共聚物的方法
公开(公告)号：US5290865A
公开(公告)日：1994-03-01
申请号：US984236
申请日：1992-12-01
CPC分类号： C08F8/30
摘要： A process for producing a graft copolymer comprising melt-blending:(A) 1 to 90 parts by weight of an ethylene copolymer, based on the weight of the graft copolymer, comprising (a) 40 to 99.9% by weight of ethylene units, (b) 0 to 60% by weight of .alpha.,.beta.-unsaturated carboxylic acid alkyl ester units, and (c) 0.1 to 10% by weight of maleic anhydride units;(B) 0.1 to 10 moles of a lactam metal salt compound per mole of the maleic anhydride units (c) of the ethylene copolymer (A); and(C) 10 to 99 parts by weight of a lactam compound, based on the weight of the graft copolymer,which results in a graft copolymer having high impact strength, high flexibility, satisfactory dyeability, and well-balanced physical properties over a wide temperature range.
摘要翻译： 一种制备接枝共聚物的方法，包括熔融共混：（A）1-90重量份乙烯共聚物，基于接枝共聚物的重量，包括（a）40-99.9重量％的乙烯单元，（ b）0至60重量％的（α），（β-）不饱和羧酸烷基酯单元，和（c）0.1至10重量％的马来酸酐单元; （B）每摩尔乙烯共聚物（A）的马来酸酐单元（c）为0.1〜10摩尔的内酰胺金属盐化合物; 和（C）10至99重量份的内酰胺化合物，基于接枝共聚物的重量，其导致接枝共聚物具有高冲击强度，高柔性，令人满意的可染性和在宽的物理性能上的良好平衡 温度范围。
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公开(公告)号：US4831095A
公开(公告)日：1989-05-16
申请号：US145353
申请日：1988-01-19
申请人： Tadayuki Ohmae , Kentaro Mashita , Noboru Yamaguchi , Kouichiro Asao , Hisao Tanaka , Tadashi Sakurai
发明人： Tadayuki Ohmae , Kentaro Mashita , Noboru Yamaguchi , Kouichiro Asao , Hisao Tanaka , Tadashi Sakurai
IPC分类号： C08F8/44 , C08F210/02 , C08F220/60
CPC分类号： C08F220/60 , C08F210/02 , C08F8/44
摘要： A novel ethylene copolymer and a process for producing said copolymer are disclosed. This ethylene copolymer contains from 40 to 95% by weight of ethylene, from 60 to 5% by weight of at least one dialkylaminoalkyl acrylamide comonomer represented by formula (A): ##STR1## wherein the symbols are as defined in the appended claims, and 0 to 20% by weight of at least one ethylenically unsaturated comonomer, and has a number average molecular weight of from 5,000 to 50,000.
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公开(公告)号：US4771106A
公开(公告)日：1988-09-13
申请号：US98836
申请日：1987-09-21
IPC分类号： C08G63/672 , C09J167/02 , C08L67/02
CPC分类号： C08G63/672 , C09J167/02
摘要： An adhesive resin composition is described, comprising: (A) a thermoplastic copolyester resin prepared from (1) a dicarboxylic acid component comprising from 40 to 100 mol % of terephthalic acid and from 0 to 60 mol % of other aromatic dicarboxylic acid and (2) a low molecular weight glycol component comprising from 40 to 100 mol % of 1,4-butanediol and from 0 to 60 mol % of diethylene glycol or 1,6-hexanediol and further from 0 to 10 mol %, based on the total carboxylic acid, of polytetramethylene glycol having a molecular weight of from 600 to 6,000, which has a melting point of from 90.degree. to 160.degree. C. and a reduced viscosity of at least 0.5; and (B) an ethylene copolymer having at least one functional group selected from an epoxy group, a carboxylic acid group, and a dicarboxylic anhydride group; and if desired, (C) a thermoplastic resin other than the resin (A), and if further desired, (D) a polyfunctional epoxy compound. This composition exhibits excellent adhesion to synthetic resins such as polyvinyl chloride, polyesters, and polyolefins and also to metals such as aluminum and has excellent adhesive durability against moisture.
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公开(公告)号：US4764551A
公开(公告)日：1988-08-16
申请号：US116817
申请日：1987-11-05
CPC分类号： C08L23/12 , C08L23/02 , C08L23/142 , C08L2203/12 , C08L23/0869 , C08L23/0892 , C08L33/26
摘要： A dyeable poly-.alpha.-olefin composition having improved dyeablity, is disclosed, comprising a melt kneaded mixture of(A) 100 parts by weight of a poly-.alpha.-olefin;(B) from 1 to 20 parts by weight of an ethylene copolymer having a melt index as defined in JIS K-6760 at 190.degree. C. in the range of from 1 to 1,000 g/10 min, which is composed of(a) from 40 to 95% by weight of ethylene and(b) from 5 to 60% by weight of at least one dialkylaminoalkyl acrylamides comonomer represented by the formula: ##STR1## wherein R.sub.1 represents hydrogen or a methyl group; R.sub.2 and R.sub.3 each represents hydrogen or an alkyl group having from 1 to 4 carbon atoms; and n represents an integer of from 2 ro 4; and(C) from 0 to 3 parts by weight of at least one alkali metal salt of an organic carboxylic acid having from 7 to 24 carbon atoms.
摘要翻译： 公开了具有改进的可染色性的可染色聚α-烯烃组合物，其包含（A）100重量份聚-α-烯烃的熔融捏合混合物; （B）1〜20份（重量）乙烯共聚物，其熔融指数为JIS K-6760，190℃，为1〜1000g / 10min，由（a） 40至95重量％的乙烯和（b）5至60重量％的由下式表示的至少一种二烷基氨基烷基丙烯酰胺共聚单体：其中R1表示氢或甲基; R2和R3各自表示氢或具有1至4个碳原子的烷基; n表示2〜4的整数。 和（C）0至3重量份的至少一种具有7至24个碳原子的有机羧酸的碱金属盐。
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