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1.发明授权公开(公告)号：US07807601B2
公开(公告)日：2010-10-05
申请号：US11998778
申请日：2007-11-30
CPC分类号： B01J35/002 , B01J23/002 , B01J23/28 , B01J27/0576 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C51/252 , C07D301/08 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/53
摘要： A catalyst for the oxidation of an alkane, alkene or mixtures thereof. The catalyst includes a mixed-metal oxide having the formula MoaVbNbcTedSbeOf wherein, when a=1, b=0.01 to 1.0, c=0.01 to 1.0, d=0.01 to 1.0, e=0.01 to 1.0, and f is dependent upon the oxidation state of the other elements, the catalyst further characterized by having at least two crystal phases, the first crystal phase being an orthorhombic M1 phase and the second crystal phase being a pseudo-hexagonal M2 phase, the orthorhombic M1 phase present in an amount between greater than 60 weight percent to less than 90 weight percent. The catalysts disclosed herein exhibit a chemisorption of NH3 of less than about 0.2 mmole per gram of metal oxide.
摘要翻译： 用于氧化烷烃，烯烃或其混合物的催化剂。 催化剂包括具有式MoaVbNbcTedSbeOf的混合金属氧化物，其中当a = 1时，b = 0.01至1.0，c = 0.01至1.0，d = 0.01至1.0，e = 0.01至1.0，f取决于氧化 其他元素的状态，催化剂的特征还在于具有至少两个结晶相，第一晶相是正交的M 1相，第二晶相是拟六方晶系的M 2相，正交晶相M1相位存在于较大的 超过60重量％至小于90重量％。 本文公开的催化剂表现出每克金属氧化物小于约0.2毫摩尔的NH 3的化学吸附。
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2.发明授权Chabazite-containing molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins 有权含有菱沸石的分子筛，其合成及其在含氧化合物转化为烯烃中的应用公开(公告)号：US07094389B2
公开(公告)日：2006-08-22
申请号：US11017286
申请日：2004-12-20
申请人： Guang Cao , Machteld M. Mertens , Karl G. Strohmaier , Richard B. Hall , Thomas Herman Colle , Mobae Afeworki , Antonie J. Bons , Wilfried J. Mortier , Chris Kliewer , Hailian Li , Anil S. Guram , Robert J. Saxton , Mark T. Muraoka , Jeffrey C. Yoder
发明人： Guang Cao , Machteld M. Mertens , Karl G. Strohmaier , Richard B. Hall , Thomas Herman Colle , Mobae Afeworki , Antonie J. Bons , Wilfried J. Mortier , Chris Kliewer , Hailian Li , Anil S. Guram , Robert J. Saxton , Mark T. Muraoka , Jeffrey C. Yoder
IPC分类号： C01B39/48
CPC分类号： C01B39/46 , C01B37/02 , C01B39/023 , C01B39/48 , C10G3/45 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2300/802 , C10G2400/20 , Y02P30/20 , Y02P30/42
摘要： A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.
摘要翻译： 基本上不含骨架磷的结晶物质，其包含具有堆垛层错的CHA骨架型分子筛或CHA骨架型分子筛和AEI骨架型分子筛的至少一个共生相，其中所述材料以其煅烧的无水形式 具有涉及摩尔关系的组成：<？in-line-formula description =“In-line Formulas”end =“lead”？>（n）X＆lt; 2＆lt; 3＆lt; 3＆ 其中X是三价元素;其中X是三价元素;其中X是三价元素; Y是四价元素; 且n为0至约0.5。 该材料在甲醇转化为低级烯烃，特别是乙烯和丙烯时具有活性和选择性。
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公开(公告)号：US06316683B1
公开(公告)日：2001-11-13
申请号：US09391770
申请日：1999-09-08
申请人： Marcel J. G. Janssen , Cornelius W. M. Van Oorschot , Shun C. Fung , Luc R. M. Martens , Wilfried J. Mortier , Ronald G. Searle , Machteld M. Mertens , Stephen N. Vaughn
发明人： Marcel J. G. Janssen , Cornelius W. M. Van Oorschot , Shun C. Fung , Luc R. M. Martens , Wilfried J. Mortier , Ronald G. Searle , Machteld M. Mertens , Stephen N. Vaughn
IPC分类号： C07C120
CPC分类号： B01J37/08 , B01J29/85 , B01J2229/24 , B01J2229/40 , C07C1/20 , C07C2529/85 , C10G3/49 , C10G2300/4018 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within the molecular sieve; shielding the catalytic sites to protect from loss of catalytic activity; and contacting the protected sieve in its activated state with an oxygenate feedstock under conditions effective to produce an olefin product before undesirable loss of catalytic activity. Undesirable loss in catalytic activity occurs when activated molecular sieve contacting the oxygenate feedstock has a methanol uptake index of at least 0.15.
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4.发明授权Process for catalytically converting C10 and higher olefins to C9 and lower olefins 失效将C10和更高级烯烃催化转化为C9和低级烯烃的方法
公开(公告)号：US5120893A
公开(公告)日：1992-06-09
申请号：US580659
申请日：1990-09-11
申请人： Joseph W. Gabriel , Alexandr P. Glivicky , Nur R. Gurak , Norman C. Murtaugh , Wilfried J. Mortier , David E. Vaughan , Ram N. Bhatia
发明人： Joseph W. Gabriel , Alexandr P. Glivicky , Nur R. Gurak , Norman C. Murtaugh , Wilfried J. Mortier , David E. Vaughan , Ram N. Bhatia
IPC分类号： C07C4/06
CPC分类号： C07C4/06 , C07C2521/08 , C07C2521/12 , C07C2529/18 , C07C2529/40 , C07C2529/70
摘要： The present invention provides a highly selective catalytic cracking process for the conversion of feedstocks containing a predominant content of C.sub.10 and higher mixed olefins into C.sub.9 and lower olefin products at efficiencies of greater than 20%. said products further characterized in that the content C.sub.6 to C.sub.9 olefins is maximized while the content of C.sub.2 to C.sub.4 olefins is minimized. The process involves contacting an olefin feedstock mixture containing at least about 50 weight %, more preferably at least about 70 weight %, of C.sub.10 and higher olefins under cracking conditions with a catalyst selected from the group consisting of amorphous precipitated silica, selected crystalline silicates and aluminosilicates, namely beta, mordenite and ZSM-5 types, as well as ion exchanged or acid variants thereof. Cracking conditions include a temperature within the range of from about 250.degree. up to about 450.degree. C., pressures from atmospheric up to about 300 psig and a space velocity within the range of from about 0.5 up to about 4 wt/wt/hour.
摘要翻译： 本发明提供了一种高选择性催化裂化方法，用于将含有主要含量的C10和更高混合烯烃的原料转化成C9和低级烯烃产物，效率大于20％。 所述产物的特征还在于C6至C9烯烃含量最大，而C2至C4烯烃的含量最小。 该方法包括在裂化条件下将含有至少约50重量％，更优选至少约70重量％的C 10和更高级烯烃的烯烃原料混合物与选自以下的催化剂接触：无定形沉淀二氧化硅，选择的结晶硅酸盐和 铝硅酸盐，即β，丝光沸石和ZSM-5类型，以及离子交换或其酸变体。 开裂条件包括在约250℃至约450℃范围内的温度，从大气压至约300psig的压力和约0.5至约4重量/重量/小时范围内的空间速度。
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公开(公告)号：US08470289B2
公开(公告)日：2013-06-25
申请号：US12163393
申请日：2008-06-27
申请人： Helge Jaensch , Wilfried J. Mortier
发明人： Helge Jaensch , Wilfried J. Mortier
IPC分类号： G01G5/00
CPC分类号： C07C5/48 , B01J23/34 , B01J23/688 , B01J35/002 , B01J37/03 , B01J37/30 , C01G45/00 , C01G45/02 , C01P2002/08 , C01P2002/72 , C01P2002/85 , C07B33/00 , C07C45/33 , C07C51/215 , C07C51/252 , C07C2523/34 , Y02P20/582 , C07C11/02 , C07C57/04
摘要： Catalytic structures are provided comprising octahedral tunnel lattice manganese oxides ion-exchanged with metal cations or mixtures thereof. The structures are useful as catalysts for the oxidation of alkanes and may be prepared by treating layered manganese oxide under highly acidic conditions, optionally drying the treated product, and subjecting it to ion exchange.
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6.发明申请公开(公告)号：US20080161602A1
公开(公告)日：2008-07-03
申请号：US11998778
申请日：2007-11-30
IPC分类号： C07C51/215 , C01G39/02
CPC分类号： B01J35/002 , B01J23/002 , B01J23/28 , B01J27/0576 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C51/252 , C07D301/08 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/53
摘要： A catalyst for the oxidation of an alkane, alkene or mixtures thereof. The catalyst includes a mixed-metal oxide having the formula MoaVbNbcTedSbeOf wherein, when a=1, b=0.01 to 1.0, c=0.01 to 1.0, d=0.01 to 1.0, e=0.01 to 1.0, and f is dependent upon the oxidation state of the other elements, the catalyst further characterized by having at least two crystal phases, the first crystal phase being an orthorhombic M1 phase and the second crystal phase being a pseudo-hexagonal M2 phase, the orthorhombic M1 phase present in an amount between greater than 60 weight percent to less than 90 weight percent. The catalysts disclosed herein exhibit a chemisorption of NH3 of less than about 0.2 mmole per gram of metal oxide.
摘要翻译： 用于氧化烷烃，烯烃或其混合物的催化剂。 催化剂包括具有以下分子式的混合金属氧化物：其中R a，R b，C b， 其中，当a = 1时，b = 0.01〜1.0，c = 0.01〜1.0，d = 0.01〜1.0，e = 0.01〜1.0，f为依赖性 在其它元素的氧化态下，催化剂的特征还在于具有至少两个结晶相，第一晶相为正交晶相M1相，第二晶相为伪六边形M2相，斜方晶相M1存在于 大于60重量％至小于90重量％。 本文公开的催化剂表现出每克金属氧化物小于约0.2毫摩尔的NH 3的化学吸附。
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公开(公告)号：US07074384B2
公开(公告)日：2006-07-11
申请号：US10433674
申请日：2001-12-07
申请人： Machteld Maria Mertens , Johan Adriaan Martens , Raman Rayishankar , Christine Eva Antiona Kirschhock , Pierre August Jacobs , Antonie Jan Bons , Wilfried J. Mortier
发明人： Machteld Maria Mertens , Johan Adriaan Martens , Raman Rayishankar , Christine Eva Antiona Kirschhock , Pierre August Jacobs , Antonie Jan Bons , Wilfried J. Mortier
IPC分类号： C01B39/48
摘要： A new family of crystalline molecular sieves is described having a characteristic XRD pattern as illustrated in FIG. 1, and having three sharp peaks at 2θ (CuKα) of 8.82, 12.44, and 23.01.
摘要翻译： 描述了一种新的结晶分子筛系列，其具有如图1所示的特征XRD图案。 1，并且在2θ（CuKαα/α）上具有8.82,12.44和23.01的三个尖峰。
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公开(公告)号：US20150298982A1
公开(公告)日：2015-10-22
申请号：US14440946
申请日：2013-11-14
申请人： Jane C. CHENG , Marc H. ANTHONIS , Machteld M. TENS , Antonie J. BONS , Brita ENGELS , Wilfried J. MORTIER , EXXONMOBIL CHEMICAL PATENTS INC.
发明人： Machteld Maria Wilfried Mertens , Marc H. Anthonis , Antonie Jan Bons , Brita Engels , Wilfried Jozef Mortier , Jane Chi-ya Cheng
CPC分类号： C01B39/40 , B01J20/18 , B01J29/40 , C07C5/52 , C07C2529/44 , C07C2529/46 , C07C2529/48
摘要： A method of making a crystalline molecular sieve of MFI framework type, preferably ZSM-5, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure directing agent (R) and water, said synthesis mixture having the following molar composition: YO2:(p) X2O3:(q) MOH:(r) R:(s) H2O, wherein (p) is from 0.005 to 0.025, (q) is from 0.05 to 0.5, (r) is from 0.05 to 0.15 and (s) is from 35 to 45, wherein the ratio of the largest dimension (L) to the smallest dimension (S) of each crystal of the molecular sieve product is at least 5, and the smallest dimension (S) is from 20 nm to 200 nm.
摘要翻译： 从包含至少一种四价元素（Y）源，至少一种三价元素（X）源的合成混合物制备MFI框架型结晶分子筛，优选ZSM-5的方法，至少一种源 碱金属氢氧化物（MOH），至少一种结构导向剂（R）和水，所述合成混合物具有以下摩尔组成：YO 2：（p）X 2 O 3：（q）MOH：（r）R：（s） 其中（p）为0.005〜0.025，（q）为0.05〜0.5，（r）为0.05〜0.15，（s）为35〜45，其中最大尺寸（L）与最小尺寸 分子筛产物的每个晶体的尺寸（S）至少为5，最小尺寸（S）为20nm至200nm。
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9.发明授权Crystalline intergrowth material of silicoaluminophosphate having two intergrown phases 有权具有两个共生相的硅铝磷酸盐的结晶共生材料公开(公告)号：US07914760B2
公开(公告)日：2011-03-29
申请号：US12576062
申请日：2009-10-08
申请人： Machteld M. Mertens , An Verberckmoes , Marcel J. Janssen , Yun Feng Chang , Luc R. M. Martens , Stephen Neil Vaughn , Kenneth Ray Clem , Wilfried J. Mortier
发明人： Machteld M. Mertens , An Verberckmoes , Marcel J. Janssen , Yun Feng Chang , Luc R. M. Martens , Stephen Neil Vaughn , Kenneth Ray Clem , Wilfried J. Mortier
IPC分类号： C01B25/36 , C01B25/45 , B01J21/12 , B01J27/18 , B01J27/182
CPC分类号： B01J29/85 , C01B39/54 , C07C1/20 , C07C2529/70 , C07C2529/85 , Y02P30/20 , Y02P30/42 , Y10S423/30 , Y10T428/2982 , C07C11/02
摘要： A silicoaluminophosphate molecular sieve is disclosed that comprises first and second intergrown phases of a CHA framework type and an AEI framework type, wherein said first intergrown phase has an AEI/CHA ratio of from about 5/95 to about 40/60 as determined by DIFFaX analysis, the second intergrown phase has an AEI/CHA ratio of about 30/70 to about as determined by DIFFaX analysis and said molecular sieve has a silica to alumina molar ratio (Si/Al2) from about 0.13 to about 0.24.
摘要翻译： 公开了一种硅铝磷酸盐分子筛，其包含CHA骨架型和AEI骨架型的第一和第二共生相，其中所述第一共生相的AEI / CHA比为约5/95至约40/60，如通过DIFFaX 分析中，第二共生相具有通过DIFFaX分析确定的约30/70至约的AEI / CHA比，并且所述分子筛具有约0.13至约0.24的二氧化硅与氧化铝的摩尔比（Si / Al 2）。
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10.发明申请公开(公告)号：US20100324326A1
公开(公告)日：2010-12-23
申请号：US12869275
申请日：2010-08-26
IPC分类号： C07C253/18 , C07C51/25 , C07C51/215 , C07C253/00
CPC分类号： B01J35/002 , B01J23/002 , B01J23/28 , B01J27/0576 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C51/252 , C07D301/08 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/53
摘要： A catalyst for the oxidation of an alkane, alkene or mixtures thereof. The catalyst includes a mixed-metal oxide having the formula MoaVbNbcTedSbeOf wherein, when a=1, b=0.01 to 1.0, c=0.01 to 1.0, d=0.01 to 1.0, e=0.01 to 1.0, and f is dependent upon the oxidation state of the other elements, the catalyst further characterized by having at least two crystal phases, the first crystal phase being an orthorhombic M1 phase and the second crystal phase being a pseudo-hexagonal M2 phase, the orthorhombic M1 phase present in an amount between greater than 60 weight percent to less than 90 weight percent. The catalysts disclosed herein exhibit a chemisorption of NH3 of less than about 0.2 mmole per gram of metal oxide.
摘要翻译： 用于氧化烷烃，烯烃或其混合物的催化剂。 催化剂包括具有式MoaVbNbcTedSbeOf的混合金属氧化物，其中当a = 1时，b = 0.01至1.0，c = 0.01至1.0，d = 0.01至1.0，e = 0.01至1.0，f取决于氧化 其他元素的状态，催化剂的特征还在于具有至少两个结晶相，第一晶相是正交的M 1相，第二晶相是拟六方晶系的M 2相，正交晶相M1相位存在于较大的 超过60重量％至小于90重量％。 本文公开的催化剂表现出每克金属氧化物小于约0.2毫摩尔的NH 3的化学吸附。
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