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公开(公告)号：US06258991B1
公开(公告)日：2001-07-10
申请号：US09481969
申请日：2000-01-12
IPC分类号： C01B3908
CPC分类号： B01D67/0044 , B01D67/0051 , B01D71/028 , B01D2323/08 , B01D2323/12 , B01J29/60 , B01J29/605 , B01J29/70 , B01J2229/26 , B01J2229/42 , C01B39/082 , C01B39/32 , C07C5/226 , C07C5/415 , C07C2529/60 , Y10S423/28
摘要： Low temperature hydrothermal treatment of an LTL zeolite-producing mixture produces a colloidal suspension of the zeolite; the suspension may be used as seeds in Al- and Ga-LTL zeolite manufacture.
摘要翻译： LTL沸石生产混合物的低温水热处理产生沸石的胶体悬浮液; 该悬浮液可用作Al-和Ga-LTL沸石制造中的种子。
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公开(公告)号：US06074457A
公开(公告)日：2000-06-13
申请号：US101219
申请日：1999-01-13
申请人： Marc H. Anthonis , Antonie Jan Bons , Lothar Ruediger Czarnetzki , Wim Guy Jean-Marie DeGijnst , Wilfried Jozef Mortier , Cornelius Wilhelmus Maria Van Oorschot
发明人： Marc H. Anthonis , Antonie Jan Bons , Lothar Ruediger Czarnetzki , Wim Guy Jean-Marie DeGijnst , Wilfried Jozef Mortier , Cornelius Wilhelmus Maria Van Oorschot
IPC分类号： B01D71/02 , B01J29/035 , B01J29/04 , B01J29/40 , B01J37/02 , C01B37/02 , C01B39/04 , C01B39/40 , B01D53/22
CPC分类号： B01D67/0072 , B01D69/12 , B01D71/028 , B01J29/40 , B01J37/0244 , B01J37/0246 , C01B37/02 , C01B39/40 , B01D2325/22 , B01J2229/64 , Y10S423/22
摘要： Structures comprising a crystalline molecular sieve layer on a substrate and an additional layer of a refractory material to occlude voids in the molecular sieve layer.
摘要翻译： PCT No.PCT / EP96 / 05579 Sec。 371日期1999年1月13日 102（e）日期1999年1月13日PCT 1996年12月2日PCT公布。 公开号WO97 / 25129 日期1997年7月17日结构包括在基底上的结晶分子筛层和另外的耐火材料层以封闭分子筛层中的空隙。
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3.发明授权Tailored zeolite bound zeolite catalysts and its use for hydrocarbon conversion 失效定性沸石结合沸石催化剂及其用于烃转化公开(公告)号：US06858129B2
公开(公告)日：2005-02-22
申请号：US10635400
申请日：2003-08-06
申请人： Gary David Mohr , Kenneth Ray Clem , Wilfried Jozef Mortier , Machteld Maria Mertens , Xiaobing Feng , Marc H. Anthonis , Bart Schoofs
发明人： Gary David Mohr , Kenneth Ray Clem , Wilfried Jozef Mortier , Machteld Maria Mertens , Xiaobing Feng , Marc H. Anthonis , Bart Schoofs
IPC分类号： B01J29/40 , B01J29/70 , B01J29/80 , B01J29/87 , B01J29/89 , B01J37/00 , C10G11/05 , C10G29/20 , C10G45/64 , C07C5/22
CPC分类号： B01J29/7042 , B01J29/06 , B01J29/40 , B01J29/80 , B01J29/87 , B01J29/89 , B01J37/0009 , B01J2229/42 , B01J2229/62 , C10G11/05 , C10G29/205 , C10G45/64
摘要： There is provided a zeolite bound zeolite catalyst which does not contain significant amount of non-zeolitic binder and can be tailored to optimize its performance and a process for converting hydrocarbons utilizing the zeolite bound zeolite catalyst. The zeolite bound zeolite catalyst comprises core crystals containing first crystals of a first zeolite and optionally second crystals of a second zeolite having a composition, structure type, or both that is different from said first zeolite and binder crystals containing third crystals of a third zeolite and optionally fourth crystals of a fourth zeolite having a composition, structure type, or both that is different from said third zeolite. If the core crystals do not contain the second crystals of the second zeolite, then the binder crystals must contain the fourth crystals of the fourth zeolite. The zeolite bound zeolite finds application in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportional of toluene, isomerization, and transalkylation reactions.
摘要翻译： 提供沸石结合的沸石催化剂，其不含有显着量的非沸石粘合剂，并且可以调整其优化其性能，以及使用沸石结合的沸石催化剂转化烃的方法。 沸石结合的沸石催化剂包括含有第一沸石的第一晶体的芯晶体和任选具有与所述第一沸石不同的组成，结构类型或两者的第二沸石的第二晶体，以及包含第三沸石的第三晶体的粘结剂晶体， 任选具有与所述第三沸石不同的组成，结构类型或二者的第四沸石的第四晶体。 如果核心晶体不含第二沸石的第二晶体，则粘合剂晶体必须含有第四沸石的第四晶体。 沸石结合的沸石可用于烃转化过程，例如催化裂化，烷基化，甲苯不成比例，异构化和烷基转移反应。
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公开(公告)号：US06190638B1
公开(公告)日：2001-02-20
申请号：US09101220
申请日：1998-10-19
IPC分类号： C01B3940
CPC分类号： B01D67/0072 , B01D69/12 , B01D71/028 , B01D2325/22 , B01J29/40 , B01J37/0244 , B01J37/0246 , B01J2229/64 , C01B37/02 , C01B39/40 , Y10S423/22
摘要： Mixtures of synthesis mixtures of different alkalinity's produce small MFI crystals that are not spherical.
摘要翻译： 不同碱度的合成混合物的混合物产生不是球形的小MFI晶体。
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公开(公告)号：US20150298982A1
公开(公告)日：2015-10-22
申请号：US14440946
申请日：2013-11-14
申请人： Jane C. CHENG , Marc H. ANTHONIS , Machteld M. TENS , Antonie J. BONS , Brita ENGELS , Wilfried J. MORTIER , EXXONMOBIL CHEMICAL PATENTS INC.
发明人： Machteld Maria Wilfried Mertens , Marc H. Anthonis , Antonie Jan Bons , Brita Engels , Wilfried Jozef Mortier , Jane Chi-ya Cheng
CPC分类号： C01B39/40 , B01J20/18 , B01J29/40 , C07C5/52 , C07C2529/44 , C07C2529/46 , C07C2529/48
摘要： A method of making a crystalline molecular sieve of MFI framework type, preferably ZSM-5, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure directing agent (R) and water, said synthesis mixture having the following molar composition: YO2:(p) X2O3:(q) MOH:(r) R:(s) H2O, wherein (p) is from 0.005 to 0.025, (q) is from 0.05 to 0.5, (r) is from 0.05 to 0.15 and (s) is from 35 to 45, wherein the ratio of the largest dimension (L) to the smallest dimension (S) of each crystal of the molecular sieve product is at least 5, and the smallest dimension (S) is from 20 nm to 200 nm.
摘要翻译： 从包含至少一种四价元素（Y）源，至少一种三价元素（X）源的合成混合物制备MFI框架型结晶分子筛，优选ZSM-5的方法，至少一种源 碱金属氢氧化物（MOH），至少一种结构导向剂（R）和水，所述合成混合物具有以下摩尔组成：YO 2：（p）X 2 O 3：（q）MOH：（r）R：（s） 其中（p）为0.005〜0.025，（q）为0.05〜0.5，（r）为0.05〜0.15，（s）为35〜45，其中最大尺寸（L）与最小尺寸 分子筛产物的每个晶体的尺寸（S）至少为5，最小尺寸（S）为20nm至200nm。
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公开(公告)号：US6042808A
公开(公告)日：2000-03-28
申请号：US809164
申请日：1997-06-20
IPC分类号： B01D71/02 , B01J29/60 , B01J29/70 , B01J29/87 , B01J37/025 , C01B39/08 , C01B39/32 , C07C5/22 , C07C5/41
CPC分类号： B01D67/0044 , B01D67/0051 , B01D71/028 , B01J29/60 , B01J29/605 , B01J29/70 , C01B39/082 , C01B39/32 , C07C5/226 , C07C5/415 , B01D2323/08 , B01D2323/12 , B01J2229/26 , B01J2229/42 , C07C2529/60 , Y10S423/28
摘要： Low temperature hydrothermal treatment of an LTL zeolite-producing mixture produces a colloidal suspension of the zeolite; the suspension may be used as seeds in Al-- and Ga--LTL zeolite manufacture.
摘要翻译： PCT No.PCT / EP96 / 03597 371日期：1997年6月20日 102（e）1997年6月20日PCT PCT 1996年7月9日PCT公布。 第WO97 / 03021号公报 日期1997年1月30日LTL沸石生产混合物的低温水热处理产生沸石的胶体悬浮液; 该悬浮液可用作Al-和Ga-LTL沸石制造中的种子。
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7.发明授权Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权含有菱沸石的分子筛的合成及其在含氧化合物转化为烯烃的用途公开(公告)号：US07670589B2
公开(公告)日：2010-03-02
申请号：US11521155
申请日：2006-09-14
申请人： Guang Cao , Machteld Maria Mertens , Matu J. Shah , Marc H. Anthonis , Hailian Li , Anil S. Guram , Robert J. Saxton , Mark T. Muraoka , Jeffrey C. Yoder , Anthony F. Volpe, Jr.
发明人： Guang Cao , Machteld Maria Mertens , Matu J. Shah , Marc H. Anthonis , Hailian Li , Anil S. Guram , Robert J. Saxton , Mark T. Muraoka , Jeffrey C. Yoder , Anthony F. Volpe, Jr.
IPC分类号： C01B39/04
CPC分类号： C01B39/48 , B01J29/70 , B01J29/7015 , B01J29/80 , C01B37/02 , C01B39/023 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2300/1011 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： The synthesis of a crystalline material, in particular, a high silica zeolite, comprising a chabazite-type framework molecular sieve is conducted in the presence of an organic directing agent having the formula: [R1R2R3N—R4]+Q− wherein R1 and R2 are independently selected from hydrocarbyl groups and hydroxy-substituted hydrocarbyl groups having from 1 to 3 carbon atoms, provided that R1 and R2 may be joined to form a nitrogen-containing heterocyclic structure, R3 is an alkyl group having 2 to 4 carbon atoms and R4 is selected from a 4- to 8-membered cycloalkyl group, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms; and a 4- to 8-membered heterocyclic group having from 1 to 3 heteroatoms, said heterocyclic group being, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms and the or each heteroatom in said heterocyclic group being selected from the group consisting of O, N, and S, or R3 and R4 are hydrocarbyl groups having from 1 to 3 carbon atoms joined to form a nitrogen-containing heterocyclic structure; and Q− is a anion.
摘要翻译： 包含菱沸石型骨架分子筛的结晶材料，特别是高硅石沸石的合成在具有下式的有机导向剂的存在下进行：[R 1 R 2 R 3 N-R 4] + Q-，其中R 1和R 2是 独立地选自具有1至3个碳原子的烃基和羟基取代的烃基，条件是R 1和R 2可以连接形成含氮杂环结构，R 3是具有2至4个碳原子的烷基，R 4是 选自4至8元环烷基，任选被1至3个具有1至3个碳原子的烷基取代; 和具有1至3个杂原子的4至8元杂环基，所述杂环基任选被1至3个具有1至3个碳原子的烷基取代，并且所述杂环基中的每个杂原子被选定 由O，N和S组成的组，或R3和R4是具有1至3个碳原子的烃基连接以形成含氮杂环结构; 和Q-是阴离子。
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公开(公告)号：US09725327B2
公开(公告)日：2017-08-08
申请号：US14440946
申请日：2013-11-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , Machteld Maria Wilfried Mertens , Marc H. Anthonis , Antonie Jan Bons , Brita Engels , Wilfried Jozef Mortier , Jane Chi-ya Cheng
发明人： Machteld Maria Wilfried Mertens , Marc H. Anthonis , Antonie Jan Bons , Brita Engels , Wilfried Jozef Mortier , Jane Chi-ya Cheng
CPC分类号： C01B39/40 , B01J20/18 , B01J29/40 , C07C5/52 , C07C2529/44 , C07C2529/46 , C07C2529/48
摘要： A method of making a crystalline molecular sieve of MFI framework type, preferably ZSM-5, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure directing; (R) and water, said synthesis mixture having the following molar composition: YO2, (p)X2O3: (q) MOH: (r) R: (s) H2O, wherein (p) is from 0.005 to 0.025, (q) is from 0.05 to 0.5, (r) is from 0.05 to 0.15 and (s) is from 35 to 45, wherein the ratio of the largest dimension (L) to the smallest dimension (S) of each crystal of the molecular sieve product is at least 5, and the smallest dimension (S) is from 20 nm to 200 nm.
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公开(公告)号：US07033968B1
公开(公告)日：2006-04-25
申请号：US09936312
申请日：2000-03-10
申请人： Antonie Jan Bons , Marc H. Anthonis
发明人： Antonie Jan Bons , Marc H. Anthonis
IPC分类号： B01J20/28
CPC分类号： B01D67/0051 , B01D67/0083 , B01D69/105 , B01D71/028 , B01D2325/10 , B01J20/183 , B01J35/065 , B01J37/0246 , B01J37/0248 , B01J2229/64
摘要： A process is described for the manufacture of a crystalline molecular sieve layer on a support, which process comprises impregnation of the support with an impregnating material prior to deposition of a crystalline molecular sieve layer and subsequent removal of substantially all the impregnating material.
摘要翻译： 描述了在载体上制造结晶分子筛层的方法，该方法包括在沉积结晶分子筛层之前用浸渍材料浸渍载体并随后除去基本上所有的浸渍材料。
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公开(公告)号：US06699811B1
公开(公告)日：2004-03-02
申请号：US09565975
申请日：2000-05-05
申请人： Gary David Mohr , Kenneth Ray Clem , Wilfried Jozef Mortier , Machteld Maria Mertens , Xiaobing Feng , Marc H. Anthonis , Bart Schoofs
发明人： Gary David Mohr , Kenneth Ray Clem , Wilfried Jozef Mortier , Machteld Maria Mertens , Xiaobing Feng , Marc H. Anthonis , Bart Schoofs
IPC分类号： B01J2906
CPC分类号： B01J29/7042 , B01J29/06 , B01J29/40 , B01J29/80 , B01J29/87 , B01J29/89 , B01J37/0009 , B01J2229/42 , B01J2229/62 , C10G11/05 , C10G29/205 , C10G45/64
摘要： There is provided a zeolite bound zeolite catalyst which does not contain significant amount of non-zeolitic binder and can be tailored to optimize its performance and a process for converting hydrocarbons utilizing the zeolite bound zeolite catalyst. The zeolite bound zeolite catalyst comprises core crystals containing first crystals of a first zeolite and optionally second crystals of a second zeolite having a composition, structure type, or both that is different from said first zeolite and binder crystals containing third crystals of a third zeolite and optionally fourth crystals of a fourth zeolite having a composition, structure type, or both that is different from said third zeolite. If the core crystals do not contain the second crystals of the second zeolite, then the binder crystals must contain the fourth crystals of the fourth zeolite. The zeolite bound zeolite finds application in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportional of toluene, isomerization, and transalkylation reactions.
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