公开(公告)号：US20170051130A1

公开(公告)日：2017-02-23

申请号：US15345615

申请日：2016-11-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jennifer L. Cook ,  Tatsuo Fukushi ,  Werner M.A. Grootaert ,  Alain Verschuere

IPC: C08K5/3492 ,  C08K5/14

CPC classification number: C08K5/34924 ,  C08K5/0025 ,  C08K5/14 ,  C08K2003/2296 ,  C08L27/12

Abstract: Described herein are partially fluorinated elastomers and methods of curing comprising (i) a fluoroelastomer comprising interpolymerized units derived from (a) at least one hydrogen containing monomer and (b) at least one nitrile containing monomer, and (ii) a curing agent, wherein the curing agent consists essentially of a peroxide and a coagent.

Abstract translation: 本文描述的是部分氟化的弹性体和固化方法，其包括（i）包含衍生自（a）至少一种含氢单体和（b）至少一种含腈单体的共聚单元的含氟弹性体，和（ii）固化剂，其中 固化剂基本上由过氧化物和助剂组成。

公开(公告)号：US20160355623A1

公开(公告)日：2016-12-08

申请号：US15238889

申请日：2016-08-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Claude Lavallée ,  Gregg D. Dahlke ,  Denis Duchesne ,  Tatsuo Fukushi ,  Werner M.A. Grootaert ,  Miguel A. Guerra ,  Zai-Ming Qiu

IPC: C08F214/22 ,  C08L27/16

CPC classification number: C08F214/22 ,  C08L23/06 ,  C08L27/12 ,  C08L27/16 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2207/066 ,  C08F214/28 ,  C08F228/02

Abstract: Described herein is polymer melt additive composition for use as a processing aid in the extrusion of a non-fluorinated polymer, the polymer melt additive composition comprising a fluorine-containing polymer derived from the polymerization of a monomer and a sulfinate-containing molecule, wherein the sulfinate-containing molecule is selected from the group consisting of: (a) CX1X3═CX2—(R)p—CZ1Z2—SO2M  Formula (I) (b) Formula (II); and and (c) combinations thereof, wherein X1, X2, and X3 are each independently selected from H, F, Cl, a C1 to C4 alkyl group, and a C1 to C4 fluorinated alkyl group; R is a linking group; Z1 and Z2 are independently selected from F, CF3, and a perfluoroalkyl group; R1 and R2 are end-groups; p is 0 or 1; m is at least 2; and M is a cation.

公开(公告)号：US20160115294A1

公开(公告)日：2016-04-28

申请号：US14897155

申请日：2014-06-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Werner M.A. Grootaert

IPC: C08K5/00 ,  C08K3/04 ,  C08J7/12 ,  C08K5/50 ,  C08J3/24 ,  C08K3/36 ,  C08K5/19

CPC classification number: C08K5/0025 ,  C07F9/5407 ,  C08J3/24 ,  C08J7/12 ,  C08J2327/12 ,  C08K3/04 ,  C08K3/36 ,  C08K5/19 ,  C08K5/50 ,  C08L27/18

Abstract: A curative composition includes a tetraalkylphosphonium or tetraalkylammonium cation and an anion represented by Formula (Rf)3CO−, wherein each Rf is independently perfluoroalkyl having up to 12 carbon atoms. A fluoropolymer composition includes the curative composition and a fluoropolymer. The fluoropolymer can be an amorphous, curable fluoropolymer with nitrogen-containing cure sites. Shaped articles including the fluoropolymer, a method of making a fluoroelastomer article, and a method of making the curative composition are also described.

Abstract translation: 固化剂组合物包括四烷基鏻或四烷基铵阳离子和由式（Rf）3 CO-表示的阴离子，其中每个Rf独立地为具有至多12个碳原子的全氟烷基。 含氟聚合物组合物包括固化剂组合物和含氟聚合物。 含氟聚合物可以是具有含氮固化位点的无定形可固化含氟聚合物。 还描述了包括含氟聚合物的成型制品，制备含氟弹性体制品的方法和制备该固化剂组合物的方法。

公开(公告)号：US20160032087A1

公开(公告)日：2016-02-04

申请号：US14883690

申请日：2015-10-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Claude Lavallée ,  Gregg D. Dahlke ,  Denis Duchesne ,  Tatsuo Fukushi ,  Werner M.A. Grootaert ,  Miguel A. Guerra ,  Zai-Ming Qiu

IPC: C08L23/06

CPC classification number: C08F214/22 ,  C08L23/06 ,  C08L27/12 ,  C08L27/16 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2207/066 ,  C08F214/28 ,  C08F228/02

Abstract: Described herein is a melt-processible polymer composition comprising: a non-fluorinated melt-processible polymer; and a fluorine-containing polymer comprising an end-group having a structures from group consisting of: and combinations thereof; wherein X1, X2, and X3 are each independently selected from H, F, Cl, a C1 to C4 alkyl group, and a C1 to C4 fluorinated alkyl group; R7 is a linking group comprising at least 2 or more catenary atoms; and Z1 and Z2 are independently selected from F, CF3, and a perfluoroalkyl group.

Abstract translation: 本文描述的是可熔融加工的聚合物组合物，其包含：非氟化的可熔融加工的聚合物; 和包含具有以下结构的端基的含氟聚合物及其组合： 其中X 1，X 2和X 3各自独立地选自H，F，Cl，C1-C4烷基和C1-C4氟化烷基; R7是包含至少2个或更多个链状原子的连接基团; Z 1和Z 2独立地选自F，CF 3和全氟烷基。

公开(公告)号：US20150259450A1

公开(公告)日：2015-09-17

申请号：US14433005

申请日：2013-09-30

Applicant: Steven G. CORVELEYN ,  Gregg D. DAHLKE ,  Rudolf J. DAMS ,  Werner M.A. GROOTAERT ,  Miguel A. GUERRA ,  Anthony P. MANZARA ,  Tom OPSTAL ,  3M INNOVATIVE PROPERTIES COMPANY

Inventor： Steven G. Corveleyn ,  Gregg D. Dahlke ,  Rudolf J. Dams ,  Werner M.A. Grootaert ,  Miguel A. Guerra ,  Anthony P. Manzara ,  Tom Opstal

IPC: C08F122/38 ,  C09K3/10 ,  C08K3/16 ,  C08G65/00 ,  C08K3/36

CPC classification number: C08F122/38 ,  C08G18/5015 ,  C08G18/807 ,  C08G65/00 ,  C08G65/007 ,  C08G65/325 ,  C08G65/332 ,  C08G65/333 ,  C08G65/33365 ,  C08K3/16 ,  C08K3/36 ,  C08K5/0025 ,  C08K5/28 ,  C09K3/1009 ,  C09K2003/1053

Abstract: A curable precursor composition for a fluoroelastomers, methods of making fluoroelastomers, shaped articles and methods of making shaped articles.

Abstract translation: 用于含氟弹性体的可固化前体组合物，制备含氟弹性体的方法，成形制品以及制造成型制品的方法。

公开(公告)号：US20160083489A1

公开(公告)日：2016-03-24

申请号：US14784370

申请日：2014-06-10

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Werner M.A. Grootaert ,  Miguel A. Guerra

IPC: C08F214/18

CPC classification number: C08F214/184 ,  C08K5/14 ,  C08L27/12

Abstract: Described herein is a composition comprising a fluoropolymer derived from the polymerization of a polymerizable fluorinated olefnic monomer and a hydrocarbon olefin-containing perfluoro vinyl ether monomer selected from CF2═CFO—Rf—CH═CH2, wherein Rf is a perfluorinated group with the proviso that the Rf group does not comprise 2 or 3 catenated atoms between the oxygen atom of the vinyl ether group and the vinyl group.

Abstract translation: 本文描述的是一种组合物，其包含衍生自可聚合氟化烯烃单体和选自CF 2 = CFO-R f -CH 2 CH 2的含烃烯烃的全氟乙烯基醚单体的氟聚合物，其中Rf是全氟化基团，条件是 Rf基团在乙烯基醚基团的氧原子和乙烯基之间不包含2或3个连接的原子。

公开(公告)号：US20140288232A1

公开(公告)日：2014-09-25

申请号：US14355901

申请日：2012-11-07

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Werner M.A. Grootaert ,  Michael S. Wendland ,  George W. Griesgraber

IPC: C08F14/26 ,  C08K3/04

CPC classification number: C08F14/26 ,  C07C215/88 ,  C07C2603/94 ,  C08K3/04 ,  C08K5/18 ,  C08L27/00 ,  C08L27/18 ,  C08L27/12

Abstract: Diaminospirobisindane diols, curable compositions, curative compositions, cured articles, and methods of curing are described.

Abstract translation: 描述了二氨基螺双双茚二醇，可固化组合物，固化剂，固化制品和固化方法。

公开(公告)号：US20180319986A1

公开(公告)日：2018-11-08

申请号：US15774823

申请日：2016-11-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Claude Lavallée ,  Denis Duchesne ,  Werner M.A. Grootaert ,  Miguel A. Guerra

IPC: C08L101/04 ,  C08L101/12 ,  C08L81/08 ,  C08L67/04 ,  C08L23/08

CPC classification number: C08L101/04 ,  B29C47/0007 ,  B29C47/0023 ,  B29C47/20 ,  B29C47/40 ,  B29C47/92 ,  B29L2031/7172 ,  C08F6/22 ,  C08F214/22 ,  C08J3/226 ,  C08L23/08 ,  C08L23/0815 ,  C08L67/04 ,  C08L81/08 ,  C08L101/00 ,  C08L101/12 ,  C08L2203/30 ,  C08L2205/025 ,  C08L2205/06 ,  C08L101/02 ,  C08L27/12

Abstract: Described herein is a melt-processible polymer composition comprising: a non-fluorinated melt-processible polymer; and a fluorine-containing polymer comprising at least three —(SO3−)iM+i groups per polymer chain wherein M is a cation; and i is an integer.

公开(公告)号：US20150087863A1

公开(公告)日：2015-03-26

申请号：US14561800

申请日：2014-12-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Werner M.A. Grootaert ,  Kim M. Vogel ,  Dennis E. Vogel

IPC: C08F4/00

CPC classification number: C08F4/00 ,  B01J27/14 ,  B01J31/0201 ,  B01J31/0205 ,  B01J31/0234 ,  B01J31/0239 ,  B01J31/0268 ,  B01J2231/14 ,  C07C259/06 ,  C08F214/18 ,  C08F214/184 ,  C08K5/0025 ,  C08K5/05 ,  C08K5/19 ,  C08K5/29 ,  C08K5/315 ,  C08K5/50 ,  C08L27/12 ,  C08L27/18 ,  C08L2205/02

Abstract: Provided is a catalyst composition suitable for curing a fluoroelastomer, the catalyst composition comprising an anion of Formula III: wherein each Rf independently is selected from R—CF2 and a perfluoroalkyl group having from 1 to 8 carbon atoms. R is selected from H, a halogen, an alkyl group having up to 8 carbon atoms, an aryl group having up to 8 carbon atoms, and a cycloalkyl group having up to 8 carbon atoms. The subscript n is a positive integer. The catalyst composition is free of hydrocarbon containing alcohol. In specific instances, Rf may be CF3.

Abstract translation: 提供了适用于固化含氟弹性体的催化剂组合物，该催化剂组合物包含式III的阴离子：其中每个Rf独立地选自R-CF2和具有1至8个碳原子的全氟烷基。 R选自H，卤素，具有至多8个碳原子的烷基，具有至多8个碳原子的芳基和具有至多8个碳原子的环烷基。 下标n为正整数。 催化剂组合物不含含烃的醇。 在具体情况下，Rf可以是CF 3。

公开(公告)号：US20140378594A1

公开(公告)日：2014-12-25

申请号：US14364871

申请日：2012-12-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Claude Lavallée ,  Gregg D. Dahlke ,  Denis Duchesne ,  Tatsuo Fukushi ,  Werner M.A. Grootaert ,  Miguel A. Guerra ,  Zai-Ming Qiu

IPC: C08L23/06

CPC classification number: C08F214/22 ,  C08L23/06 ,  C08L27/12 ,  C08L27/16 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2207/066 ,  C08F214/28 ,  C08F228/02

Abstract: Described herein is a melt-processible polymer composition comprising: a non-fluorinated melt-processible polymer; and a fluoropolymer derived from the polymerization of a monomer and a sulfinate-containing molecule, wherein the sulfinate-containing molecule is selected from the group consisting of: (a) CX1X3═CX2—(R)p—CZ1Z2—SO2M Formula (I) (b) Formula (II); and (c) combinations thereof, wherein X1, X2, and X3 are each independently selected from H, F, Cl, a C1 to C4 alkyl group, and a C1 to C4 fluorinated alkyl group; R is a linking group; Z1 and Z2 are independently selected from F, CF3, and a perfluoroalkyl group; R1 and R2 are end-groups; p is 0 or 1; m is at least 2; and M is a cation.

Abstract translation: 本文描述的是可熔融加工的聚合物组合物，其包含：非氟化的可熔融加工的聚合物; 和衍生自单体和含亚磺酸酯的分子的聚合的含氟聚合物，其中所述含亚磺酸酯的分子选自：（a）CX1X3 = C2-（R）p-CZ1Z2-SO2M式（I） （b）式（II）; 和（c）其组合，其中X 1，X 2和X 3各自独立地选自H，F，Cl，C1至C4烷基和C1至C4氟化烷基; R是连接基团; Z 1和Z 2独立地选自F，CF 3和全氟烷基; R1和R2是端基; p为0或1; m至少为2; 而M是阳离子。