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公开(公告)号:US11646194B2
公开(公告)日:2023-05-09
申请号:US16794289
申请日:2020-02-19
申请人: ASM IP Holding B.V.
发明人: Antti Niskanen , Suvi Haukka , Jaakko Anttila
IPC分类号: H01L21/02 , C23C16/455 , C23C16/34
CPC分类号: H01L21/0217 , C23C16/345 , C23C16/4554 , C23C16/45553 , H01L21/0228 , H01L21/02211 , H01L21/02274
摘要: The present invention relates to methods of forming silicon nitride thin films on a substrate in a reaction chamber by plasma enhanced atomic layer deposition (PEALD). Exemplary methods include the steps of (i) introducing an octahalotrisilane Si3X8 silicon precursor, such as octachlorotrisilane (OCTS) Si3Cl8, into a reaction space containing a substrate, (ii) introducing a nitrogen containing plasma into the reaction space, and wherein steps (i), (ii) and any steps in between constitute one cycle, and repeating said cycles a plurality of times until an atomic layer nitride film having a desired thickness is obtained.
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公开(公告)号:US11081342B2
公开(公告)日:2021-08-03
申请号:US15581726
申请日:2017-04-28
申请人: ASM IP HOLDING B.V.
发明人: Elina Färm , Hidemi Suemori , Raija Matero , Antti Niskanen , Suvi P. Haukka , Eva Tois
IPC分类号: H01L21/02 , C23C16/40 , C23C16/455 , H01L21/32
摘要: Vapor deposition processes are provided in which a material is selectively deposited on a first surface of a substrate relative to a second organic surface. In some embodiments a substrate comprising a first surface, such as a metal, semi-metal or oxidized metal or semi-metal is contacted with a first vapor phase hydrophobic reactant and a second vapor phase reactant such that the material is deposited selectively on the first surface relative to the second organic surface. The second organic surface may comprise, for example, a self-assembled monolayer, a directed self-assembled layer, or a polymer, such as a polyimide, polyamide, polyuria or polystyrene. The material that is deposited may be, for example, a metal or metallic material. In some embodiments the material is a metal oxide, such as ZrO2 or HfO2. In some embodiments the vapor deposition process is a cyclic chemical vapor deposition (CVD) process or an atomic layer deposition (ALD) process. In some embodiments the material is deposited on the first surface relative to the second surface with a selectivity of greater than about 50%, greater than about 60%, greater than about 70%, greater than about 80%, greater than about 90% or greater than about 95%.
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公开(公告)号:US20200181766A1
公开(公告)日:2020-06-11
申请号:US16594365
申请日:2019-10-07
申请人: ASM IP Holding B.V.
发明人: Suvi P. Haukka , Raija H. Matero , Eva Tois , Antti Niskanen , Marko Tuominen , Hannu Huotari , Viljami J. Pore
IPC分类号: C23C16/04 , C23C16/40 , C23C16/22 , C23C16/18 , H01L21/768 , H01L21/285 , C23C16/56 , C23C16/455 , C23C16/30 , C23C16/06 , C23C16/02
摘要: Methods are provided for dual selective deposition of a first material on a first surface of a substrate and a second material on a second, different surface of the same substrate. The selectively deposited materials may be, for example, metal, metal oxide, or dielectric materials.
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公开(公告)号:US20200071828A1
公开(公告)日:2020-03-05
申请号:US16677446
申请日:2019-11-07
申请人: ASM IP Holding B.V.
发明人: Bert Jongbloed , Delphine Longrie , Robin Roelofs , Lucian Jdira , Suvi Haukka , Antti Niskanen , Jun Kawahara , Yukihiro Mori
IPC分类号: C23C16/455 , C23C16/458 , C23C16/52 , H01L21/02 , H01L21/285 , C23C16/54
摘要: In accordance with some embodiments herein, methods and apparatuses for deposition of thin films are provided. In some embodiments, a deposition reactor is provided comprising: a first station configured to contain a substrate, the first station comprising a first heating element; a second station configured to contain the substrate, the second station comprising a second heating element, wherein the first station is configured to contact the substrate with a first reactant in the first station in substantial isolation from the second station such that a layer of the first reactant is deposited on the substrate, wherein the first heating element is configured to heat the first station to a first station temperature during contacting of the substrate with the first reactant, wherein the second station is configured to contact the substrate with a second reactant in the second station substantially in the absence of the first reactant, and wherein the second heating element is configured to heat the second station to a second station temperature during contacting of the substrate with the second reactant, a transfer system; and a controller set to control a cycle of: moving the substrate via the transfer system to the first station, directing the first station to contact the substrate with the first reactant at the first station temperature, moving the substrate to the second station via the transfer system, and directing the second station to contact the substrate with the second reactant at the second station temperature, and further set to repeat the cycle until a film of desired thickness is formed on a surface of the substrate.
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公开(公告)号:US20220205088A1
公开(公告)日:2022-06-30
申请号:US17563158
申请日:2021-12-28
申请人: ASM IP Holding B.V.
发明人: Antti Niskanen
IPC分类号: C23C16/448 , C23C16/54 , C23C16/52 , C23C16/455
摘要: A precursor vessel for a vapor deposition process is disclosed. The vessel includes a housing having an inlet, an outlet, and defining an interior volume. A tube is disposed within the interior volume and extends from the inlet to the outlet. The tube has sidewalls defining a flowpath there through. The sidewalls have an internal surface facing the flowpath having a plurality of depressions in the internal surface having a depth and a width. A solid precursor material may be loaded into the depressions. A system including the precursor vessel and a vapor deposition process are further disclosed herein.
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公开(公告)号:US20220193720A1
公开(公告)日:2022-06-23
申请号:US17547083
申请日:2021-12-09
申请人: ASM IP HOLDING B.V.
发明人: Suvi P. Haukka , Raija H. Matero , Eva Tois , Antti Niskanen , Marko Tuominen , Hannu Huotari , Viljami J. Pore , Ivo Raaijmakers
IPC分类号: B05D3/10 , C23C18/06 , C23C18/12 , C23C16/02 , C23C16/04 , C23C16/14 , C23C16/18 , C23C16/28 , C23C16/40
摘要: Methods are provided for selectively depositing a material on a first surface of a substrate relative to a second, different surface of the substrate. The selectively deposited material can be, for example, a metal, metal oxide, or dielectric material.
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公开(公告)号:US20180243787A1
公开(公告)日:2018-08-30
申请号:US15877632
申请日:2018-01-23
申请人: ASM IP Holding B.V.
发明人: Suvi P. Haukka , Raija H. Matero , Eva Tois , Antti Niskanen , Marko Tuominen , Hannu Huotari , Viljami J. Pore , Ivo Raaijmakers
IPC分类号: B05D3/10 , C23C16/02 , C23C18/12 , C23C18/06 , C23C16/40 , C23C16/28 , C23C16/18 , C23C16/14 , C23C16/04
摘要: Methods are provided for selectively depositing a material on a first surface of a substrate relative to a second, different surface of the substrate. The selectively deposited material can be, for example, a metal, metal oxide, or dielectric material.
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公开(公告)号:US09895715B2
公开(公告)日:2018-02-20
申请号:US14612784
申请日:2015-02-03
申请人: ASM IP Holding B.V.
发明人: Suvi P. Haukka , Raija H. Matero , Eva Tois , Antti Niskanen , Marko Tuominen , Hannu Huotari , Viljami J. Pore , Ivo Raaijmakers
IPC分类号: C23C16/40 , B05D3/10 , C23C18/06 , C23C18/12 , C23C16/02 , C23C16/04 , C23C16/14 , C23C16/18 , C23C16/28
CPC分类号: B05D3/107 , C23C16/02 , C23C16/045 , C23C16/14 , C23C16/18 , C23C16/28 , C23C16/40 , C23C16/402 , C23C16/403 , C23C18/06 , C23C18/1208 , C23C18/1212 , C23C18/1216 , C23C18/122 , C23C18/1225 , C23C18/1245
摘要: Methods are provided for selectively depositing a material on a first surface of a substrate relative to a second, different surface of the substrate. The selectively deposited material can be, for example, a metal, metal oxide, or dielectric material.
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公开(公告)号:US11649546B2
公开(公告)日:2023-05-16
申请号:US16828753
申请日:2020-03-24
申请人: ASM IP Holding B.V.
发明人: Antti Niskanen , Eva Tois , Hidemi Suemori , Suvi Haukka
IPC分类号: C23C16/04 , C23C16/455 , C23C16/40 , C23C16/06
CPC分类号: C23C16/45525 , C23C16/04 , C23C16/06 , C23C16/40 , C23C16/45553
摘要: A method for selectively depositing a metal oxide film is disclosed. In particular, the method comprises pulsing a metal or semi-metal precursor onto the substrate and pulsing an organic reactant onto the substrate. A reaction between the metal or semi-metal precursor and the organic reactant selectively forms a metal oxide film on either a dielectric layer or a metal layer.
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公开(公告)号:US20210351031A1
公开(公告)日:2021-11-11
申请号:US17370263
申请日:2021-07-08
申请人: ASM IP HOLDING B.V.
发明人: Elina Färm , Hidemi Suemori , Raija H. Matero , Antti Niskanen , Suvi P. Haukka , Eva Tois
IPC分类号: H01L21/02 , C23C16/40 , H01L21/32 , C23C16/455
摘要: Vapor deposition processes are provided in which a material is selectively deposited on a first surface of a substrate relative to a second organic surface. In some embodiments a substrate comprising a first surface, such as a metal, semi-metal or oxidized metal or semi-metal is contacted with a first vapor phase hydrophobic reactant and a second vapor phase reactant such that the material is deposited selectively on the first surface relative to the second organic surface. The second organic surface may comprise, for example, a self-assembled monolayer, a directed self-assembled layer, or a polymer, such as a polyimide, polyamide, polyurea or polystyrene. The material that is deposited may be, for example, a metal or metallic material. In some embodiments the material is a metal oxide, such as ZrO2 or HfO2. In some embodiments the vapor deposition process is a cyclic chemical vapor deposition (CVD) process or an atomic layer deposition (ALD) process. In some embodiments the material is deposited on the first surface relative to the second surface with a selectivity of greater than about 50%, greater than about 60%, greater than about 70%, greater than about 80%, greater than about 90% or greater than about 95%.
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