Oxidative dehydrogenation and cracking of paraffins using a promoted
cobalt catalyst
    1.
    发明授权
    Oxidative dehydrogenation and cracking of paraffins using a promoted cobalt catalyst 失效
    使用促进的钴催化剂氧化脱氢和裂解石蜡

    公开(公告)号:US4835127A

    公开(公告)日:1989-05-30

    申请号:US658978

    申请日:1984-10-09

    摘要: A paraffin or mixture of paraffins having from 2 to 5 carbon atoms is oxidatively dehydrogenated in the presence of a cobalt based catalyst composition which has been calcined in the absence of oxygen. The catalyst composition comprises cobalt; phosphorus; at least one promoter selected from the group consisting of zinc, titanium, zirconium, niobium, indium, lead and bismuth; at least one alkali metal and oxygen. The catalyst composition may also contain sulfur and/or a halogen. If the feed to the oxidative dehydrogenation process contains paraffins having more than two carbon atoms, some cracking of such paraffins will also occur at the conditions at which the oxidative dehydrogenation process is carried out.

    摘要翻译: 在已经在不存在氧气的情况下煅烧的钴基催化剂组合物存在下,具有2至5个碳原子的链烷烃或链烷烃的混合物被氧化脱氢。 催化剂组合物包括钴; 磷; 选自锌,钛,锆,铌,铟,铅和铋的至少一种助催化剂; 至少一种碱金属和氧。 催化剂组合物还可以含有硫和/或卤素。 如果氧化脱氢方法的进料含有具有多于2个碳原子的链烷烃,则在进行氧化脱氢过程的条件下也会发生这种链烷烃的一些裂解。

    Oxidative dehydrogenation of paraffins
    4.
    发明授权
    Oxidative dehydrogenation of paraffins 失效
    石蜡氧化脱氢

    公开(公告)号:US4482646A

    公开(公告)日:1984-11-13

    申请号:US586503

    申请日:1984-03-05

    CPC分类号: C07C5/48 B01J23/04 B01J23/34

    摘要: An oxidative dehydrogenation process for a paraffin or mixture of paraffins having from 2 to 5 carbon atoms employing a catalyst composition comprising lithium and titanium. The selectivity of the catalyst composition may be improved by adding manganese to the catalyst composition.

    摘要翻译: 使用包含锂和钛的催化剂组合物的石蜡或具有2至5个碳原子的链烷烃混合物的氧化脱氢方法。 可以通过向催化剂组合物中加入锰来改善催化剂组合物的选择性。

    Method for producing lithium vanadium polyanion powders for batteries
    7.
    发明申请
    Method for producing lithium vanadium polyanion powders for batteries 审中-公开
    电池用锂钒聚阴离子粉末的制造方法

    公开(公告)号:US20080305256A1

    公开(公告)日:2008-12-11

    申请号:US12024038

    申请日:2008-01-31

    IPC分类号: B05D3/00 C01B25/45

    CPC分类号: H01M4/5825 C01B25/45

    摘要: This invention relates to a process for producing an improved cathode powder for making lithium ion batteries wherein the powder comprises lithium, vanadium and a polyanion. The process includes forming a solution-suspension of the precursors, which include vanadium pentoxide, with a reducing agent, a solvent, and a carbon-residue-forming material. The reducing agent causes the vanadium in vanadium pentoxide to reduce from V5+ to V3+. The solution-suspension is heated in an inert environment to drive the synthesis of the LVP (Li3V2(PO4)3) such that the carbon-residue-forming material is also oxidized to precipitate in and on the LVP forming carbon-containing LVP or CCLVP. The liquids are separated from the solids and the dry powder is heated to a second higher temperature to drive the crystallization of the product. The resulting product retains a small particle size, includes carbon in the LVP for conductivity and is created with very low cost precursors and avoids the need for milling or other processing to reduce the product to a particle size suitable for use in batteries. It also does not require the addition of carbon black, graphite or other form of carbon to provide the conductivity required for use in batteries.

    摘要翻译: 本发明涉及一种制备用于制备锂离子电池的改进的阴极粉末的方法,其中该粉末包括锂,钒和聚阴离子。 该方法包括形成包含五氧化二钒的前体与还原剂,溶剂和形成碳残留物的溶液的悬浮液。 还原剂使五氧化二钒中的钒从V5 +降低至V3 +。 将溶液 - 悬浮液在惰性环境中加热以驱动LVP(Li 3 V 2(PO 4)3)的合成),使得碳残留物形成材料也被氧化沉淀在LVP形成含碳的LVP或CCLVP中 。 将液体与固体分离,将干燥粉末加热至第二较高温度以驱使产物结晶。 所得到的产品保持小的粒度,包括LVP中的导电性碳,并且以非常低成本的前体产生,并且避免需要研磨或其它加工以将产品降低至适合用于电池的粒度。 它也不需要添加炭黑,石墨或其他形式的碳,以提供用于电池所需的电导率。