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公开(公告)号：US5866737A
公开(公告)日：1999-02-02
申请号：US779840
申请日：1997-01-07
IPC分类号： B01J8/00 , B01J8/24 , C07B33/00 , C07B35/04 , C07C5/42 , C07C253/26 , C07C253/28 , C07C5/09 , C07C5/327 , C07C5/333
CPC分类号： B01J8/1809 , B01J8/006 , B01J8/24 , C07B33/00 , C07B35/04 , C07C5/42 , B01J2208/00044 , B01J2208/00141 , B01J2208/00256 , B01J2208/00274 , Y02P20/584 , Y10S585/943
摘要： A process for the oxidation and oxidative dehydrogenation of hydrocarbons, in particular ethylbenzene, to form corresponding oxidized or olefinically unsaturated compounds, in particular styrene, over an oxygen-conferring, oxygen-regenerable catalyst involving a working period, a time-displaced regenerating period and at least one intermediate rinsing period comprises effecting a partial regeneration during the working period by time-displaced addition of a substoichiometric amount of oxygen.
摘要翻译： 一种用于烃，特别是乙苯的氧化和氧化脱氢以形成相应的氧化或烯属不饱和化合物，特别是苯乙烯的方法，该氧化或烯属不饱和化合物特别是涉及工作期的含氧赋氧催化剂，时间流逝的再生时间和 至少一个中间漂洗周期包括通过时间偏移加入亚化学计量的氧来在工作期间进行部分再生。
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2.发明授权Regeneration of catalysts used in oxidative dehydrogenation of alkylaromatics and paraffins 失效用于烷基芳烃和链烷烃的氧化脱氢催化剂的再生
公开(公告)号：US5691262A
公开(公告)日：1997-11-25
申请号：US542185
申请日：1995-10-12
IPC分类号： B01J23/08 , B01J23/10 , B01J23/14 , B01J23/48 , B01J23/70 , B01J38/12 , C07B35/04 , C07B61/00 , C07C5/42 , C07C11/02 , C07C15/46 , B01J38/32
CPC分类号： C07C5/42 , B01J38/12 , C07B35/04 , C07C2521/06 , C07C2523/26 , Y02P20/584
摘要： A regenerative process for the preparation of olefinically unsaturated compounds by oxidation/dehydrogenation of selectively oxidizable hydrocarbons over an oxygen carrier acting as catalyst, in the absence of molecular oxygen, alternating (in repeated cycles) with regeneration of the spent oxygen carrier with a gaseous molecular oxidizing agent, in which the spent (reduced) catalyst is cooled, prior to introduction of the regenerating gas, to a temperature which is below the temperature of the reaction, regeneration being controlled in such a manner that the highest temperature occurring during regeneration does not exceed the temperature of reaction at which dehydrogenation is commenced.
摘要翻译： 通过在不存在分子氧的情况下，在不存在分子氧的情况下，以氧气载体氧化/脱氢的氧选择性氧化烃氧化/脱氢制备烯属不饱和化合物的再生方法，与废氧载体与气态分子的再生交替（重复循环） 在将再生气体引入之前将已用（还原的）催化剂冷却的氧化剂达到低于反应温度的温度，再生被控制为使再生时发生的最高温度不再 超过开始脱氢反应的温度。
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公开(公告)号：US06211113B1
公开(公告)日：2001-04-03
申请号：US08711553
申请日：1996-09-10
申请人： Klaus Harth , Alfred Hagemeyer , Otto Watzenberger
发明人： Klaus Harth , Alfred Hagemeyer , Otto Watzenberger
IPC分类号： B01J2724
CPC分类号： B01J37/34 , B01J27/24 , B01J33/00 , B01J37/0238 , B01J37/0244 , Y10T428/12181 , Y10T428/2991 , Y10T428/2993
摘要： A layered catalyst support or carrier provides a core member for carrying out non-steady state heterogeneously catalyzed processes where reaction gases and their products come in contact with a conventional catalyst applied to the carrier. The support as a carrier is made up of a large number of individually shaped particulate bodies or monolithic packings to be loaded into a reactor and maintained as a fluidized bed or a fixed bed during the non-steady state reaction and the recovery of the products. The support or carrier may consist of glass, quartz, oxides, nitrides, aluminosilicates, magnesium silicates, metals and carbon or their mixtures. Each shaped particle or monolithic packing of this core support is then completely enclosed by depositing thereon a thin protective layer of a nitride, oxide, carbide or chloride of a metal, a non-metal or a mixture thereof, which exhibits a dense, pore-free microstructure and a nonpolar surface having a very low density of acid centers. This outer layer is applied to the core support by a plasma-assisted gas phase deposition. The catalytically active layer is then applied to this protective layer.
摘要翻译： 层状催化剂载体或载体提供用于进行非稳态异质催化方法的芯构件，其中反应气体及其产物与施加到载体上的常规催化剂接触。 作为载体的载体由大量单独形状的颗粒体或整体填料组成，以在非稳态反应和产物的回收期间装载到反应器中并保持为流化床或固定床。 载体或载体可以由玻璃，石英，氧化物，氮化物，铝硅酸盐，硅酸镁，金属和碳或它们的混合物组成。 然后，通过在其上沉积金属，非金属或它们的混合物的氮化物，氧化物，碳化物或氯化物的薄保护层，将这种芯支撑体的每个成形颗粒或整体式填料完全封闭， 自由微结构和具有非常低的酸中心密度的非极性表面。 通过等离子体辅助气相沉积将该外层施加到芯支撑体上。 然后将催化活性层施加到该保护层。
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公开(公告)号：US5780700A
公开(公告)日：1998-07-14
申请号：US527683
申请日：1995-09-13
IPC分类号： C07B31/00 , C07B35/04 , C07B61/00 , C07C2/84 , C07C5/333 , C07C5/42 , C07C11/02 , C07C15/44 , C07C45/28 , C07C45/65 , C07C51/377 , C07C57/055 , C07C67/39 , C07C253/26 , C07C5/09
CPC分类号： C07B35/04 , C07C2/84 , C07C45/28 , C07C45/65 , C07C5/42 , C07C51/377 , C07C67/39 , C07C2521/06 , C07C2523/26 , Y02P20/584
摘要： A process for the preparation of olefinically unsaturated compounds by catalytic oxidation, ie oxidative dehydrogenation by transferring oxygen from a previously oxidized oxygen carrier acting as catalyst, in the absence of molecular oxygen, the catalyst being regenerated after exhaustion, wherein, during the operating phase of the catalyst (oxidation/dehydration partial step), the residence time, space velocity and/or temperature of the reactants in the reactor is/are adjusted, ie, controlled, continuously or in discrete steps, in a manner appropiate to the momentary state of activity of the redox catalyst by adjusting--continuously or stepwise--the residence time of the reactants in the freshly regenerated catalyst (ie at the commencement of the reaction) to a shorter time, and/or the temperature to a lower value, than the corresponding parameter(s) in the partially reduced catalyst.
摘要翻译： 一种通过催化氧化制备烯属不饱和化合物的方法，即通过在不存在分子氧的情况下，将氧气从作为催化剂的氧化氧载体中转移而进行的氧化脱氢，该催化剂在耗尽后再生，其中，在操作阶段 催化剂（氧化/脱水部分步骤），反应器中的反应物的停留时间，空间速度和/或温度被调整，即以适当的方式适当地连续或以离散步骤控制 通过将新鲜再生催化剂中的反应物（即反应开始时）的停留时间连续或逐步调节至较短时间和/或温度降至较低值的氧化还原催化剂的活性， 部分还原催化剂中的参数。
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5.发明申请公开(公告)号：US20110162484A1
公开(公告)日：2011-07-07
申请号：US13063321
申请日：2009-09-02
申请人： Jochen Steiner , Ekkehard Schwab , Andreas Keller , Otto Watzenberger , Ulrich Grässle , Manfred Julius
发明人： Jochen Steiner , Ekkehard Schwab , Andreas Keller , Otto Watzenberger , Ulrich Grässle , Manfred Julius
IPC分类号： B22F9/22
CPC分类号： B01J23/745 , B01J23/78 , B01J37/086 , C07C1/044 , C07C2523/745 , C10G2/332 , C10G2400/20 , C10J3/00 , C10J2300/0916 , C10J2300/093 , C10J2300/1659 , C10K1/00 , Y02P20/125 , Y02P20/145 , Y02P20/52 , C07C11/02
摘要： Integrated process, in which pure carbonyl iron powder (CIP) is prepared by decomposition of pure iron pentacarbonyl (IPC) in a plant A, carbon monoxide (CO) liberated in the decomposition of the IPC is used in plant A for the preparation of further CIP from iron or is fed to an associated plant B for the preparation of synthesis gas or is fed to an associated plant C for the preparation of hydrocarbons from synthesis gas, and the CIP prepared in plant A is used as catalyst or catalyst component in an associated plant C for the preparation of hydrocarbons from synthesis gas from plant B.
摘要翻译： 通过在植物A中分解纯铁五羰基（IPC）制备纯羰基铁粉（CIP）的综合方法，在植物A中使用在IPC分解中释放出的一氧化碳（CO）用于制备进一步的 将CIP从铁中加入到相关联的工厂B中用于制备合成气，或者将其进料到合成工厂C用于从合成气制备烃，并将在工厂A中制备的CIP用作催化剂或催化剂组分 联合植物C用于从植物B的合成气制备烃。
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公开(公告)号：US06190567B1
公开(公告)日：2001-02-20
申请号：US09327968
申请日：1999-06-08
IPC分类号： C02F172
CPC分类号： C02F1/76 , C02F1/722 , Y10S210/903
摘要： A process for breaking down hydroxylamine in aqueous solutions, especially wastewaters, by treatment with an oxidizing agent, which comprises using as said oxidizing agent an alkali metal hypohalite or alkaline earth metal hypohalite or peroxomonosulfuric or peroxodisulfuric acid or a salt thereof and carrying out the treatment with said oxidizing agent at a pH
摘要翻译： 一种通过用氧化剂处理来分解水溶液，特别是废水中的羟胺的方法，其包括使用碱金属次卤酸盐或碱土金属次卤酸盐或过硫酸或过氧二硫酸或其盐，并进行处理 所述氧化剂在pH <8。
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公开(公告)号：US20050135987A1
公开(公告)日：2005-06-23
申请号：US10992777
申请日：2004-11-22
CPC分类号： C01G49/16
摘要： Iron pentacarbonyl is prepared by reacting iron with carbon monoxide in suspension and in the presence of a polysulfide of the general formula RSxR′ as a catalyst, where R is an organic radical and x is a number from 2 to 8.
摘要翻译： 铁五羰基通过使铁与一氧化碳在悬浮液中反应并在通式为RS x R R'的多硫化物的存在下反应制备，其中R是有机基团，x是从 2到8。
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公开(公告)号：US6153799A
公开(公告)日：2000-11-28
申请号：US445186
申请日：1999-12-08
CPC分类号： C01B21/1481 , C01B21/1445 , C01B21/1463
摘要： A very pure aqueous solution of free hydroxylamine is prepared by a process in which the dilute, aqueous hydroxylamine solution is concentrated in a column by removing hydroxylamine-containing vapors via a side take-off in the bottom of the column, and very pure hydroxylamine is obtained by condensing the vapors. The novel process can be carried out simply, in a gentle manner and on a large scale and gives electronic grade hydroxylamine.
摘要翻译： PCT No.PCT / EP98 / 03714 Sec。 371 1999年12月8日第 102（e）日期1999年12月8日PCT提交1998年6月18日PCT公布。 公开号WO98 / 57886 日期1998年12月23日非常纯的游离羟胺水溶液是通过一种方法制备的，其中通过在柱底部的侧排料除去含羟胺的蒸气将稀的羟胺水溶液浓缩在柱中， 并且通过冷凝蒸气获得非常纯的羟胺。 该新方法可以简单地以温和的方式大规模进行，并得到电子级羟胺。
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公开(公告)号：US08608824B2
公开(公告)日：2013-12-17
申请号：US13063321
申请日：2009-09-02
申请人： Jochen Steiner , Ekkehard Schwab , Andreas Keller , Otto Watzenberger , Ulrich Gräβle , Manfred Julius
发明人： Jochen Steiner , Ekkehard Schwab , Andreas Keller , Otto Watzenberger , Ulrich Gräβle , Manfred Julius
CPC分类号： B01J23/745 , B01J23/78 , B01J37/086 , C07C1/044 , C07C2523/745 , C10G2/332 , C10G2400/20 , C10J3/00 , C10J2300/0916 , C10J2300/093 , C10J2300/1659 , C10K1/00 , Y02P20/125 , Y02P20/145 , Y02P20/52 , C07C11/02
摘要： Integrated process, in which pure carbonyl iron powder (CIP) is prepared by decomposition of pure iron pentacarbonyl (IPC) in a plant A, carbon monoxide (CO) liberated in the decomposition of the IPC is used in plant A for the preparation of further CIP from iron or is fed to an associated plant B for the preparation of synthesis gas or is fed to an associated plant C for the preparation of hydrocarbons from synthesis gas, and the CIP prepared in plant A is used as catalyst or catalyst component in an associated plant C for the preparation of hydrocarbons from synthesis gas from plant B.
摘要翻译： 通过在植物A中分解纯铁五羰基（IPC）制备纯羰基铁粉（CIP）的综合方法，在植物A中使用在IPC分解中释放出的一氧化碳（CO）用于制备进一步的 将CIP从铁中加入到相关联的工厂B中用于制备合成气，或者将其进料到合成工厂C用于从合成气制备烃，并将在工厂A中制备的CIP用作催化剂或催化剂组分 联合植物C用于从植物B的合成气制备烃。
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公开(公告)号：US06328941B1
公开(公告)日：2001-12-11
申请号：US09480690
申请日：2000-01-11
申请人： Otto Watzenberger , David Agar
发明人： Otto Watzenberger , David Agar
IPC分类号： B01D5354
CPC分类号： B01D53/005 , B01D53/56 , B01D2257/402 , C01B21/22 , F23G7/06 , F28D17/00 , F28D19/00 , F28D21/001 , Y02C20/10 , Y02E20/12 , Y02P20/129 , Y02P20/133 , Y02P20/153
摘要： Recuperative heat exchangers or regenerative heat exchangers are used for the thermal decomposition of N2O in N2O-containing gases. The process for the thermal decomposition of N2O in N2O-containing gases at from 800 to 1200° C. comprises passing the N2O-containing gas through one or more recuperative heat exchangers or regenerative heat exchangers in such a way that when the gas to be reacted is passed through a charge of heat transfer material it is heated to a temperature in the range from 800 to 1200° C. and the N2O present is decomposed thermally, and cooling the reacted gas by heat exchange so as to heat the charge of heat transfer material and the gas to be reacted.
摘要翻译： 再生热交换器或再生热交换器用于N2O在含N2O气体中的热分解。 800℃〜1200℃，含N2O的气体中N2O的热分解过程包括使含N2O的气体通过一个或多个再生热交换器或再生式热交换器，使得当待反应的气体 通过传热材料的加料，将其加热到800〜1200℃的温度，并且使N2O存在热分解，并通过热交换冷却反应气体，以加热传热装料 材料和待反应的气体。
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