公开(公告)号：US07553477B2

公开(公告)日：2009-06-30

申请号：US11517949

申请日：2006-09-08

申请人： Avelino Corma Canós ,  María José Sabater Picot ,  Fernando Rey García ,  Susana Valencia Valencia

发明人： Avelino Corma Canós ,  María José Sabater Picot ,  Fernando Rey García ,  Susana Valencia Valencia

IPC分类号： C01B39/48 ,  C01B39/46 ,  C01B39/04

CPC分类号： C01B39/06 ,  B01J29/04 ,  C01B37/02 ,  C01B39/145

摘要： The invention relates to a material which, once calcined and in the anhydrous state has general formula x (M1/n XO2):z ZO2:y GeO2:(1−y) SiO2, wherein x has a value of less than 0.2, preferably less than 0.15 and can equal zero; z has a value of between 0 and 0.1, preferably between 0 and 0.05; y has a value of between 0 and 1, preferably between 0 and 0.75; M represents one or more +n charged inorganic cations; X represents one or more +3 oxidation state chemical elements (Al, B, Ga, Fe); and Z represents one or more +4 oxidation state cations different from silicon and germanium, preferably Ti or Sn. Said material can be used as a component of catalysts in acid catalysis processes or as a metal or oxide support in separation and absorption/adsorption processes.

摘要翻译： 本发明涉及一旦煅烧并且处于无水状态的材料具有通式x（M1 / n XO2）：z ZO 2：y GeO 2：（1-y）SiO 2，其中x的值小于0.2，优选 小于0.15，可以等于零; z的值在0和0.1之间，优选在0和0.05之间; y的值在0和1之间，优选在0和0.75之间; M表示一个或多个带+ n的无机阳离子; X表示一种或多种+3氧化态化学元素（Al，B，Ga，Fe）; Z表示与硅和锗不同的一种或多种+4氧化态阳离子，优选为Ti或Sn。 所述材料可用作酸催化方法中的催化剂组分或用作分离和吸收/吸附方法中的金属或氧化物载体。

公开(公告)号：US07344697B2

公开(公告)日：2008-03-18

申请号：US11392473

申请日：2006-03-29

申请人： Avelino Corma Canós ,  María José Sabater Picot ,  Susana Valencia Valencia

发明人： Avelino Corma Canós ,  María José Sabater Picot ,  Susana Valencia Valencia

IPC分类号： C01B39/46 ,  C01B39/48

CPC分类号： C01B37/005 ,  B01J29/035 ,  B01J29/70 ,  B01J29/87 ,  B01J29/89 ,  C01B37/02 ,  C01B39/065 ,  C01B39/48

摘要： The invention relates to a microporous crystalline zeolite material, zeolite ITQ-28, the production method thereof and the use of same. More specifically, the invention relates to a microporous crystalline zeolite material, ITQ-28, which, in the calcined state and in the absence of defects in the crystalline lattice thereof, manifested by the presence of silanols, is characterised by having empirical formula x (M1/nXO2): y YO2: SiO2, wherein: M is selected from H+, at least one inorganic cation with charge +n, preferably alkalines or alkaline earths, and a mixture of both; X is at least one chemical element in oxidation state +3, preferably Al, Ga, B, Fe, Cr or mixtures thereof; Y is at least a chemical element in oxidation state +4, which is different from Si, preferably Ge, Ti, Sn, V or mixtures of same; x has a value of between 0 and 0.2 inclusive; and y has a value of between 0 and 0.1 inclusive. The invention is further characterised in that the material as it is synthesised has an x-ray diffraction pattern with at least values of angle 2θ (degrees) and the relative intensities given in table 1. The invention also relates to the method of preparing said material and to the use thereof in the conversion of organic compounds.

摘要翻译： 本发明涉及微孔结晶沸石材料，沸石ITQ-28，其制备方法及其用途。 更具体地说，本发明涉及一种微孔结晶沸石材料ITQ-28，其在煅烧状态中并且在其不存在其晶格缺陷的情况下，通过硅烷醇的存在而表现出来，其特征在于具有经验式x（ M 1 / n 2 XO 2）：y Y 2 O 2 SiO 2其中：M选自H 至少一种带电荷的无机阳离子，优选碱金属或碱土金属，以及二者的混合物; X是氧化态+3，优选Al，Ga，B，Fe，Cr或其混合物中的至少一种化学元素; Y至少是氧化态+4的化学元素，其不同于Si，优选Ge，Ti，Sn，V或其混合物; x的值在0和0.2之间; y的值在0和0.1之间。 本发明的特征还在于其合成的材料具有x射线衍射图，其至少具有角度2θ（度）和表1中给出的相对强度。本发明还涉及制备所述材料的方法 以及其在有机化合物的转化中的用途。

公开(公告)号：US07014836B2

公开(公告)日：2006-03-21

申请号：US10750329

申请日：2003-12-31

申请人： Avelino Corma Canós ,  Fernando Rey García ,  María Teresa Navarro Villalba ,  Susana Valencia Valencia

发明人： Avelino Corma Canós ,  Fernando Rey García ,  María Teresa Navarro Villalba ,  Susana Valencia Valencia

IPC分类号： C01B39/48

CPC分类号： B01J29/70 ,  B01J29/035 ,  B01J29/04 ,  C01B37/005 ,  C01B39/06 ,  Y10S423/27

摘要： The present invention refers to a crystalline material that does not contain fluorides, with a composition in a roasted state corresponding to that of the material called ITQ-17 and that has a composition on an anhydrous base and in terms of oxide moles upon being synthesized, unroasted, represented by: xX2O3:(1−z)YO2:zGeO2:r/nRnO wherein: X is at least one trivalent element, Y is one or more tetravalent elements other than germanium, R is an organic structure directing compound, preferably the cation 1-methyl-4-aza,1-azoniumbicyclo[2.2.2]octane (DABMe+) or the cation 1,4-bis[N-(4-aza,1-azoniumbicyclo[2.2.2]octane)methyl]benzene (d-DABBz)+2 x varies between 0 and 0.02, z is comprised between 0.02 and 0.67, r varies between 0.01 and 0.5, and n is 1 or 2. It also refers to a process for synthesizing said material, as well as to the material obtained by said process and subjected to a step of post-synthesis to eliminate the organic component from its structure.

摘要翻译： 本发明涉及不含氟化物的结晶材料，其组成为与称为ITQ-17的材料相当的焙烧状态，其组成为无水碱和合成后的氧化物摩尔数， 未加工的，由以下代表：<？in-line-formula description =“In-line Formulas”end =“lead”？> xX 2 3（1-z ）YO 2：zGeO 2：r / n R n +2X在0和0.02之间变化，z在0.02和0.67之间，r在0.01和0.5之间变化，n是1或2.它也是指sy 使所述材料固化，以及通过所述方法获得的材料，并进行后合成步骤以从其结构中除去有机组分。

公开(公告)号：US07056489B2

公开(公告)日：2006-06-06

申请号：US10632535

申请日：2003-08-01

申请人： Avelino Corma Canós ,  Teresa Navarro Villalba ,  Susana Valencia Valencia ,  Fernando Rey García

发明人： Avelino Corma Canós ,  Teresa Navarro Villalba ,  Susana Valencia Valencia ,  Fernando Rey García

IPC分类号： C01B39/48

CPC分类号： C10G11/05 ,  B01J29/04 ,  C01B37/005 ,  C01B39/023 ,  C01B39/08 ,  C10G47/16 ,  Y10S423/27

摘要： The invention relates to a method for synthesizing a family of zeolite materials, grouped together under the name ITQ-16, in an OH− medium and in the absence of fluorides and to the catalytic applications thereof. The zeolite ITQ-16 family of materials is characterized by having different proportions of distinct polymorphs A, B and C described as possible intergrowths in the Beta zeolite and, therefore, the X-ray diffraction patterns of said family are different from that described for the Beta zeolite. In its calcinated form, zeolite ITQ-16 has the following empirical formula: x(MXO2):tTO2:gGeO2:(1−g)SiO2, wherein T is one or more elements having +4 oxidation status and different from Ge and Si; X is one or more elements having +3 oxidation status; and M can be H+ or one or more inorganic cations with a +n charge.

摘要翻译： 本发明涉及一种用于合成沸石材料族的一种方法，该材料族以名称ITQ-16，在OH - 介质中和在不存在氟化物的情况下分组在一起，以及其催化应用。 沸石ITQ-16系列材料的特征在于具有不同比例的不同的多晶型物A，B和C作为β沸石中可能的共生生长而被描述，因此，所述族的X射线衍射图不同于对于 β沸石。 在其煅烧形式中，沸石ITQ-16具有以下经验式：x（MXO 2 2）：tTO 2：gGeO 2：（1 -g）SiO 2，其中T是具有+4氧化状态并且不同于Ge和Si的一种或多种元素; X是具有+3氧化状态的一种或多种元素; 并且M可以是H + +或一种或多种具有+ n电荷的无机阳离子。

公开(公告)号：US06916459B2

公开(公告)日：2005-07-12

申请号：US10412624

申请日：2003-04-11

申请人： Avelino Corma Canós ,  Maria Teresa Navarro Villalba ,  Fernando Rey García ,  Susana Valencia Valencia

发明人： Avelino Corma Canós ,  Maria Teresa Navarro Villalba ,  Fernando Rey García ,  Susana Valencia Valencia

IPC分类号： B01D53/86 ,  B01J29/04 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  B01J35/10 ,  C01B39/02 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C01B39/48 ,  C07B61/00 ,  C07C2/66 ,  C07C45/29 ,  C07C45/33 ,  C07C45/46 ,  C10G11/02 ,  C10G11/05 ,  C10G29/20 ,  C10G45/64 ,  C10G47/16

CPC分类号： C10G47/16 ,  B01J29/04 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  B01J35/002 ,  C01B39/023 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C01B39/48 ,  C07C2/66 ,  C07C45/29 ,  C07C45/294 ,  C07C45/33 ,  C07C45/46 ,  C10G11/05 ,  C10G29/205 ,  C10G45/64 ,  Y02C20/30 ,  Y02P20/52 ,  C07C15/085

摘要： This invention refers to a new zeolitic material included under the ITQ-16 denomination, to the method for obtaining them and their use as catalysts.This material, ITQ-16 zeolite, is characterized by having different ratios of the different polymorphs A, B and C described as possible intergrowths in Beta zeolite and which, therefore, show different X-ray diffraction patterns to that described for Beta zeolite, showing the X-ray diffraction pattern for ITQ-16, as it is synthesised, diffraction peaks at 2θ angles of 6.9°, 7.4°, and 9.6°, simultaneously.ITQ-16 zeolite in its calcinated form has the following empiric formula: x(M1/nXO2):tTO2:gGeO2:(1−g)SiO2 where T is one or various elements with +4 oxidation status, different of Ge and Si; X is one or various elements with +3 oxidation status and M can be H+ or one or various inorganic cations with charge +n, t is comprised between 0 and 0.1, g is comprised between 0.001 and 0.33 and x is comprised between 0 and 0.2.

摘要翻译： 本发明涉及包含在ITQ-16面额内的新型沸石材料，其获得方法及其作为催化剂的用途。 该材料，ITQ-16沸石的特征在于具有不同比例的不同的多晶型物A，B和C作为β沸石中可能的共生生长，因此与β沸石所述的X射线衍射图不同，显示出 合成了ITQ-16的X射线衍射图，同时在2θ角为6.9°，7.4°和9.6°的衍射峰。 其煅烧形式的ITQ-16沸石具有以下经验公式：<？in-line-formula description =“In-line Formulas”end =“lead”？> x（M 1 / n XO 2→2→1：gGeO 2：（1-g）SiO 2-β-in-in-line-2 公式描述=“在线公式”end =“tail”？>其中T是具有+4氧化状态，Ge和Si不同的一种或多种元素; X是具有+3氧化状态的一种或各种元素，M可以是H + +或一种或多种带电荷+ n的无机阳离子，t在0和0.1之间，g在0.001和0.33之间 并且x在0和0.2之间。

公开(公告)号：US07449169B2

公开(公告)日：2008-11-11

申请号：US10996182

申请日：2004-11-23

申请人： Avelino Corma Canós ,  Fernando Rey García ,  Susana Valencia Valencia ,  Luis Joaquín Martinez Triguero

发明人： Avelino Corma Canós ,  Fernando Rey García ,  Susana Valencia Valencia ,  Luis Joaquín Martinez Triguero

IPC分类号： C01B39/46 ,  C01B39/48 ,  B01J29/80 ,  B01J29/70

CPC分类号： C10G29/205 ,  B01J29/04 ,  B01J29/89 ,  C01B37/02 ,  C01B39/06 ,  C01B39/08 ,  C10G45/64 ,  C10G50/00

摘要： The present invention refers to a microporous crystalline material of zeolitic nature (ITQ-22) which, in the calcined state, has the empirical formula x(M1/nX02):yYO2:zR:wH20wherein M is H+ or at least one inorganic cation of charge +n; X is at least one chemical element of oxidation state +3, preferably selected from the group consisting of Al, Ga, B, Fe and Cr; Y is at least one chemical element with oxidation state +4 other than Si and Ge, preferably selected from the group consisting of Ti, Sn and V; x has a value less than 0.2, preferably less than 0.1 and can take the value zero, y has a value less than 0.1, preferably less than 0.05 and can take the value zero, z has a value less than 0.8, preferably between 0.005 and 0.5 and can take the value zero, with a characteristic X-ray diffraction pattern, to the method of preparation and to the use of the material in separation and transformation processes of organic compounds.

摘要翻译： 本发明涉及沸石性质的微孔结晶材料（ITQ-22），其在煅烧状态下具有经验式x（M1 / nX02）：yYO2：zR：wH20其中M为H +或至少一种无机阳离子 的收费+ n; X是氧化态+3的至少一种化学元素，优选选自Al，Ga，B，Fe和Cr; Y是至少一种氧化态除了Si和Ge以外的化合物，优选选自Ti，Sn和V; x的值小于0.2，优选小于0.1，并且可以取零值，y的值小于0.1，优选小于0.05，并且可以取零值，z的值小于0.8，优选为0.005和 0.5，并且可以使用特征X射线衍射图，将零值作为制备方法和在有机化合物的分离和转化过程中使用该材料。

公开(公告)号：US07582278B2

公开(公告)日：2009-09-01

申请号：US11883354

申请日：2006-01-26

申请人： Avelino Corma Canós ,  Ángel Cantín Sanz ,  Fernando Rey García ,  Susana Valencia Valencia ,  Sandra Leiva Herrero

发明人： Avelino Corma Canós ,  Ángel Cantín Sanz ,  Fernando Rey García ,  Susana Valencia Valencia ,  Sandra Leiva Herrero

IPC分类号： C01B39/46 ,  C01B39/48

CPC分类号： C01B37/02 ,  B01J20/18 ,  B01J29/70 ,  C01B39/06 ,  C01B39/065 ,  C01B39/082 ,  C01B39/12 ,  C01B39/48

摘要： The invention relates to a microporous crystalline zeolite material which, in the calcined state and in the absence of defects in the crystalline lattice thereof, manifested by the presence of silanols, has empirical formula x(M1/nXO2):yYO2:SiO2, in which M is selected from among H+, at least one inorganic cation with charge +n and a mixture of both; X is at least one chemical element in oxidation state +3; Y is at least one chemical element in oxidation state +4, which is different from Si, x has a value of between 0 and 0.2 inclusive, and y has a value of between 0 and 0.1 inclusive. In addition, as it is synthesised, and in the calcined state, the material has a characteristic X-ray diffraction pattern known as ITQ-32. The invention also relates to the method of preparing said material and to the use thereof.

摘要翻译： 本发明涉及一种微孔结晶沸石材料，其在煅烧状态下并且在不存在其晶格缺陷的情况下，由硅烷醇的存在表现出，具有经验式x（M1 / nXO2）：yYO2：SiO2，其中 M选自H +，至少一种电荷+ n的无机阳离子和两者的混合物; X是至少一种氧化态的化学元素+3; Y是氧化态+4中的至少一种化学元素，其与Si不同，x具有在0和0.2之间的值，包括0和0.2之间，y的值在0和0.1之间。 此外，如合成，并且在煅烧状态下，该材料具有称为ITQ-32的特征X射线衍射图。 本发明还涉及制备所述材料的方法及其用途。

公开(公告)号：US06896869B2

公开(公告)日：2005-05-24

申请号：US10412641

申请日：2003-04-11

申请人： Avelino Corma Canós ,  María Teresa Navarro Villalba ,  Fernando Rey García ,  Susana Valencia Valencia

发明人： Avelino Corma Canós ,  María Teresa Navarro Villalba ,  Fernando Rey García ,  Susana Valencia Valencia

IPC分类号： B01J29/04 ,  B01J29/70 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  C01B39/06 ,  C01B39/08 ,  C01B39/46 ,  C01B39/48 ,  C10G11/05 ,  C10G29/20 ,  C10G45/64 ,  C10G47/16

CPC分类号： C10G45/64 ,  B01J29/04 ,  B01J29/046 ,  B01J29/70 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48 ,  C10G11/05 ,  C10G29/205 ,  C10G47/16

摘要： A microporous crystalline material of a zeolitic nature, that corresponds to the empirical formula x(M1/nXO2):yYO2:zGeO2:(1−z)TO2 wherein x has a value between 0 and 0.2; y has a value between 0 and 0.1; z has a value between 0 and 0.67; being at least one of the z, x and y above zero; M is selected between H+ and inorganic cations with a +n charge; X is at least one chemical element with a +3 oxidation status; Y is at least one chemical element with a +4 oxidation status; and T is at least one chemical element with a +4 oxidation status; and is also characterised by its X-ray diffraction pattern and its microporous properties, and can be employed as a catalyst or oxidating agent in the separation and transformation of organic compounds.

摘要翻译： 沸石性质的微孔结晶材料，其对应于经验公式<？in-line-formula description =“In-line Formulas”end =“lead”？> x（M 1 / n） XO 2 2）：y Y 2 2：zGeO 2：（1-z）2＆lt; 2＆lt;＆gt;＆lt; -formulae description =“In-line Formulas”end =“tail”？>其中x的值介于0和0.2之间; y的值在0到0.1之间; z的值介于0和0.67之间; 是z，x和y中的至少一个高于零; 在H +和无机阳离子之间选择一个+ n电荷; X是至少一种具有+3氧化状态的化学元素; Y是至少一种具有+4氧化状态的化学元素; 和T是具有+4氧化状态的至少一种化学元素; 并且其特征在于其X射线衍射图及其微孔性质，并且可用作有机化合物的分离和转化中的催化剂或氧化剂。

公开(公告)号：US06306364B1

公开(公告)日：2001-10-23

申请号：US09407652

申请日：1999-09-28

申请人： Susana Valencia Valencia ,  Avelino Corma Canós

发明人： Susana Valencia Valencia ,  Avelino Corma Canós

IPC分类号： C01B3908

CPC分类号： C01B39/085 ,  Y10S423/27

摘要： A new family of stannosilicate molecular sieves which have the zeolite beta structure are disclosed. These molecular sieves have a three dimensional framework structure composed of SnO2 and SiO2 tetrahedral oxide units and at least one of TiO2 or GeO2 tetrahedral oxide units and have an empirical formula of: (SnxTiySi1-x-y-zGez)2 where “x”, “y” and “z” are the mole fractions of tin, titanium and germanium respectively (“y” and “z” are not simultaneously zero). Processes for the selective oxidation of organic compounds with peroxides using the molecular sieves as catalysts is also presented.

摘要翻译： 公开了一种具有沸石β结构的新硅酸硅烷分子筛族。 这些分子筛具有由SnO 2和SiO 2四面体氧化物单元和TiO 2或GeO 2四面体氧化物单元中的至少一种组成的三维骨架结构，并且具有以下经验式：其中“x”，“y”和“z” 锡，钛和锗的分数（“y”和“z”不是同时为零）。 还提出了使用分子筛作为催化剂用过氧化物选择性氧化有机化合物的方法。

公开(公告)号：US07611623B2

公开(公告)日：2009-11-03

申请号：US11662762

申请日：2005-09-15

申请人： Avelino Corma Canós ,  Fernando Rey Garcia ,  Susana Valencia Valencia

发明人： Avelino Corma Canós ,  Fernando Rey Garcia ,  Susana Valencia Valencia

IPC分类号： C07C7/13 ,  B01D53/85 ,  B01D53/86

CPC分类号： C07C7/12 ,  B01D53/02 ,  B01D2253/108 ,  B01D2257/702 ,  B01D2257/80 ,  C01B39/145

摘要： The invention relates to a method of separating the components of a mixture. The inventive method is characterised in that it comprises the following steps: (a) the bringing into contact of the components of a mixture selected from (i) at least two hydrocarbons, (ii) a mixture containing at least nitrogen and oxygen, and (iii) at least one hydrocarbon and water, with an ITQ-29 zeolite material having a T(IV)/T(III) ratio of greater than 7, whereby T(IV) denotes one or more tetravalent elements and T(III) denotes one or more trivalent elements; (b) preferential adsorption of one or more of the components by the ITQ-29 zeolite material and (c) recovery of one or more of the components, preferably for the separation of hydrocarbon mixtures, such as linear or branched olefins from paraffins.

摘要翻译： 本发明涉及一种分离混合物组分的方法。 本发明的方法的特征在于其包括以下步骤：（a）使选自（i）至少两种烃的混合物的组分与（ii）至少含有氮和氧的混合物和（ iii）至少一种烃和水，其具有T（IV）/ T（III）比大于7的ITQ-29沸石材料，由此T（IV）表示一种或多种四价元素，并且T（III）表示 一种或多种三价元素; （b）通过ITQ-29沸石材料优先吸附一种或多种组分，和（c）回收一种或多种组分，优选用于从石蜡中分离烃混合物，例如直链或支链烯烃。