Abstract:
The present invention relates to an aqueous coating composition comprising at least one binder (A) comprising at least one polymeric resin (A1), at least one pigment (B), and an aqueous dispersion of at least one thickener (C), where (C) is obtainable by a method comprising at least the steps (1), (2), (3), and (4), namely preparing a dispersion or solution of at least one polyurethane as a polymeric resin (C2) in at least one organic solvent (step (1)), preparing a mixture of the dispersion or solution obtained by step (1) and of a melt or solution of at least one polyamide as at least one polymeric resin (C1) having an acid number in a range from 1 to 200 mg of KOH per g of (C1) (step (2)), adding water to the mixture obtained by step (2) (step (3)), and removing the organic solvent from the mixture obtained by step (3), to give the aqueous dispersion of (C) (step (4)), to the use thereof for at least partly coating an optionally coated substrate with a basecoat film, to a coating method of this kind, and to a substrate coated accordingly.
Abstract:
Solventborne filler comprises at least one alpha,omega-hydroxy-functionalized oligoester which possesses an OH number of 30 to 160 mg KOH/g, a theoretical carbon-carbon double bond content of 1 to 3 mmol/g, a number-average molecular weight of 1000 to 3000 g/mol and a weight-average molecular weight of 2800 to 10 000 g/mol, moreover, the sum of the weight percentage fractions of all the alpha,omega-hydroxy-functionalized oligoesters being 0.5 to 10 wt. %, based on the total amount of the solventborne filler. Also provided are a multicoat paint system, a process for producing a multicoat paint system, and use of the above-designated alpha,omega-hydroxy-functionalized oligoester in solventborne fillers for improving adhesion.
Abstract:
Disclosed herein is a dual-reactive composition including a). from 24% to 90% by weight of crosslinkable silane-functional monomer and/or oligomer and/or polymer; b). from 9% to 75% by weight of one monomer and/or unsaturated oligomer and/or unsaturated polymer; c). from 0.5% to 10% by weight of one initiator; and d). from 0.5% to 10% by weight of one catalyst, all weight percentages are based on the total weight of the coating composition and a film obtained from curing and drying of the coating composition as well as a substrate coated with the dual-reactive coating composition. Additionally disclosed herein is a process for preparing the dual-reactive coating composition and a roll-to-roll coating composition and a 1K clearcoat composition including the dual-reactive coating composition.
Abstract:
The present invention relates to a solventborne primer surfacer which comprises at least one additive preparable by reacting at least one alpha,omega-hydroxy-functionalized oligoester which possesses an OH number of 30 to 160 mg KOH/g, a theoretical carbon-carbon double bond content of 1 to 2.5 mmol/g, a number-average molecular weight of 1000 to 3000 g/mol, and a weight-average molecular weight of 2800 to 10 000 g/mol, and at least one alkoxysilane which possesses an OH-reactive functional group, the sum of the weight percentage fractions of all additives of the invention being 0.5 to 10 wt %, based on the total amount of the solventborne primer surfacer. The present invention further relates to a process for producing multicoat paint systems, and to multicoat paint systems producible by means of said process. The invention further relates to the use of the additive identified above in solventborne primer surfacers for improving adhesion.
Abstract:
The present invention relates to a copolymer (A) having a glass transition temperature Tg of at least −30° C. obtainable by copolymerization of a mixture of olefinically unsaturated monomers (a) in at least one organic solvent and in the presence of at least one initiator, where the mixture of monomers (a) to be polymerized comprises (a1) 10 to 60 mol % of at least one monomer of the formula (I) below where R1=C1 to C4 alkoxy, R2=C1 to C4 alkyl, and m=0 to 2, and (a2) 40 to 90 mol % of at least one olefinically unsaturated monomer selected from the group consisting of monomers of the formulae H2C═CH2—(C═O)—O—Rx, H2C═CH(CH3)—(C═O)—O—Rx, and H2C═CH2—O—(C═O)—Rx, where Rx is an alkyl radical having 1 to 20 carbon atoms, and where the sum total of the molar fractions of the monomers (a1) and (a2), based on the total molar amount of monomers (a) used, is at least 90 mol %, and where the copolymerization is carried out at a temperature from 60 to 200° C. and at a pressure of at least 2 bar.
Abstract:
The present invention relates to a nonaqueous coating material composition comprising (A) at least one oligomeric and/or polymeric compound (A) having at least two hydroxyl groups, (B) at least one oligomeric and/or polymeric compound (B) having at least two alkylidene-1,3-dioxolan-2-one groups, and (D) at least one catalyst (D) for the crosslinking, wherein the compound (B) contains at least two alkyliden-1,3-dioxolan-2-one groups of the formula (I′) where # stands for the attachment to the polymer backbone and R1, R2 independently of one another are hydrogen, C1-C6 alkyl, C1-C4 alkoxy-C1-C4 alkyl, C5-C6 cycloalkyl, phenyl or phenyl-C1-C4 alkyl; R3 is hydrogen, C1-C6 alkyl, C1-C4 alkoxy-C1-C4 alkyl, C5-C6 cycloalkyl, phenyl, or phenyl-C1-C4 alkyl; A is a chemical bond or C1-C4 alkanediyl; X is O or NR7; Z is a chemical bond, PO2, SO2, or C═O, Y is a chemical bond, CH2, or CHCH3, and R7 where present is C1-C6 alkyl. The present invention further provides the coatings produced from these coating material compositions, and also the use thereof.
Abstract:
The present invention relates to a solventborne, pigmented coating composition having a solids fraction of at least 35%, which comprises, based on the total amount of the coating composition, 0.1 to 1.5 wt % of at least one copolymer (A), where the copolymer (A) is obtainable by copolymerization of a mixture of olefinically unsaturated monomers (a) in at least one organic solvent, the mixture of monomers (a) to be polymerized consists of (a1) 10 to 60 mol % of at least one monomer of the formula (I) below where R1═C1 to C4 alkoxy, R2═C1 to C4 alkyl, and m=0 to 2, and also (a2) 40 to 90 mol % of at least one further olefinically unsaturated monomer, and the copolymer (A) possesses a glass transition temperature Tg of at least −30° C. The present invention also relates to a method for producing a multicoat paint system using the coating composition, and to the multicoat paint systems themselves.
Abstract:
The present invention relates to an aqueous coating composition comprising at least one mixture (M) of at least one polymeric resin (P1) and at least one polymeric resin (P2), different therefrom, where (P1) is a polyamide and (P2) is a polyester which is at least obtainable by reaction of at least one polymerized aliphatic C12-C24-monocarboxylic acid with at least one diol and/or polyol, at least one binder (A) comprising at least one polymeric resin (A1), which is different from the polymeric resins (P1) and (P2), at least one pigment (B), where the polyamide used as polymeric resin (P1) has an acid number
Abstract:
The present invention relates to a solventborne, pigmented coating composition, which comprises, based on the total amount of the coating composition, 0.02 to 0.75 wt % of at least one copolymer (A), where the copolymer (A) is obtainable by copolymerization of a mixture of olefinically unsaturated monomers (a) in at least one organic solvent, the mixture of monomers (a) to be polymerized consists of (a1) 10 to 60 mol % of at least one monomer of the formula (I) below where R1=C1 to C4 alkoxy, R2=C1 to C4 alkyl, and m=0 to 2, and also (a2) 40 to 90 mol % of at least one further olefinically unsaturated monomer, and the copolymer (A) possesses a glass transition temperature Tg of at least −30° C. The present invention also relates to a method for producing a multicoat paint system using the coating composition, and to the multicoat paint systems themselves.
Abstract:
The invention relates to aqueous dispersions comprising multistage-prepared polymers, and also to coating material compositions comprising them, preparable by multistage polymerization of olefinically unsaturated monomers, using an emulsifier and a water-soluble initiator, under conditions of starved feed polymerization, and using particular monomer mixtures in the individual stages.The invention also relates to a pigmented aqueous basecoat material comprising the aqueous dispersion of the invention, to the use of the aqueous dispersion of the invention in aqueous basecoat materials for improving adhesion, to a process for producing a multicoat paint system on a substrate, and to a multicoat paint system produced in accordance with the stated process.