公开(公告)号：US11896962B2

公开(公告)日：2024-02-13

申请号：US16953533

申请日：2020-11-20

申请人： BASF Corporation

发明人： Shiang Sung ,  Stanley A. Roth ,  Karifala Dumbuya ,  Susanne Stiebels ,  Claudia Zabel ,  Olga Gerlach ,  Andreas Sundermann

IPC分类号： B01D53/94 ,  B01J29/076 ,  B01J37/02 ,  B01J35/00 ,  B01J23/63 ,  B01J23/40 ,  B01J23/656

CPC分类号： B01J29/076 ,  B01D53/944 ,  B01D53/945 ,  B01J35/0006 ,  B01J37/0244 ,  B01J37/0246 ,  B01D53/9418 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/2073 ,  B01D2255/50 ,  B01D2255/502 ,  B01D2255/504 ,  B01D2255/9025 ,  B01J23/40 ,  B01J23/63 ,  B01J23/6562 ,  Y02T10/12

摘要： An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat comprising a zeolite, Pt, and first refractory metal oxide support containing manganese, a second washcoat comprising a second refractory metal oxide support, a Pt component and a Pd component, and a third washcoat comprising palladium and a rare earth oxide component is described.

公开(公告)号：US20210102486A1

公开(公告)日：2021-04-08

申请号：US16500340

申请日：2018-04-03

申请人： BASF CORPORATION

发明人： Shiang Sung ,  Torsten Neubauer ,  Pushkaraj R. Patwardhan ,  Susanne Stiebels ,  Claudia Zabel

IPC分类号： F01N3/20 ,  B01J23/58 ,  B01J21/04 ,  B01J23/656 ,  B01J35/00 ,  B01J35/04 ,  B01J29/76 ,  B01D53/94 ,  F01N3/10 ,  F01N3/08 ,  F01N3/28

摘要： The invention provides an emission control system for treatment of an exhaust gas stream that includes an oxidation catalyst composition disposed on a substrate in fluid communication with the exhaust gas stream; at least one selective catalytic reduction (SCR) composition disposed on a substrate downstream from the oxidation catalyst composition, and a hydrogen injection article configured to introduce hydrogen into the exhaust gas stream upstream of the oxidation catalyst composition or downstream of the oxidation catalyst composition and upstream of the at least one SCR composition. The invention also provides a method of treating an exhaust gas stream, the method including receiving the exhaust gas stream into the emission control system of the invention and intermittently introducing hydrogen upstream of the oxidation catalyst article or downstream of the oxidation catalyst article and upstream stream of the SCR article.

公开(公告)号：US20210069684A1

公开(公告)日：2021-03-11

申请号：US16953533

申请日：2020-11-20

申请人： BASF Corporation

发明人： Shiang Sung ,  Stanley A. Roth ,  Karifala Dumbuya ,  Susanne Stiebels ,  Claudia Zabel ,  Olga Gerlach ,  Andreas Sundermann

IPC分类号： B01J29/076 ,  B01D53/94 ,  B01J37/02 ,  B01J35/00

摘要： An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat comprising a zeolite, Pt, and first refractory metal oxide support containing manganese, a second washcoat comprising a second refractory metal oxide support, a Pt component and a Pd component, and a third washcoat comprising palladium and a rare earth oxide component is described.

公开(公告)号：US20150165423A1

公开(公告)日：2015-06-18

申请号：US14107781

申请日：2013-12-16

申请人： BASF Corporation

发明人： Shiang Sung ,  Stanley A. Roth ,  Karifala Dumbuya ,  Susanne Stiebels ,  Claudia Zabel ,  Olga Gerlach ,  Andreas Sundermann

IPC分类号： B01J29/076 ,  B01D53/94

CPC分类号： B01J29/076 ,  B01D53/9418 ,  B01D53/944 ,  B01D53/945 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/2073 ,  B01D2255/50 ,  B01D2255/502 ,  B01D2255/504 ,  B01D2255/9025 ,  B01J23/40 ,  B01J23/63 ,  B01J23/6562 ,  B01J35/0006 ,  B01J37/0244 ,  B01J37/0246 ,  Y02T10/24

摘要： An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat comprising a zeolite, Pt, and first refractory metal oxide support containing manganese, a second washcoat comprising a second refractory metal oxide support, a Pt component and a Pd component, and a third washcoat comprising palladium and a rare earth oxide component is described.

摘要翻译： 描述了用于处理来自柴油发动机的废气排放物的氧化催化剂复合材料，方法和系统。 更具体地说，一种氧化催化剂复合材料，包括包含沸石，Pt和含有锰的第一难熔金属氧化物载体的第一修补基面涂料，包含第二难熔金属氧化物载体的第二修补基面涂料，Pt组分和Pd组分，以及第三修补基面涂料， 描述了钯和稀土氧化物组分。

公开(公告)号：US20220258141A1

公开(公告)日：2022-08-18

申请号：US17608184

申请日：2020-05-06

申请人： BASF CORPORATION

发明人： Yi Liu ,  Brian T. Jones ,  Donald H. Reeder ,  Eric George Klauber ,  Oliver Seel ,  Torsten Neubauer ,  Saeed Alerasool ,  James Dale Hoggard ,  John Robert White ,  Claudia Zabel

IPC分类号： B01J29/76 ,  B01J37/00 ,  B01J37/04 ,  B01J35/02 ,  B01J35/10 ,  B01J37/03 ,  B01J37/08 ,  B01J37/30 ,  B01J35/04 ,  F01N3/20 ,  F01N3/28 ,  B01D53/94

摘要： The present disclosure provides catalyst compositions capable of reducing nitrogen oxide (NOx) emissions in engine exhaust, catalyst articles coated with such compositions, and processes for preparing such catalyst compositions and articles. The catalyst compositions include metal ion-exchanged zeolites useful for selective catalytic reduction (SCR) of NOx. Further provided is an exhaust gas treatment system including such catalytic articles, and methods for reducing NOx in an exhaust gas stream using such catalytic articles.

公开(公告)号：US11213789B2

公开(公告)日：2022-01-04

申请号：US15757384

申请日：2016-08-29

申请人： BASF Corporation

发明人： Marcus Hilgendorff ,  Karifala Dumbuya ,  Claudia Zabel ,  Susanne Stiebels

IPC分类号： B01J37/02 ,  B01J35/00 ,  B01D53/94 ,  B01J29/76 ,  F01N3/20

摘要： A catalyst containing a washcoat including copper or iron on a small pore molecular sieve material having a maximum ring size of eight tetrahedral atoms physically mixed with platinum and rhodium on a refractory metal oxide support including alumina, silica, zirconia, titania, and a physical mixture or a chemical combination or an atomically doped combination thereof is described. A catalyst containing a first washcoat zone substantially free of platinum group metal and including copper or iron on a small pore molecular sieve material having a maximum ring size of eight tetrahedral atoms; and a second washcoat zone including copper or iron on a small pore molecular sieve material having a maximum ring size of eight tetrahedral atoms physically mixed with platinum or platinum and rhodium on a refractory metal oxide support including alumina, silica, zirconia, titania, and a physical mixture or a chemical combination or an atomically doped combination thereof is provided. A method and a system for treating emissions using the catalyst are also described.

公开(公告)号：US11125133B2

公开(公告)日：2021-09-21

申请号：US16500340

申请日：2018-04-03

申请人： BASF CORPORATION

发明人： Shiang Sung ,  Torsten Neubauer ,  Pushkaraj R. Patwardhan ,  Susanne Stiebels ,  Claudia Zabel

IPC分类号： F01N3/08 ,  F01N3/10 ,  F01N3/20 ,  F01N3/28 ,  B01J21/04 ,  B01J23/58 ,  B01J23/656 ,  B01J29/76 ,  B01J35/00 ,  B01J35/04 ,  B01D53/94

摘要： The invention provides an emission control system for treatment of an exhaust gas stream that includes an oxidation catalyst composition disposed on a substrate in fluid communication with the exhaust gas stream; at least one selective catalytic reduction (SCR) composition disposed on a substrate downstream from the oxidation catalyst composition, and a hydrogen injection article configured to introduce hydrogen into the exhaust gas stream upstream of the oxidation catalyst composition or downstream of the oxidation catalyst composition and upstream of the at least one SCR composition. The invention also provides a method of treating an exhaust gas stream, the method including receiving the exhaust gas stream into the emission control system of the invention and intermittently introducing hydrogen upstream of the oxidation catalyst article or downstream of the oxidation catalyst article and upstream stream of the SCR article.

公开(公告)号：US10724411B2

公开(公告)日：2020-07-28

申请号：US16484874

申请日：2018-03-13

申请人： BASF Corporation

发明人： Karifala Dumbuya ,  Claudia Zabel ,  Shiang Sung

IPC分类号： F01N3/10 ,  B01J23/00 ,  B01J35/00 ,  B01J35/02 ,  B01J35/04 ,  B01J37/00 ,  B01J37/02

摘要： A diesel oxidation catalyst, containing a washcoat containing four layers, the washcoat being disposed on a substrate, wherein the washcoat contains: a first layer containing a first platinum group metal supported on a first metal oxide support material, wherein the first layer is disposed on the substrate; a second layer containing a second platinum group metal supported on a second metal oxide support material, and containing a fifth platinum group metal, wherein the second layer is disposed on the first layer; a third layer containing a third platinum group metal supported on a third metal oxide support material and containing a zeolitic material containing Fe and containing a sixth platinum group metal; and a fourth layer containing a fourth platinum group metal and a fourth metal oxide.

公开(公告)号：US10335776B2

公开(公告)日：2019-07-02

申请号：US14107704

申请日：2013-12-16

申请人： BASF Corporation

发明人： Shiang Sung ,  Stanley A. Roth ,  Claudia Zabel ,  Susanne Stiebels ,  Andreas Sundermann ,  Olga Gerlach

IPC分类号： B01D53/94 ,  B01J29/076 ,  B01J37/02 ,  B01J35/00 ,  B01J23/40 ,  B01J23/656

摘要： An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat layer comprising a Pt component and a Pd component, and a second washcoat layer including a refractory metal oxide support containing manganese, a zeolite, and a platinum component is described.

公开(公告)号：US11691106B2

公开(公告)日：2023-07-04

申请号：US17309016

申请日：2019-10-30

申请人： BASF CORPORATION

发明人： Matthias Peter ,  Susanne Stiebels ,  Karifala Dumbuya ,  Claudia Zabel

IPC分类号： B01D53/94 ,  B01J21/06 ,  B01J21/12 ,  B01J21/18 ,  B01J29/76 ,  B01J35/00 ,  B01J35/02 ,  B01J35/04 ,  B01J35/10 ,  B01J37/02 ,  B01J37/04 ,  B01J37/08 ,  F01N3/021 ,  F01N3/10 ,  F01N3/20 ,  F01N3/28 ,  F01N3/08

CPC分类号： B01D53/9418 ,  B01J21/066 ,  B01J21/12 ,  B01J21/18 ,  B01J29/763 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1076 ,  B01J37/0228 ,  B01J37/04 ,  B01J37/082 ,  F01N3/021 ,  F01N3/106 ,  F01N3/2066 ,  F01N3/28 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9032 ,  B01D2255/9035 ,  B01D2255/911 ,  B01D2255/9155 ,  B01D2255/9207 ,  F01N3/0814 ,  F01N3/0871 ,  F01N2330/30 ,  F01N2370/04 ,  F01N2370/24 ,  F01N2510/0682 ,  F01N2510/0684

摘要： A selective catalytic reduction catalyst for the treatment of an exhaust gas stream of a passive ignition engine, the catalyst comprising a porous wall-flow filter substrate comprising an inlet end, an outlet end, a substrate axial length (w) extending between the inlet end and the outlet end, and a plurality of passages defined by porous internal walls of the porous wall flow filter substrate; wherein the catalyst further comprises a first coating, said first coating extending over x % of the substrate axial length from the inlet end toward the outlet end of the substrate, x being in the range of from 10 to 100, wherein the first coating comprises copper and an 8-membered ring pore zeolitic material; wherein the catalyst further comprises a second coating, the second coating extending over y % of the substrate axial length from the outlet end toward the inlet end of the substrate, y being in the range of from 20 to 90, wherein the second coating comprises copper, and optionally an 8-membered ring pore zeolitic material; wherein the catalyst optionally further comprises a third coating; wherein x+y is at least 90; wherein y % of w from the outlet end toward the inlet end of the substrate define the outlet zone of the coated substrate and (100−y) % of w from the inlet end toward the outlet end of the substrate define the inlet zone of the coated substrate; wherein the ratio of the loading of copper in the inlet zone, Cu(in), calculated as CuO, relative to the loading of copper in the outlet zone, Cu(out), calculated as CuO, Cu(in):Cu(out), is less than 1:1.