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公开(公告)号:US08329601B2
公开(公告)日:2012-12-11
申请号:US12337779
申请日:2008-12-18
申请人: Bo Shi , Sarah A. Funk , James H. Wang , Gregory J. Wideman , Ross T. Kaufman , Vasily A. Topolkaraev
发明人: Bo Shi , Sarah A. Funk , James H. Wang , Gregory J. Wideman , Ross T. Kaufman , Vasily A. Topolkaraev
CPC分类号: A61L15/225 , A61L15/425 , A61L15/62 , B29C47/00 , B29C47/0026 , B29C55/005 , B29K2003/00 , B29K2105/04 , B29K2105/16 , B29K2995/006 , B32B5/022 , B32B9/02 , B32B27/08 , B32B27/12 , B32B27/20 , B32B27/22 , B32B27/30 , B32B27/32 , B32B27/36 , B32B27/40 , B32B37/153 , B32B2038/0028 , B32B2262/0238 , B32B2262/0246 , B32B2262/0253 , B32B2262/0261 , B32B2262/0276 , B32B2262/0292 , B32B2262/062 , B32B2305/20 , B32B2307/31 , B32B2307/7145 , B32B2307/7163 , B32B2307/724 , B32B2307/7265 , B32B2555/02 , C08J5/18 , C08J2300/16 , C08J2303/02 , C08L3/02 , C08L89/00 , Y10T428/24504 , Y10T442/282 , Y10T442/674 , C08L2666/26 , C08L89/02
摘要: A biodegradable and renewable film that may be employed in a wide variety of applications is provided. The film is formed from a thermoplastic composition that contains at least one starch and at least one plant protein. Even at a high renewable material content, the present inventors have discovered that films may be readily formed from plant proteins and starches by selectively controlling the individual amount of the starch and plant proteins, the nature of the starch and plant proteins, and other components used in the film. Balancing the amount of starches and plant proteins within a certain range, for instance, can reduce the likelihood of plant protein aggregation and enhance the ability of the composition to be melt processed. The composition also contains at least one plasticizer that improves the thermoplastic nature of the protein and starch components. The selection of the plasticizer may also help reduce the tendency of the plant protein to aggregate during melt processing. For example, a relatively acidic plasticizer (e.g., carboxylic acid) may be employed in certain embodiments to minimize the formation of disulfide bonds in a gluten protein, and thereby decrease its tendency to aggregate.
摘要翻译: 提供了可用于各种应用的可生物降解和可再生的膜。 该膜由含有至少一种淀粉和至少一种植物蛋白质的热塑性组合物形成。 即使在高可再生材料含量下,本发明人也发现,通过选择性地控制淀粉和植物蛋白质的个体数量,淀粉和植物蛋白质的性质以及所使用的其它组分,可以容易地从植物蛋白质和淀粉形成膜 在电影里。 例如,将一定范围内的淀粉和植物蛋白质的量平衡可以降低植物蛋白质聚集的可能性并增加组合物被熔融加工的能力。 该组合物还含有至少一种改善蛋白质和淀粉组分的热塑性质的增塑剂。 增塑剂的选择也有助于降低植物蛋白质在熔融加工过程中聚集的趋势。 例如,在某些实施方案中可以使用相对酸性的增塑剂(例如羧酸)以最小化谷蛋白中二硫键的形成,从而降低其聚集趋势。
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公开(公告)号:US20100159203A1
公开(公告)日:2010-06-24
申请号:US12337779
申请日:2008-12-18
申请人: Bo Shi , Sarah A. Funk , James H. Wang , Gregory J. Wideman , Ross T. Kaufman , Vasily A. Topolkaraev
发明人: Bo Shi , Sarah A. Funk , James H. Wang , Gregory J. Wideman , Ross T. Kaufman , Vasily A. Topolkaraev
CPC分类号: A61L15/225 , A61L15/425 , A61L15/62 , B29C47/00 , B29C47/0026 , B29C55/005 , B29K2003/00 , B29K2105/04 , B29K2105/16 , B29K2995/006 , B32B5/022 , B32B9/02 , B32B27/08 , B32B27/12 , B32B27/20 , B32B27/22 , B32B27/30 , B32B27/32 , B32B27/36 , B32B27/40 , B32B37/153 , B32B2038/0028 , B32B2262/0238 , B32B2262/0246 , B32B2262/0253 , B32B2262/0261 , B32B2262/0276 , B32B2262/0292 , B32B2262/062 , B32B2305/20 , B32B2307/31 , B32B2307/7145 , B32B2307/7163 , B32B2307/724 , B32B2307/7265 , B32B2555/02 , C08J5/18 , C08J2300/16 , C08J2303/02 , C08L3/02 , C08L89/00 , Y10T428/24504 , Y10T442/282 , Y10T442/674 , C08L2666/26 , C08L89/02
摘要: A biodegradable and renewable film that may be employed in a wide variety of applications is provided. The film is formed from a thermoplastic composition that contains at least one starch and at least one plant protein. Even at a high renewable material content, the present inventors have discovered that films may be readily formed from plant proteins and starches by selectively controlling the individual amount of the starch and plant proteins, the nature of the starch and plant proteins, and other components used in the film. Balancing the amount of starches and plant proteins within a certain range, for instance, can reduce the likelihood of plant protein aggregation and enhance the ability of the composition to be melt processed. The composition also contains at least one plasticizer that improves the thermoplastic nature of the protein and starch components. The selection of the plasticizer may also help reduce the tendency of the plant protein to aggregate during melt processing. For example, a relatively acidic plasticizer (e.g., carboxylic acid) may be employed in certain embodiments to minimize the formation of disulfide bonds in a gluten protein, and thereby decrease its tendency to aggregate.
摘要翻译: 提供了可用于各种应用的可生物降解和可再生的膜。 该膜由含有至少一种淀粉和至少一种植物蛋白质的热塑性组合物形成。 即使在高可再生材料含量下,本发明人也发现,通过选择性地控制淀粉和植物蛋白质的个体数量,淀粉和植物蛋白质的性质以及所使用的其它组分,可以容易地从植物蛋白质和淀粉形成膜 在电影里。 例如,将一定范围内的淀粉和植物蛋白质的量平衡可以降低植物蛋白质聚集的可能性并增加组合物被熔融加工的能力。 该组合物还含有至少一种改善蛋白质和淀粉组分的热塑性质的增塑剂。 增塑剂的选择也有助于降低植物蛋白质在熔融加工过程中聚集的趋势。 例如,在某些实施方案中可以使用相对酸性的增塑剂(例如羧酸)以最小化谷蛋白中二硫键的形成,从而降低其聚集趋势。
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公开(公告)号:US20100048081A1
公开(公告)日:2010-02-25
申请号:US12513557
申请日:2006-12-15
申请人: Vasily A. Topolkaraev , Gregory J. Wideman , Ross T. Kaufman , Alan E. Wright , Jeffrey J. Krueger , Jayant Chakravarty
发明人: Vasily A. Topolkaraev , Gregory J. Wideman , Ross T. Kaufman , Alan E. Wright , Jeffrey J. Krueger , Jayant Chakravarty
CPC分类号: C08G63/916 , A61F13/15252 , B32B27/36 , D01D5/0985 , D01F6/625 , D01F6/92 , D04H3/011 , D04H3/03 , D04H3/153 , D04H3/16 , D04H13/00 , Y10T442/68
摘要: A method for forming a biodegradable polyester suitable for use in fibers is provided. Specifically, a biodegradable polyester is melt processed at a controlled water content to initiate a hydrolysis reaction. Without intending to be limited by theory, it is believed that the hydroxyl groups present in water are capable of attacking the ester linkage of the polyester, thereby leading to chain scission or “depolymerization” of the polyester molecule into one or more shorter ester chains. By selectively controlling the reaction conditions (e.g., water content, temperature, shear rate, etc.), a hydrolytically degraded polyester may be achieved that has a molecular weight lower than the starting polymer. Such lower molecular weight polymers have a higher melt flow rate and lower apparent viscosity, which are useful in a wide variety of fiber forming applications, such as in the meltblowing of nonwoven webs.
摘要翻译: 提供一种形成适用于纤维的可生物降解聚酯的方法。 具体地说,将可生物降解的聚酯以受控的水含量熔融加工以引发水解反应。 不期望受理论的限制,据信存在于水中的羟基能够攻击聚酯的酯键,从而导致聚酯分子链断裂或“解聚”成一个或多个较短的酯链。 通过选择性地控制反应条件(例如水含量,温度,剪切速率等),可以获得具有低于起始聚合物的分子量的水解降解的聚酯。 这种较低分子量的聚合物具有较高的熔体流动速率和较低的表观粘度,其可用于多种纤维形成应用中,例如在非织造纤维网的熔喷中。
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公开(公告)号:US20100048082A1
公开(公告)日:2010-02-25
申请号:US12513558
申请日:2006-12-15
申请人: Vasily A. Topolkaraev , Gregory J. Wideman , Ross T. Kaufman , Alan E. Wright , Jeffrey J. Krueger , Jayant Chakravarty
发明人: Vasily A. Topolkaraev , Gregory J. Wideman , Ross T. Kaufman , Alan E. Wright , Jeffrey J. Krueger , Jayant Chakravarty
CPC分类号: C08G63/912 , A61F13/15252 , B32B9/04 , C08L67/04 , C08L71/02 , D01D5/0985 , D01F6/625 , D01F6/92 , D01F8/14 , D04H3/011 , D04H3/02 , D04H3/03 , D04H3/153 , D04H3/16 , D04H5/03 , D04H5/06 , D04H5/08 , D04H13/00 , Y10T442/60 , Y10T442/68 , C08L2666/22
摘要: A method for forming a biodegradable polylactic acid suitable for use in fibers is provided. Specifically, a polylactic acid is melt processed at a controlled water content to initiate a hydrolysis reaction. Without intending to be limited by theory, it is believed that the hydroxyl groups present in water are capable of attacking the ester linkage of polylactic acids, thereby leading to chain scission or “depolymerization” of the polylactic acid molecule into one or more shorter ester chains. The shorter chains may include polylactic acids, as well as minor portions of lactic acid monomers or oligomers, and combinations of any of the foregoing. By selectively controlling the hydrolysis conditions (e.g., moisture and polymer concentrations, temperature, shear rate, etc.), a hydrolytically degraded polylactic acid may be achieved that has a molecular weight lower than the starting polymer. Such lower molecular weight polymers have a higher melt flow rate and lower apparent viscosity, which are useful in a wide variety of fiber forming applications, such as in the meltblowing of nonwoven webs.
摘要翻译: 提供一种形成适用于纤维的可生物降解的聚乳酸的方法。 具体地说,将聚乳酸以受控的水分进行熔融加工以引发水解反应。 不期望受理论的限制,据信存在于水中的羟基能够攻击聚乳酸的酯键,从而导致聚乳酸分子链断裂或“解聚”成一个或多个较短酯链 。 较短的链可以包括聚乳酸,以及乳酸单体或低聚物的少部分,以及上述任何一种的组合。 通过选择性地控制水解条件(例如水分和聚合物浓度,温度,剪切速率等),可以实现分子量低于起始聚合物的水解降解聚乳酸。 这种较低分子量的聚合物具有较高的熔体流动速率和较低的表观粘度,其可用于多种纤维形成应用中,例如在非织造纤维网的熔喷中。
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公开(公告)号:US08334327B2
公开(公告)日:2012-12-18
申请号:US12373976
申请日:2006-08-31
CPC分类号: C08J5/18 , B32B27/20 , C08J2367/00 , C08K3/01 , Y10T428/24942
摘要: A breathable film having a base layer comprising first filler particles and second filler particles dispersed within a biodegradable polymer matrix is provided. The first filler particles constitute from about 25 wt. % to about 75 wt. % of the base layer and the second filler particles constitute from about 0.1 wt. % to about 10 wt. % of the base layer. The ratio of the average size of the first filler particles to the average size of the second filler particles being from about 2 to about 100. The film exhibits a water vapor transmission rate of about 2,000 g/m2/24 hours or more and a peak load in the machine direction of about 800 grams-force per inch or more.
摘要翻译: 提供了一种透气膜,其具有包含分散在可生物降解的聚合物基质内的第一填料颗粒和第二填料颗粒的基层。 第一填料颗粒构成约25wt。 %至约75wt。 基础层和第二填料颗粒的%构成约0.1wt。 %至约10wt。 基础层的%。 第一填料颗粒的平均尺寸与第二填料颗粒的平均尺寸的比例为约2至约100.该膜的水蒸气透过率为约2,000g / m 2/24小时以上,峰值 在机器方向负载约800克力/英寸以上。
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公开(公告)号:US08927443B2
公开(公告)日:2015-01-06
申请号:US12094273
申请日:2006-04-07
申请人: Jayant Chakravarty , Vasily Topolkaraev , Ross T. Kaufman , Stephen Avedis Baratian , Jared L. Martin
发明人: Jayant Chakravarty , Vasily Topolkaraev , Ross T. Kaufman , Stephen Avedis Baratian , Jared L. Martin
IPC分类号: B32B5/26 , D04H1/559 , D04H3/011 , D04H3/02 , D04H3/14 , D04H3/147 , D04H13/00 , B32B5/02 , B32B5/08
CPC分类号: D04H1/559 , B32B5/022 , B32B5/08 , B32B5/26 , B32B2250/20 , B32B2262/0276 , B32B2262/12 , B32B2307/7163 , B32B2535/00 , D04H3/011 , D04H3/02 , D04H3/14 , D04H3/147 , D04H13/00 , Y10S428/913 , Y10T156/10 , Y10T442/66 , Y10T442/668 , Y10T442/68 , Y10T442/681 , Y10T442/696
摘要: A biodegradable nonwoven laminate is provided. The laminate comprises a spunbond layer formed from substantially continuous filaments that contain a first aliphatic polyester having a melting point of from about 50° C. to about 160° C. The meltblown layer is formed from microfibers that contain a second aliphatic polyester having a melting point of from about 50° C. to about 160° C. The first aliphatic polyester, the second aliphatic polyester, or both have an apparent viscosity of from about 20 to about 215 Pascal-seconds, as determined at a temperature of 160° C. and a shear rate of 1000 sec-1. The first aliphatic polyester may be the same or different than the second aliphatic polyester.
摘要翻译: 提供了可生物降解的非织造层压材料。 层压体包括由基本上连续的长丝形成的纺粘层,其包含熔点为约50℃至约160℃的第一脂族聚酯。熔喷层由含有熔融的第二脂肪族聚酯的微纤维形成 点在约50℃至约160℃之间。第一脂族聚酯,第二脂族聚酯或两者的表观粘度为约20至约215帕斯卡 - 秒,如在160℃的温度下测定 剪切速率为1000秒-1。 第一脂肪族聚酯可以与第二脂肪族聚酯相同或不同。
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公开(公告)号:US20080287026A1
公开(公告)日:2008-11-20
申请号:US12094273
申请日:2006-04-07
申请人: Jayant Chakravarty , Vasily Topolkaraev , Ross T. Kaufman , Stephen Avedis Baratian , Jared L. Martin
发明人: Jayant Chakravarty , Vasily Topolkaraev , Ross T. Kaufman , Stephen Avedis Baratian , Jared L. Martin
CPC分类号: D04H1/559 , B32B5/022 , B32B5/08 , B32B5/26 , B32B2250/20 , B32B2262/0276 , B32B2262/12 , B32B2307/7163 , B32B2535/00 , D04H3/011 , D04H3/02 , D04H3/14 , D04H3/147 , D04H13/00 , Y10S428/913 , Y10T156/10 , Y10T442/66 , Y10T442/668 , Y10T442/68 , Y10T442/681 , Y10T442/696
摘要: A biodegradable nonwoven laminate is provided. The laminate comprises a spunbond layer formed from substantially continuous filaments that contain a first aliphatic polyester having a melting point of from about 50° C. to about 160° C. The meltblown layer is formed from microfibers that contain a second aliphatic polyester having a melting point of from about 50° C. to about 160° C. The first aliphatic polyester, the second aliphatic polyester, or both have an apparent viscosity of from about 20 to about 215 Pascal-seconds, as determined at a temperature of 160° C. and a shear rate of 1000 sec-1. The first aliphatic polyester may be the same or different than the second aliphatic polyester.
摘要翻译: 提供了可生物降解的非织造层压材料。 层压体包括由基本上连续的长丝形成的纺粘层,其包含熔点为约50℃至约160℃的第一脂族聚酯。熔喷层由含有熔融的第二脂肪族聚酯的微纤维形成 点在约50℃至约160℃之间。第一脂族聚酯,第二脂族聚酯或两者的表观粘度为约20至约215帕斯卡 - 秒,如在160℃的温度下测定 剪切速率为1000秒-1。 第一脂肪族聚酯可以与第二脂肪族聚酯相同或不同。
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