公开(公告)号：US20170226031A1

公开(公告)日：2017-08-10

申请号：US15501688

申请日：2015-08-04

申请人： IFP ENERGIES NOUVELLES ,  CECA S.A.

发明人： Catherine LAROCHE ,  Philibert LEFLAIVE ,  Arnaud BAUDOT ,  Ludivine BOUVIER ,  Cecile LUTZ ,  Serge NICOLAS

IPC分类号： C07C7/13 ,  B01J20/28 ,  B01J20/18

CPC分类号： C07C7/13 ,  B01J20/18 ,  B01J20/183 ,  B01J20/186 ,  B01J20/2803 ,  B01J20/28059 ,  B01J20/28061 ,  B01J20/28071 ,  B01J20/28073 ,  B01J20/28083 ,  B01J20/28085 ,  C07C15/08

摘要： The invention relates to a method for separating meta-xylene from C8 aromatic fractions, using a zeolitic adsorbent based on sodium-exchanged or sodium-and-lithium-exchanged agglomerated crystals of zeolite Y, with a large external surface area.

公开(公告)号：US20160289146A1

公开(公告)日：2016-10-06

申请号：US15037896

申请日：2014-11-20

申请人： CECA S.A. ,  IFP ENERGIES NOUVELLES

发明人： Catherine LAROCHE ,  Ludivine BOUVIER ,  Philibert LEFLAIVE ,  Cécile LUTZ ,  Anne-Sophie GAY ,  Florent MOREAU

IPC分类号： C07C7/13 ,  B01J20/30 ,  B01J20/28 ,  B01J20/18 ,  B01J20/12

摘要： The present invention relates to a zeolitic granular material having a connected zeolitic structure across the entire volume thereof, having high mechanical resistance to crushing in the bed, and optimised material transfer in the macro-mesopores. The invention also relates to the method for preparing said zeolitic granular material, as well as to the use thereof as an adsorbent material in co-current or counter-current liquid phase separation methods, typically in a simulated mobile bed.

摘要翻译： 本发明涉及在其整个体积上具有连接的沸石结构的沸石颗粒材料，其具有高的机械抗破碎性，并且在宏观介孔中优化了材料转移。 本发明还涉及制备所述沸石颗粒材料的方法，以及其作为吸附剂材料在并流或逆流液相分离方法中的用途，通常在模拟的移动床中。

公开(公告)号：US20160176720A1

公开(公告)日：2016-06-23

申请号：US14892101

申请日：2014-08-06

申请人： CECA S.A.

发明人： Serge NICOLAS ,  Ludivine BOUVIER ,  Cecile LUTZ

IPC分类号： C01B39/24 ,  C01B39/04

CPC分类号： C01B39/24 ,  C01B39/04 ,  C01P2002/22 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/17

摘要： The present invention concerns Y-type FAU zeolites with hierarchical porosity having an Si/AI atomic ratio strictly greater than 1.4 and less than or equal to 6, having controlled and optimised crystallinity, and having mesoporosity such that the mesoporous outer surface area is between 40 m2·g−1 and 400 m2·g−1. The present invention also concerns the method for preparing said Y-type FAU zeolites with hierarchical porosity.

摘要翻译： 本发明涉及具有分级孔隙率的Y型FAU沸石，其具有严格大于1.4且小于或等于6的Si / Al原子比，具有受控和优化的结晶度，并且具有中孔性，使得介孔外表面积在40 m2·g-1和400m2·g-1。 本发明还涉及制备具有分级孔隙率的所述Y型FAU沸石的方法。

公开(公告)号：US20170239642A1

公开(公告)日：2017-08-24

申请号：US15501719

申请日：2015-08-04

申请人： CECA S.A. ,  IFP ENERGIES NOUVELLES

发明人： Ludivine BOUVIER ,  Cecile LUTZ ,  Catherine LAROCHE ,  Arnaud BAUDOT

IPC分类号： B01J20/18 ,  B01J20/28 ,  B01D53/02 ,  C07C7/13 ,  B01D15/18 ,  B01J20/12 ,  B01J20/30

摘要： The present invention relates to a zeolite absorbent comprising at least one FAU zeolite with hierarchical porosity and comprising barium or barium and potassium, and the external surface area of which is greater than 20 m2·g−1, and the non-zeolite phase content being between 6% and 12% by weight with respect to the total weight of the absorbent. The present invention also relates to the use of such a zeolite absorbent as an adsorption agent, as well as the method for separation of para-xylene from aromatic isomer fractions with 8 carbon atoms.

公开(公告)号：US20160207024A1

公开(公告)日：2016-07-21

申请号：US14914220

申请日：2014-08-06

申请人： CECA S.A.

发明人： Ludivine BOUVIER ,  Cecile LUTZ ,  Serge NICOLAS

IPC分类号： B01J20/18 ,  B01J20/28 ,  B01J20/30 ,  B01J37/06 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00 ,  B01J37/08 ,  B01J20/12 ,  B01J29/08

CPC分类号： B01J20/18 ,  B01J20/12 ,  B01J20/186 ,  B01J20/28004 ,  B01J20/28011 ,  B01J20/28083 ,  B01J20/3028 ,  B01J20/3042 ,  B01J20/3078 ,  B01J20/3085 ,  B01J29/005 ,  B01J29/041 ,  B01J29/084 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1038 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/06 ,  B01J37/08 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24

摘要： The present invention relates to zeolite materials in the form of agglomerates comprising at least one mesoporous Faujasite zeolite with an Si/Al ratio which is strictly greater than 1.4 and having both the characteristics of mesoporous zeolites, the properties associated with microporosity and the mechanical properties of zeolite agglomerates without mesoporous zeolite.The invention also relates to the process for preparing the said zeolite materials in the form of agglomerates.

摘要翻译： 本发明涉及附聚物形式的沸石材料，其包含至少一种Si / Al比严格大于1.4的中孔八面沸石沸石，并且具有介孔沸石的特性，与微孔性相关的性能和机械性能 没有介孔沸石的沸石团块。 本发明还涉及以附聚物的形式制备所述沸石材料的方法。

公开(公告)号：US20160207025A1

公开(公告)日：2016-07-21

申请号：US14917457

申请日：2014-09-05

申请人： CECA S.A. ,  IFP ENERGIES NOUVELLES

发明人： Catherine LAROCHE ,  Philibert LEFLAIVE ,  Ludivine BOUVIER ,  Serge NICOLAS ,  Cecile LUTZ ,  Marie-Laurence LABEDE

IPC分类号： B01J20/18 ,  B01J20/28 ,  C07C29/76 ,  C07C7/13 ,  C07C37/82 ,  B01J20/12 ,  B01J20/30

CPC分类号： B01J20/18 ,  B01D53/02 ,  B01D53/08 ,  B01D2253/108 ,  B01D2257/556 ,  B01J20/12 ,  B01J20/186 ,  B01J20/28004 ,  B01J20/28059 ,  B01J20/28061 ,  B01J20/28071 ,  B01J20/3028 ,  B01J20/3071 ,  B01J20/3085 ,  C07C7/13 ,  C07C29/76 ,  C07C37/82 ,  C07C201/16 ,  C07C209/86 ,  C07C15/08 ,  C07C15/02 ,  C07C211/50 ,  C07C205/06 ,  C07C39/07

摘要： The present invention relates to zeolitic adsorbents based on agglomerated crystals of FAU zeolite comprising barium and/or potassium, with large external surface area, combining optimum properties in terms of selectivity and mechanical strength.These adsorbents find applications in the separation of cuts of C8-aromatic isomers and notably of xylenes, in the separation of isomers of substituted toluene such as nitrotoluene, diethyltoluene, toluenediamine, in the separation of cresols, and polyhydric alcohols, such as sugars.

摘要翻译： 本发明涉及基于包含钡和/或钾的FAU沸石的附聚晶体的沸石吸附剂，具有大的外表面积，在选择性和机械强度方面结合了最佳性能。 这些吸附剂用于分离C8-芳族异构体，特别是二甲苯的切割，在分离甲酚时分离取代甲苯（如硝基甲苯，二乙基甲苯，甲苯二胺）的异构体和多元醇如糖。

公开(公告)号：US20150306565A1

公开(公告)日：2015-10-29

申请号：US14650780

申请日：2013-12-10

申请人： CECA S.A ,  IFP ENERGIES NOUVELLES

发明人： Ludivine BOUVIER ,  Stephane KIEGER ,  Catherine LAROCHE ,  Philibert LEFLAIVE

IPC分类号： B01J20/18 ,  C07C29/76 ,  C07C7/13 ,  C07C37/82 ,  B01J20/30 ,  B01J20/28

摘要： The present invention relates to zeolitic adsorbents based on small agglomerated crystals of zeolite X comprising barium, combining optimum properties in terms of selectivity and of mechanical strength.These adsorbents have applications in the separation of fractions of aromatic C8 isomers and in particular xylenes, in the separation of substituted toluene isomers, such as nitrotoluene, diethyltoluene or toluenediamine, in the separation of cresols and in the separation of polyhydric alcohols, such as sugars.

摘要翻译： 本发明涉及基于包含钡的沸石X的小团聚晶体的沸石吸附剂，其结合了选择性和机械强度方面的最佳性能。 这些吸附剂可用于分离芳族C8异构体，特别是二甲苯，分离取代的甲苯异构体如硝基甲苯，二乙基甲苯或甲苯二胺在分离甲酚和分离多元醇如糖 。

公开(公告)号：US20170217858A1

公开(公告)日：2017-08-03

申请号：US15501741

申请日：2015-08-04

申请人： IFP ENERGIES NOUVELLES ,  CECA S.A.

发明人： Catherine LAROCHE ,  Ludivine BOUVIER ,  Cecile LUTZ ,  Amaud BAUDOT

IPC分类号： C07C7/13 ,  B01D15/18 ,  B01J20/28 ,  B01J20/30 ,  B01J20/18 ,  B01J20/12

CPC分类号： C07C7/13 ,  B01D15/1821 ,  B01D15/1828 ,  B01J20/12 ,  B01J20/18 ,  B01J20/183 ,  B01J20/186 ,  B01J20/28004 ,  B01J20/28011 ,  B01J20/28019 ,  B01J20/2803 ,  B01J20/28059 ,  B01J20/28069 ,  B01J20/28078 ,  B01J20/2808 ,  B01J20/28083 ,  B01J20/28085 ,  B01J20/28088 ,  B01J20/28092 ,  B01J20/3007 ,  B01J20/3028 ,  B01J20/3042 ,  B01J20/3078 ,  C07C15/08

摘要： The invention relates to zeolitic absorbents based on at least one zeolite with hierarchical porosity, containing barium or barium and potassium, to the uses thereof for separating para-xylene from aromatic fractions containing 8 carbon atoms, and to the method for separating para-xylene from aromatic fractions containing 8 carbon atoms.

公开(公告)号：US20160193586A1

公开(公告)日：2016-07-07

申请号：US14910124

申请日：2014-08-04

申请人： CECA S.A.

发明人： Ludivine BOUVIER ,  Cecile LUTZ ,  Quitterie PERSILLON ,  Serge NICOLAS ,  Yvan LECOMTE

IPC分类号： B01J20/18 ,  B01J29/00 ,  B01J29/06 ,  B01J20/28 ,  B01J35/02 ,  B01J37/00 ,  B01J37/08 ,  B01J20/30 ,  B01J35/00

CPC分类号： B01J20/186 ,  B01J20/183 ,  B01J20/28004 ,  B01J20/28011 ,  B01J20/2803 ,  B01J20/2808 ,  B01J20/28083 ,  B01J20/3028 ,  B01J20/3042 ,  B01J20/3071 ,  B01J20/3078 ,  B01J20/3085 ,  B01J29/005 ,  B01J29/041 ,  B01J29/06 ,  B01J29/082 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1038 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0063 ,  B01J37/08 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24

摘要： The present invention relates to zeolite materials in the form of agglomerates comprising at least one mesoporous zeolite and having both the characteristics of mesoporous zeolites, the properties associated with microporosity and the mechanical properties of zeolite agglomerates without mesoporous zeolite.The invention also relates to the process for preparing the said zeolite materials in the form of agglomerates.

摘要翻译： 本发明涉及包含至少一种中孔沸石并具有介孔沸石特性，与微孔性相关的性质以及没有介孔沸石的沸石聚集体的机械性能的附聚物形式的沸石材料。 本发明还涉及以附聚物的形式制备所述沸石材料的方法。

公开(公告)号：US20160137517A1

公开(公告)日：2016-05-19

申请号：US14889353

申请日：2014-08-04

申请人： CECA S.A.

发明人： Serge NICOLAS ,  Karine LOPEZ ,  Cecile LUTZ ,  Ludivine BOUVIER

IPC分类号： C01B39/22 ,  C01B39/14

CPC分类号： C01B39/22 ,  C01B39/145 ,  C01B39/20 ,  C01B39/46 ,  C01P2002/72 ,  C01P2004/04 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/17

摘要： The present invention concerns zeolites with hierarchical porosity having a molar ratio Si/Al of between 1 and 1.4, inclusive, of which the average diameter, as a number, is between 0.1 μm and 20 μm, having controlled and optimized crystallinity, and having mesoporosity such that the mesoporous outer surface area is between 40 m2·g−1 and 400 m2·g−1. The present invention also concerns the method for preparing said zeolites with hierarchical porosity.

摘要翻译： 本发明涉及具有层间孔隙率的沸石，其具有介于1和1.4之间的摩尔比在1和1.4之间，其平均直径为0.1μm至20μm，具有受控和优化的结晶度，并且具有中等孔隙度 使得介孔外表面积在40m 2·g -1〜400m 2·g -1之间。 本发明还涉及制备具有分级孔隙度的所述沸石的方法。