公开(公告)号：US20030181327A1

公开(公告)日：2003-09-25

申请号：US10100966

申请日：2002-03-19

Applicant: Conoco Inc.

Inventor： Joe D. Allison ,  Yaming Jin ,  Thomas D. Baugh

IPC: B01J023/00 ,  C07C027/06

CPC classification number: C10G2/332 ,  B01J23/75 ,  B01J35/0033 ,  B01J37/0242 ,  C10G2/333

Abstract: Catalysts with silica-encapsulated magnetic supports are disclosed, along with their manner of making and process for separating them from a product stream in a reactor. A preferred catalyst comprises a catalytically active metal, preferably cobalt, and appropriate promoters, a magnetic support, preferably comprising magnetite, and an encapsulating material, preferably silica, encapsulating the magnetic support.

Abstract translation: 公开了具有二氧化硅包封的磁性载体的催化剂及其在反应器中将其与产物流分离的制备方法和方法。 优选的催化剂包括催化活性金属，优选钴，以及适当的助催化剂，优选包含磁铁矿的磁性载体，以及封装磁性载体的包封材料，优选二氧化硅。

公开(公告)号：US20030096880A1

公开(公告)日：2003-05-22

申请号：US10282382

申请日：2002-10-29

Applicant: Conoco Inc.

Inventor： Daxiang Wang ,  Yaming Jin ,  Harold A. Wright ,  Rafael L. Espinoza

IPC: B01J031/00 ,  C07C027/06 ,  B01J023/00

CPC classification number: C01B3/40 ,  B01J21/04 ,  B01J23/40 ,  B01J23/42 ,  B01J23/464 ,  B01J23/58 ,  B01J23/63 ,  B01J23/755 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J37/0203 ,  B01J37/08 ,  B01J37/084 ,  B01J37/088 ,  B01J37/18 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/066 ,  C01B2203/1011 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1241 ,  C01B2203/1276 ,  C01B2203/1604 ,  Y02P20/52

Abstract: Combustion dispersed metal-metal oxide catalysts that are highly active for catalyzing the net partial oxidation of methane to CO and H2 are disclosed, along with their manner of making and processes for producing synthesis gas employing the new catalysts. A preferred catalyst comprises rhodium nanoparticles, with or without a rare earth promoter, that is deposited on null-alumina by combusting a mixture of catalyst precursor materials and a flammable organic compound. In a preferred syngas production process a stream of reactant gas mixture containing methane and O2 is passed over the catalyst in a short contact time reactor to efficiently produce a mixture of carbon monoxide and hydrogen at superatmospheric pressures.

Abstract translation: 公开了用于催化甲烷到CO和H 2的净部分氧化的高活性的燃烧分散的金属 - 金属氧化物催化剂及其制备方法和使用新催化剂生产合成气的方法。 优选的催化剂包括具有或不具有稀土助催化剂的铑纳米颗粒，其通过燃烧催化剂前体材料和易燃有机化合物的混合物而沉积在α-氧化铝上。 在优选的合成气生产过程中，含有甲烷和O 2的反应气体混合物流在短接触时间反应器中通过催化剂，以在超大气压下有效地产生一氧化碳和氢气的混合物。

公开(公告)号：US20040033885A1

公开(公告)日：2004-02-19

申请号：US10219148

申请日：2002-08-15

Applicant: Conoco Inc.

Inventor： Daxiang Wang ,  Baili Hu ,  Yaming Jin ,  Harold A. Wright

IPC: C01B003/26

CPC classification number: B01J38/04 ,  B01J23/464 ,  B01J23/94 ,  B01J23/96 ,  B01J35/002 ,  B01J38/10 ,  B01J38/12 ,  C01B3/386 ,  C01B3/40 ,  C01B2203/0261 ,  C01B2203/06 ,  C01B2203/062 ,  C01B2203/1047 ,  C01B2203/1082 ,  C01B2203/1241 ,  Y02P20/52 ,  Y02P20/584

Abstract: The present invention relates to a process for the preparation of synthesis gas (i.e., a mixture of carbon monoxide and hydrogen), typically labeled syngas. More particularly, the present invention relates to a regeneration method for a syngas catalyst. Still more particularly, the present invention relates to the regeneration of syngas catalysts using a re-dispersion technique. One embodiment of the re-dispersion technique involves the treatment of a deactivated syngas catalyst with a re-dispersing gas, preferably a carbon monoxide-containing gas such as syngas. If necessary, the catalyst is then exposed to hydrogen for reduction and further re-dispersion.

Abstract translation: 本发明涉及通常标记为合成气的合成气（即，一氧化碳和氢气的混合物）的制备方法。 更具体地说，本发明涉及合成气催化剂的再生方法。 更具体地说，本发明涉及使用再分散技术再生合成气催化剂。 再分散技术的一个实施方案涉及用再分散气体，优选含有一氧化碳的气体如合成气处理失活的合成气催化剂。 如果需要，然后将催化剂暴露于氢气中进行还原和再分散。

公开(公告)号：US20040002422A1

公开(公告)日：2004-01-01

申请号：US10184473

申请日：2002-06-27

Applicant: Conoco Inc.

Inventor： Daxiang Wang ,  Yaming Jin ,  Harold A. Wright ,  Carl Johnston JR.

IPC: F28D001/00

CPC classification number: B01J23/63 ,  B01J23/464 ,  B01J35/006 ,  B01J35/1061 ,  B01J37/03 ,  B01J37/088

Abstract: A process and system for producing industrial-scale quantities of highly dispersed, thermally stable catalysts is disclosed. The process, which may be continuous production or batch production, includes mixing together the desired catalyst precursor materials, a combustible organic material and a solvent; evaporating the solvent, combusting the catalyst intermediate; and shaping final catalyst.

Abstract translation: 公开了一种用于生产工业规模量的高分散，热稳定的催化剂的方法和系统。 可以连续生产或批量生产的方法包括将所需的催化剂前体材料，可燃有机材料和溶剂混合在一起; 蒸发溶剂，燃烧催化剂中间体; 并成型最终催化剂。

公开(公告)号：US20040221508A1

公开(公告)日：2004-11-11

申请号：US10152278

申请日：2002-05-21

Applicant: Conoco Inc.

Inventor： Yaming Jin ,  Tianyan Niu ,  Harold A. Wright

IPC: C01B003/26 ,  C01B003/32

CPC classification number: C01B3/386 ,  B01J23/002 ,  B01J23/63 ,  B01J23/83 ,  B01J35/002 ,  B01J37/0207 ,  B01J2523/00 ,  C01B3/40 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/1047 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C10G2/32 ,  Y02P20/52 ,  Y10S502/525 ,  B01J2523/31 ,  B01J2523/3737 ,  B01J2523/3706

Abstract: The present invention relates to improved catalyst compositions, as well as methods of making and using such compositions. In particular, preferred embodiments of the present invention comprise rare earth catalyst supports, catalyst compositions having rare earth supports, and methods of preparing and using the catalysts and supports. Accordingly, the present invention also encompasses an improved method for converting a hydrocarbon containing gas and an oxygen containing gas to a gas mixture comprising hydrogen and carbon monoxide, i.e., syngas, using the rare earth catalyst supports in accordance with the present invention. In addition, the present invention contemplates an improved method for converting hydrocarbon gas to liquid hydrocarbons using the novel syngas catalyst supports and compositions described herein.

Abstract translation: 本发明涉及改进的催化剂组合物，以及制备和使用这些组合物的方法。 特别地，本发明的优选实施方案包括稀土催化剂载体，具有稀土载体的催化剂组合物，以及制备和使用催化剂和载体的方法。 因此，本发明还包括使用根据本发明的稀土催化剂载体将含烃气体和含氧气体转化为包含氢气和一氧化碳（即合成气）的气体混合物的改进方法。 此外，本发明考虑了使用本文所述的新型合成气催化剂载体和组合物将烃气体转化为液体烃的改进方法。

公开(公告)号：US20030198592A1

公开(公告)日：2003-10-23

申请号：US10126395

申请日：2002-04-19

Applicant: Conoco Inc.

Inventor： Joe D. Allison ,  Sriram Ramani ,  Daxiang Wang ,  Tianyan Niu ,  Yaming Jin ,  Gloria I. Straguzzi

IPC: C01B003/26

CPC classification number: C01B3/382 ,  B01J23/002 ,  B01J23/63 ,  B01J23/8993 ,  B01J35/0006 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/1011 ,  C01B2203/1041 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/143 ,  C01B2203/82 ,  Y02P20/142 ,  Y02P20/52

Abstract: Embodiments include a method and apparatus for converting a hydrocarbon and oxygen feed stream to a product stream such as syngas, including multiple serially aligned reaction zones and multiple hydrocarbon feeds. The first reaction zone catalyzes the net partial oxidation of the feed hydrocarbon. The subsequent zones catalyze reactions such as the stream or dry reforming of hydrocarbons or the water gas shift reaction, depending on the stream composition in the vicinity of the zone, and the desired product stream composition.

Abstract translation: 实施方案包括用于将烃和氧进料流转化为产物流如合成气的方法和装置，包括多个连续排列的反应区和多个烃进料。 第一反应区催化进料碳的净部分氧化。 随后的区域根据区域附近的流组成以及所需的产物流组合物催化烃类或水煤气变换反应的反应如烃或干重整。