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公开(公告)号:US20170029673A1
公开(公告)日:2017-02-02
申请号:US15121663
申请日:2015-03-31
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: Bindu Krishnan , Laura A. Grier , William H. Heath , Adam C. Colson , Mikhail Y Gelfer , Gary L. Jialanella
IPC: C09J163/00 , C08K9/06 , C09J5/04 , C08G18/12 , C09J175/16 , C08G18/76 , C08G18/67 , C08G18/24 , C08G59/40 , C08G59/56 , C08K3/20 , C08G18/48
CPC classification number: C09J163/00 , C08G18/10 , C08G18/12 , C08G18/242 , C08G18/4841 , C08G18/672 , C08G18/7621 , C08G59/4064 , C08G59/44 , C08G59/56 , C08K3/20 , C08K9/06 , C08K2003/2206 , C08K2201/019 , C08L63/00 , C09J5/04 , C09J175/16 , C08L75/04
Abstract: The invention relates to isocyanate-free elastomer adhesives based on hybrid urethane-acrylate epoxies. The hybrid shows properties consistent for structural adhesives with excellent mechanical and thermal stability, and low read-through. The adhesives are suitable for use in industry, e.g., as adhesives for automotive applications.
Abstract translation: 本发明涉及基于杂化氨基甲酸酯 - 丙烯酸酯环氧树脂的无异氰酸酯弹性体粘合剂。 该混合物显示出具有优异的机械和热稳定性以及低读数的结构粘合剂的性能一致性。 粘合剂适用于工业,例如用作汽车应用的粘合剂。
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公开(公告)号:US20180346637A1
公开(公告)日:2018-12-06
申请号:US15774827
申请日:2016-11-09
Applicant: Dow Global Technologies LLC
Inventor: Adam C. Colson , Dan Yu , Daniel A. Aguilar , Amber Marie Stephenson , William H. Heath , Shouren Ge
IPC: C08G18/48 , C08G18/76 , C08G18/10 , C09J175/08 , C09D175/08
CPC classification number: C08G18/4854 , C08G18/10 , C08G18/3206 , C08G18/4812 , C08G18/7614 , C08G18/7671 , C09D175/08 , C09J175/08 , C08G18/48
Abstract: A cured composition including a reaction product of a mixture that includes an isocyanate component having one or more isocyanates and an isocyanate-reactive component having a butylene oxide based polyol, which has a number average molecular weight greater than 2,000 g/mol and less than 8,000 g/mol and a nominal hydroxyl functionality from (2) to (4). At least (50) wt % of a total weight of alkylene oxides used to form the butylene oxide based polyol is butylene oxide. An isocyanate index of the mixture is from (90) to (150). The cured composition in a cured state exhibits a first tan delta peak between a first temperature range of 50° C. to 0° C. and a second tan delta peak between a second temperature range of 75° C. and 150° C., according to a tan delta plot over a range of temperatures, and a value of the first tan delta peak and a value of the second tan delta peak each represents a ratio of a loss modulus of the cured composition and a storage modulus of the cured composition at a specific temperature within the range of temperatures, as measured according to dynamic mechanical thermal analysis. The values of the first and the second tan delta peaks are from (0.10) to (0.90).
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公开(公告)号:US20180046076A1
公开(公告)日:2018-02-15
申请号:US15559564
申请日:2016-02-25
Applicant: Dow Global Technologies LLC
Inventor: Christopher S. Letko , William H. Heath , Nathan Wilmot , Sven Claessens , William L. Heaner, IV , Adam C. Colson , Stephen W. King , John G. Pendergast, Jr.
CPC classification number: G03F7/0037 , B29C64/135 , B29K2033/04 , B29K2063/00 , B29K2075/00 , B29K2105/0002 , B33Y10/00 , B33Y70/00 , B33Y80/00 , C08F290/067 , C08G18/10 , C08G18/246 , C08G18/4866 , C08G18/672 , C08G18/673 , C08G18/7607 , C08G18/7671 , G03F7/031 , C08G18/48 , C08F222/1006
Abstract: A three-dimensional printing photocurable composition includes from 20 wt % to 70 wt % of an urethane acrylate component, from 20 wt % to 60 wt % of a multifunctional epoxide component, from 1 wt % to 15 wt % of a monomer component, and from 1 wt % to 8 wt % of a photoinitiator component, based on the total weight of the composition. The urethane acrylate component includes the capping reaction product of an acrylate and an isocyanate terminated prepolymer and the isocyanate-terminated prepolymer is the reaction product of a polyisocyanate and at least one polyol having a molecular weight of at least 3000 g/mol. The multifunctional epoxide component includes one or more multifunctional epoxides. The monomer component includes at least one of a multifunctional acrylate monomer and a multifunctional vinyl ether monomer.
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公开(公告)号:US20210355030A1
公开(公告)日:2021-11-18
申请号:US16319089
申请日:2017-09-15
Applicant: Dow Global Technologies LLC
Inventor: Kaoru Aou , Sachit Goyal , Adam C. Colson , Juan Carlos Medina
Abstract: A method of preparing a polymer concrete composition includes preparing one or more adhesion promoter pre-coated aggregates, each having a base substrate and an adhesion promoter coating and the adhesion promoter coating being an outermost layer on the base substrate, providing a base composition including an isocyanate component and an isocyanate-reactive component, and mixing the one or more adhesion promoter pre-coated aggregates, the isocyanate component, and the isocyanate-reactive component to form the polymer concrete composition.
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公开(公告)号:US10066136B2
公开(公告)日:2018-09-04
申请号:US15121663
申请日:2015-03-31
Applicant: Dow Global Technologies LLC
Inventor: Bindu Krishnan , Laura A. Grier , William H. Heath , Adam C. Colson , Mikhail Y. Gelfer , Gary L. Jialanella
IPC: C08L63/00 , C09J163/00 , C08G18/48 , C08G18/67 , C08G18/76 , C08G18/10 , C08G18/12 , C09J175/16 , C08G59/40 , C08G59/44 , C08G18/24 , C08G59/56 , C08K3/20 , C08K9/06 , C09J5/04 , C08K3/22
Abstract: The invention relates to isocyanate-free elastomer adhesives based on hybrid urethane-acrylate epoxies. The hybrid shows properties consistent for structural adhesives with excellent mechanical and thermal stability, and low read-through. The adhesives are suitable for use in industry, e.g., as adhesives for automotive applications.
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公开(公告)号:US20150315330A1
公开(公告)日:2015-11-05
申请号:US14648626
申请日:2013-12-18
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: William Heath , Phillip S. Athey , Nathan Wilmot , Harshad M. Shah , Kamesh R. Vyakaranam , Nicole Knight , Adam C. Colson
IPC: C08G59/14
Abstract: Elastomers are prepared from a reaction mixture that contains a polyene compound, an epoxy resin, a thiol curing agent and a basic catalyst. The polyene compound has an average of at least two groups containing aliphatic carbon-carbon double bonds capable of reaction with a thiol group. At least one of said aliphatic carbon-carbon double bonds is separated from each other said aliphatic carbon-carbon double bond by an aliphatic spacer group having a weight of at least 500 atomic mass units. These elastomers are typically phase-separated materials having good elongation and tensile properties.
Abstract translation: 弹性体由含有多烯化合物,环氧树脂,硫醇固化剂和碱性催化剂的反应混合物制备。 多烯化合物平均具有至少两个能够与硫醇基反应的脂族碳 - 碳双键的基团。 所述脂肪族碳 - 碳双键中的至少一个通过具有至少500原子质量单位的重量的脂肪族间隔基彼此分离,所述脂肪族碳 - 碳双键。 这些弹性体通常是具有良好伸长率和拉伸性能的相分离材料。
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公开(公告)号:US20210340375A1
公开(公告)日:2021-11-04
申请号:US16319081
申请日:2017-09-12
Applicant: Dow Global Technologies LLC
Inventor: Kaoru Aou , Sachit Goyal , Adam C. Colson , Juan Carlos Medina , Phillip S. Athey , Arjun Raghuraman
IPC: C08L75/08 , C09D177/06 , C09D161/06 , C09D163/00 , C09D175/08
Abstract: A polymer concrete composition has a base composition including a first isocyanate component and a first isocyanate reactive component, and one or more pre-coated aggregates that each has a base substrate and a two-component reaction product polymeric coating on an outer surface of the base substrate. The polymeric coating is the reaction product of a second isocyanate component and a second isocyanate-reactive component.
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公开(公告)号:US10662276B2
公开(公告)日:2020-05-26
申请号:US15774827
申请日:2016-11-09
Applicant: Dow Global Technologies LLC
Inventor: Adam C. Colson , Dan Yu , Daniel A. Aguilar , Amber Marie Stephenson , William H. Heath , Shouren Ge
IPC: C08G18/48 , C08G18/10 , C09D175/08 , C09J175/08 , C08G18/76 , C08G18/32
Abstract: A cured composition including a reaction product of a mixture that includes an isocyanate component having one or more isocyanates and an isocyanate-reactive component having a butylene oxide based polyol, which has a number average molecular weight greater than 2,000 g/mol and less than 8,000 g/mol and a nominal hydroxyl functionality from (2) to (4). At least (50) wt % of a total weight of alkylene oxides used to form the butylene oxide based polyol is butylene oxide. An isocyanate index of the mixture is from (90) to (150). The cured composition in a cured state exhibits a first tan delta peak between a first temperature range of 50° C. to 0° C. and a second tan delta peak between a second temperature range of 75° C. and 150° C., according to a tan delta plot over a range of temperatures, and a value of the first tan delta peak and a value of the second tan delta peak each represents a ratio of a loss modulus of the cured composition and a storage modulus of the cured composition at a specific temperature within the range of temperatures, as measured according to dynamic mechanical thermal analysis. The values of the first and the second tan delta peaks are from (0.10) to (0.90).
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公开(公告)号:US20180162988A1
公开(公告)日:2018-06-14
申请号:US15577903
申请日:2016-05-27
Applicant: Dow Global Technologies LLC
Inventor: Adam C. Colson , Amber Marie Stephenson , Bindu Krishnan
IPC: C08G18/79 , C08G18/66 , C08G18/48 , C09D175/08 , C09J175/08 , C08G18/32
Abstract: A curable composition includes a reaction product of an isocyanate component that includes one or more isocyanates, at an isocyanate index being from 90 to 150, and an isocyanate reactive component that includes a blend including from 5 wt % to 95 wt % of a first butylene oxide based polyol and from 5 wt % to 95 wt % of a second butylene oxide based polyol. The first butylene oxide based polyol has a number average molecular weight from 200 g/mol to 1,000 g/mol and a nominal hydroxyl functionality from 2 to 6. The second butylene oxide based polyol has a number average molecular weight greater than 1,000 g/mol and less than 8,000 g/mol and a nominal hydroxyl functionality from 2 to 4. The blend accounts for at least 50 wt % of a total weight of polyols in the isocyanate-reactive component.
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公开(公告)号:US20170369635A1
公开(公告)日:2017-12-28
申请号:US15533640
申请日:2015-12-05
Applicant: Dow Global Technologies LLC
Inventor: Adam C. Colson , Avery L. Watkins , Zubin B. Kuvadia , Kwanho Chang
Abstract: Rapidly gelling epoxy resin systems include an epoxy resin, certain acrylate-functional compounds, and a curing agent mixture that includes a thiol curing agent and an amine curing agent. Gel times well less than 1 minute can be obtained. The ratio of acrylate-functional compound to thiol curing agent can be varied to adjust the gel time to precise values within a broad range.
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