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    Thermoplastic vulcanizate including a block composite
    1.
    发明授权
    Thermoplastic vulcanizate including a block composite 有权

    公开(公告)号：US10344154B2

    公开(公告)日：2019-07-09

    申请号：US15538953

    申请日：2015-12-11

    Applicant: Dow Global Technologies LLC

    Inventor： Xiaosong Wu ,  Colin Li Pi Shan ,  Kim L. Walton ,  Gary R. Marchand

    IPC: C08L23/14 ,  C08L23/16 ,  C08L53/00 ,  C08F297/08

    Abstract: A thermoplastic vulcanizate composition includes (A) greater than 15 wt % of a block composite that has (i) an ethylene/alpha-olefin/diene interpolymer in which the alpha-olefin is an alpha olefin monomer having from 3 to 10 carbon atoms and the diene is a diene monomer having from 2 to 25 carbon atoms, (ii) a propylene based polymer, and (iii) a block copolymer comprising a soft block and a hard block in which the soft block has the same composition as the ethylene/alpha-olefin/diene polymer and the hard block has the same composition as the propylene based polymer; and (B) a remainder of a curative system and optionally at least one of a vulcanizable elastomer, a thermoplastic polyolefin, and an oil.

    Process to produce polyolefin ionomers and ionomers produced thereby
    2.
    发明授权
    Process to produce polyolefin ionomers and ionomers produced thereby 有权

    公开(公告)号：US10167360B2

    公开(公告)日：2019-01-01

    申请号：US15111178

    申请日：2014-12-15

    Applicant: Dow Global Technologies LLC ,  Regents of the University of Minnesota

    Inventor： Henry Martinez ,  Marc A. Hillmyer ,  Jeffrey C. Munro ,  Kim L. Walton ,  Morgan M. Hughes

    IPC: C08G61/08

    Abstract: A process to produce an ionomer comprising reacting alkyl-cis-cyclooctene and cis-cyclooctene in a mole ratio from 1:0 to 0:1, in the presence of a difunctional chain transfer agent under ring opening metathesis polymerization conditions to form an unsaturated polyolefin reactive telechelic pre-polymer; hydrogenating the unsaturated polyolefin reactive telechelic pre-polymer to produce a hydrogenated polyolefin reactive telechelic pre-polymer; reacting the hydrogenated polyolefin reactive telechelic pre-polymer with at least one compound according to the formula aMx+b(R)y, wherein M is a metal, x is a charge of M, R is an alkyl, aryl, oxide, or fatty acid, y is a charge of R, a and b are integers of at least 1, and ax+by=0, to form an ionomer is provided. Further provided are ionomers produced thereby.

    A POLYOLEFIN BLEND COMPOSITION AND ARTICLES MADE THEREFROM
    5.
    发明申请
    A POLYOLEFIN BLEND COMPOSITION AND ARTICLES MADE THEREFROM 有权
    POLYOLEFIN混合组合物及其制品

    公开(公告)号：US20160083571A1

    公开(公告)日：2016-03-24

    申请号：US14391318

    申请日：2013-04-02

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Guang Ming Li ,  Colin LiPiShan ,  Kim L. Walton ,  Raymond L. Laakso, JR. ,  Walter J. Brown

    IPC: C08L23/14

    CPC classification number: C08L23/14 ,  C08L23/142 ,  C08L2205/025 ,  C08L2205/03 ,  C08L23/0815

    Abstract: The instant invention provides a polyolefin blend composition, process for producing the same, and articles made therefrom. The polyolefin blend composition according to the present invention comprises: (a) from 75 to 97 percent by weight of one or more random propylene copolymers having a DSC melting point in the range of from 120° C. to 160° C., and a melt flow rate (MFR) in the range of from 1 to 120 g/10 minutes; (b) from 3 to 25 percent by weight of one or more ethylene ?-olefin copolymers having a melt index (I2) in the range of from 100 to 1500 g/10 minutes, a density in the range of 0.860 to 0.910 g/cm3, and a molecular weight (Mw) in the range of from 10,000 to 50,000 g/mole, wherein said ethylene ?-olefin copolymer is homogenously branched copolymer, and wherein said ethylene ?-olefin copolymer is linear or substantially linear; (c) optionally from 5 to 15 percent by weight of one or more propylene ?-olefin interpolymers having a DSC melting point in the range of less than 110° C., a heat of fusion in the range of less than 50 Joules/gram, and a crystallinity in the range of from at least 1 percent by to 40 percent by weight, and a melt flow rate in the range of less than 80 g/10 minutes.

    Abstract translation: 本发明提供了一种聚烯烃共混组合物，其制备方法和由其制成的制品。 根据本发明的聚烯烃共混物组合物包含：（a）75至97重量％的一种或多种DSC熔点在120℃至160℃范围内的无规丙烯共聚物，和 熔体流动速率（MFR）在1至120g / 10分钟的范围内; （b）3至25重量％的一种或多种熔体指数（I 2）在100至1500g / 10分钟范围内的乙烯α-烯烃共聚物，密度在0.860至0.910g / cm 3，分子量（Mw）在10,000〜50,000g / mol范围内，其中所述乙烯α-烯烃共聚物是均匀支化的共聚物，并且其中所述乙烯α-烯烃共聚物是线性或基本上线性的; （c）任选的5至15重量％的一种或多种DSC熔点在小于110℃范围内的丙烯α-烯烃互聚物，熔融热在小于50焦耳/克 ，结晶度在至少1重量％至40重量％的范围内，熔体流动速率在小于80克/ 10分钟的范围内。

    Polyolefin blends including compatibilizer
    8.
    发明授权
    Polyolefin blends including compatibilizer 有权

    公开(公告)号：US10597520B2

    公开(公告)日：2020-03-24

    申请号：US15758952

    申请日：2016-09-08

    Applicant: Dow Global Technologies LLC

    Inventor： Yushan Hu ,  Kyle Anderson ,  Gary R. Marchand ,  Kim L. Walton ,  Colin LiPiShan

    IPC: C08L23/06 ,  C08L53/00

    Abstract: A composition comprising from 10 wt % to 90 wt % of an ethylene component including at least one ethylene based polymer having an ethylene content of at least 50.0 wt %, a melt index from 0.1 g/10 min to 100.0 g/10 min, and a density from 0.935 g/cm3 to 0.965 g/cm3; from 10 wt % to 90 wt % of a propylene component including at least one propylene based polymer having a propylene content of at least 50.0 wt % and a melt flow rate from 0.5 g/10 min to 200.0 g/10 min; and from 1 wt % to 20 wt % of a composite component including a specified block composite, derived from at least ethylene and an alpha-olefin.

    Nucleation with a block composite nucleator
    10.
    发明授权
    Nucleation with a block composite nucleator 有权

    公开(公告)号：US10155861B2

    公开(公告)日：2018-12-18

    申请号：US15505475

    申请日：2015-08-20

    Applicant: Dow Global Technologies LLC

    Inventor： Yi Jin ,  Kim L. Walton ,  Morgan M. Hughes ,  Thomas W. Karjala ,  Lamy J. Chopin, III ,  Dean Lee ,  Rongjuan Cong

    IPC: C08L53/00 ,  C08L23/14 ,  C08L23/16 ,  C09J153/00 ,  C09J123/14 ,  C09J123/20

    Abstract: A composition includes (A) 30-95 wt % of a random or homogeneous propylene-based interpolymer having: (i) a comonomer content of at least one of C2 and C4-10 α-olefins of 7 wt % to 49 wt % based on the total weight of the propylene-based interpolymer, (ii) a density of 0.90 g/cc or less, and (iii) an MFR of 1 g/10 min or greater (230° C./2.16 kg); and (B) 5-70 wt % of a block composite nucleator comprising: (1) a first polymer that includes polypropylene; (2) a second polymer that includes an alpha-olefin based polymer, the alpha-olefin being selected from at least one of a C2 and C4-10 α-olefins, and (3) a block copolymer having a first segment and a second segment, the first segment of the block copolymer having the same composition as the first polymer in the block composite nucleator and the second segment of the block copolymer having the same composition as the second polymer of the block composite nucleator.

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