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    Aminoplast curable coating compositions containing cycloaliphatic sulfonic acid esters as latent acid catalysts
    1.
    发明授权
    Aminoplast curable coating compositions containing cycloaliphatic sulfonic acid esters as latent acid catalysts 失效
    含有脂环族磺酸酯作为潜酸催化剂的氨基塑料可固化涂料组合物

    公开(公告)号：US4454274A

    公开(公告)日：1984-06-12

    申请号：US427400

    申请日：1982-09-29

    申请人： Debra L. Singer ,  Gregory J. McCollum ,  Rostyslaw Dowbenko ,  Roger M. Christenson

    发明人： Debra L. Singer ,  Gregory J. McCollum ,  Rostyslaw Dowbenko ,  Roger M. Christenson

    IPC分类号： C08F8/36 ,  C08K5/42

    CPC分类号： C08K5/42 ,  C07C309/00

    摘要： A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin; and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formulas: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom;W is C.sub.1 -C.sub.18 alkylene, C.sub.2 -C.sub.18 alkenylene;V is C.sub.1 -C.sub.18 alkylene, C.sub.1 -C.sub.18 hydroxyl substituted alkylene, C.sub.2 -C.sub.18 alkenylene, C.sub.2 -C.sub.18 hydroxyl substituted alkenylene; andR.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical.

    摘要翻译： 能够进行酸催化交联的高固含量有机溶剂型可喷涂涂料组合物由含活性氢的树脂，外部存在和/或内部作为活性含氢树脂的一部分存在的固化剂组成。 和催化量的磺酸的非离子酯。 磺酸酯由以下结构式表示：其中：Z是选自氨基和有机基团的基团，所述有机基团与硫连接 原子由碳原子; W是C 1 -C 18亚烷基，C 2 -C 18亚烯基; V是C 1 -C 18亚烷基，C 1 -C 18羟基取代的亚烷基，C 2 -C 18亚烯基，C 2 -C 18羟基取代的亚烯基; 并且R 1，R 2，R 3，R 4，R 5独立地为氢或有机基团。

    Aminoplast curable coating compositions containing sulfonic acid esters as latent acid catalysts
    2.
    发明授权
    Aminoplast curable coating compositions containing sulfonic acid esters as latent acid catalysts 失效
    含有磺酸酯作为潜酸催化剂的氨基塑料可固化涂料组合物

    公开(公告)号：US4477618A

    公开(公告)日：1984-10-16

    申请号：US427402

    申请日：1982-09-29

    申请人： Debra L. Singer ,  Gregory J. McCollum ,  Rostyslaw Dowbenko ,  Roger M. Christenson ,  Michael M. Chau ,  Wen-Hsuan Chang

    发明人： Debra L. Singer ,  Gregory J. McCollum ,  Rostyslaw Dowbenko ,  Roger M. Christenson ,  Michael M. Chau ,  Wen-Hsuan Chang

    IPC分类号： C08F8/36 ,  C08K5/42 ,  C09D161/20

    CPC分类号： C07C309/00 ,  C08K5/42 ,  C09D161/20

    摘要： A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formula: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom; ##STR2## C.sub.3 -C.sub.20 cycloalkyl; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical. These groups can be particularly described as follows:R.sub.1 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.2 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.3 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.4 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl, andR.sub.5 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl.

    摘要翻译： 能够进行酸催化交联的高固体，有机溶剂型可喷涂涂料组合物由含活性氢的树脂，在外部和/或内部作为含活性氢树脂的一部分存在的固化剂组成，以及 催化量的磺酸的非离子酯。 磺酸酯由以下结构式表示：其中：Z是选自氨基和有机基团的基团，所述有机基团通过碳原子连接到硫原子上; C3-C20环烷基; 并且R 1，R 2，R 3，R 4，R 5独立地为氢或有机基团。 这些基团可以特别描述如下：R 1是氢，烷氧羰基，C 3 -C 20烷基，C 6 -C 18芳基或C 3 -C 20环烷基; R2是氢，烷氧羰基，C3-C20烷基，C6-C18芳基或C3-C20环烷基; R3是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3-C20烷基，C6-C18芳基或C3-C20环烷基; R4是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3-C20烷基，C6-C18芳基或C3-C20环烷基，R5是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3 -C 20烷基，C 6 -C 18芳基或C 3 -C 20环烷基。

    Acrylic functional urethane alkyd resin coating compositions
    9.
    发明授权
    Acrylic functional urethane alkyd resin coating compositions 失效
    丙烯酸官能氨基甲酸酯醇酸树脂涂料组合物

    公开(公告)号：US4591518A

    公开(公告)日：1986-05-27

    申请号：US639874

    申请日：1984-08-13

    申请人： William J. Schillinger ,  J. Alden Erikson ,  Rostyslaw Dowbenko ,  Roger M. Christenson

    发明人： William J. Schillinger ,  J. Alden Erikson ,  Rostyslaw Dowbenko ,  Roger M. Christenson

    IPC分类号： C09D175/14 ,  C08G18/42 ,  C08G18/81 ,  C09D175/16 ,  B05D3/02 ,  C08F20/00 ,  C08G63/76

    CPC分类号： C09D175/16 ,  C08G18/4288 ,  C08G18/8108 ,  C08G18/8158

    摘要： An air oxidizable coating composition is disclosed comprising an ungelled urethane modified alkyd resin containing pendant polymerizable unsaturated groups attached to the alkyd through urethane linkages. The ungelled urethane modified alkyd is the reaction product of components comprising a hydroxyl containing, air oxidizable alkyd resin having an oil length of between about 20 percent and about 70 percent and an isocyanate-functional ethylenically unsaturated compound. Also disclosed are a process for coating the substrate with the coating composition and certain ungelled urethane modified alkyd resins.

    摘要翻译： 公开了一种空气可氧化涂料组合物，其包含含有通过氨基甲酸酯键连接到醇酸树脂上的侧基聚合不饱和基团的未凝胶化的聚氨酯改性醇酸树脂。 未凝胶化的氨基甲酸酯改性醇酸树脂是包含具有约20％至约70％的油长度的含羟基的可空气可氧化醇酸树脂和异氰酸酯官能的烯属不饱和化合物的组分的反应产物。 还公开了用涂料组合物和某些未凝胶化的氨基甲酸酯改性醇酸树脂涂覆基材的方法。