公开(公告)号：US20190119510A1

公开(公告)日：2019-04-25

申请号：US15790922

申请日：2017-10-23

Applicant: Christophe Steinbrecher ,  Cédric Le Fevere De Ten Hove ,  Robert Van't Sand ,  Denis Heymans ,  Aleksandra Kotlewska

Inventor： Christophe Steinbrecher ,  Cédric Le Fevere De Ten Hove ,  Robert Van't Sand ,  Denis Heymans ,  Aleksandra Kotlewska

IPC: C09D7/47 ,  C07C53/128 ,  C09D7/20

Abstract: The invention relates to compositions of α,α-branched alkane carboxylic acids glycidyl esters with a defined isomeric composition where the sum of the concentration of the blocked and of the highly branched isomers is maximum 55% preferably below 40%, and most preferably below 30%.The mixture of neononanoic acid glycidyl esters comprising at least 2,2-dimethyl heptanoic acid glycidyl ester and 2-methyl 2-ethyl hexanoic acid glycidyl ester and 2-methyl 2-ethyl 3-methyl pentanoic acid glycidyl esters.

公开(公告)号：US09783709B2

公开(公告)日：2017-10-10

申请号：US14989361

申请日：2016-01-06

Applicant: Denis Heymans

Inventor： Denis Heymans

IPC: C07C51/00 ,  C09J133/06 ,  C08F18/10 ,  C08F218/08 ,  C09D133/08 ,  C09J133/08

CPC classification number: C09J133/06 ,  C08F18/10 ,  C08F218/08 ,  C09D133/08 ,  C09J133/08 ,  C08F218/10

Abstract: The invention relates to a process for the manufacture of α,α-branched carboxylic acids vinyl esters comprising the following steps: isomerising and converting an olefin feed with CO and water under Koch reaction conditions to make an acid with a ratio of Non Blocking isomers (NB) versus Blocking isomers (B) of NB/B above 1.5, wherein a blocking isomer has always a tertiary carbon atom in alpha position of the carboxylic acid and in the beta position of the carboxylic acid, whereas a non-blocking isomer has primary carbon atoms in the beta position of the carboxylic acid converting the resulting acid into a vinyl ester.

公开(公告)号：US09260374B2

公开(公告)日：2016-02-16

申请号：US14007699

申请日：2012-04-03

Applicant: Denis Heymans

Inventor： Denis Heymans

IPC: C07C51/00 ,  C07C67/38 ,  C08K5/101 ,  C07C67/04 ,  C07C51/14 ,  C08F220/04 ,  C07C69/533 ,  C07C69/56

CPC classification number: C07C67/38 ,  C07C51/14 ,  C07C67/04 ,  C07C69/533 ,  C07C69/56 ,  C08F220/04 ,  C08K5/101 ,  C07C53/128 ,  C07C69/24

Abstract: The invention relates to a process for the manufacture of α,α-branched carboxylic acids vinyl esters comprising the following steps: isomerizing and converting an olefin feed with CO and water under Koch reaction conditions to make an acid with a ratio of Non Blocking isomers (NB) versus Blocking isomers (B) of NB/B above 1.5, wherein a blocking isomer has always a tertiary carbon atom in alpha position of the carboxylic acid and in the beta position of the carboxylic acid, whereas a non-blocking isomer has primary carbon atoms in the beta position of the carboxylic acid converting the resulting acid into a vinyl ester.

Abstract translation: 本发明涉及一种制备α，α-支化羧酸乙烯基酯的方法，其包括以下步骤：在Koch反应条件下用CO和水异构化和转化烯烃进料以制备具有非封闭异构体比例的酸（ NB）相对于1.5以上的NB / B的封闭异构体（B），其中阻聚异构体在羧酸的α位置和羧酸的β位总是具有叔碳原子，而非阻塞异构体具有伯 羧酸的β位上的碳原子将所得酸转化成乙烯基酯。

公开(公告)号：US20140316030A1

公开(公告)日：2014-10-23

申请号：US13880604

申请日：2011-10-12

Applicant: Cédric Le Fevere de Ten Hove ,  Denis Heymans ,  Christophe Steinbrecher ,  Aleksandra Kotlewska ,  Robert Van't Sand

Inventor： Cédric Le Fevere de Ten Hove ,  Denis Heymans ,  Christophe Steinbrecher ,  Aleksandra Kotlewska ,  Robert Van't Sand

IPC: C09D7/12 ,  C08F8/14

CPC classification number: C08F8/14 ,  C07C51/15 ,  C07D303/16 ,  C08G63/91 ,  C09D7/65 ,  C07C53/128

Abstract: The invention relates to a manufacturing process for the preparation of α,α-branched alkane carboxylic acids providing glycidyl esters with an improved softness or hardness of the coatings derived thereof.In which the mixture of neononanoic acid providing a high hardness is a mixture where the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75%. In which a mixture of neononanoic acids providing soft polymers is a mixture where the concentration of blocked and highly branched isomers is maximum 55%, preferably below 40% and most preferably below 30%.

Abstract translation: 本发明涉及一种制备提供缩水甘油酯的α，α-支链烷烃羧酸的制备方法，其具有改进的衍生自其的涂料的柔软度或硬度。 其中提供高硬度的新戊酸的混合物是其中封端和高度支化的异构体的浓度之和为至少50％，优选高于60％，最优选高于75％的混合物。 其中提供软质聚合物的新戊酸的混合物是其中封闭和高度支化的异构体的浓度最大为55％，优选低于40％，最优选低于30％的混合物。

公开(公告)号：US20140256906A1

公开(公告)日：2014-09-11

申请号：US13997309

申请日：2011-12-16

Applicant: Christophe Steinbrecher ,  Cedric Le Fevere De Ten Hove ,  Robert Van't Sand ,  Denis Heymans ,  Aleksandra Joanna Kotlewska

Inventor： Christophe Steinbrecher ,  Cedric Le Fevere De Ten Hove ,  Robert Van't Sand ,  Denis Heymans ,  Aleksandra Joanna Kotlewska

IPC: C08G63/66

CPC classification number: C08G63/66 ,  C07D303/16 ,  C08G18/4291 ,  C08G59/12 ,  C08K5/1515 ,  C08L33/04 ,  C08L63/00 ,  C08L67/02 ,  C08L71/02 ,  C09D4/00 ,  C09D133/04 ,  C09D163/00 ,  C09D167/02 ,  C09D171/02

Abstract: The invention relates to compositions of α,α-branched alkane carboxylic acids glycidyl esters with a define isomeric composition where the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75% on total composition.

Abstract translation: 本发明涉及具有定义的异构体组合物的α，α-支链烷烃羧酸缩水甘油酯的组合物，其中封端和高度支化的异构体的浓度之和为至少50％，优选高于60％，最优选高于 75％的总成分。

公开(公告)号：US09879113B2

公开(公告)日：2018-01-30

申请号：US13997309

申请日：2011-12-16

Applicant: Christophe Steinbrecher ,  Cedric Le Fevere De Ten Hove ,  Robert Van't Sand ,  Denis Heymans ,  Aleksandra Joanna Kotlewska

Inventor： Christophe Steinbrecher ,  Cedric Le Fevere De Ten Hove ,  Robert Van't Sand ,  Denis Heymans ,  Aleksandra Joanna Kotlewska

IPC: C07D303/16 ,  C08G18/00 ,  C08G63/66 ,  C08G65/08 ,  C08G18/42 ,  C08G18/62 ,  C08G63/91 ,  C09D163/00 ,  C09D7/12 ,  C09D201/00 ,  C09D125/14 ,  C09D133/02 ,  C09D167/02 ,  C09D171/02 ,  C09D201/06 ,  C09D7/00 ,  C09J11/06 ,  C09J201/02 ,  C07C67/465 ,  C08K5/10 ,  C08F120/28 ,  C08F8/00 ,  C08L63/00 ,  C08K5/1515 ,  C08L33/04 ,  C08L67/02 ,  C09D133/04 ,  C08L71/02 ,  C08G59/12 ,  C09D4/00

CPC classification number: C08G63/66 ,  C07D303/16 ,  C08G18/4291 ,  C08G59/12 ,  C08K5/1515 ,  C08L33/04 ,  C08L63/00 ,  C08L67/02 ,  C08L71/02 ,  C09D4/00 ,  C09D133/04 ,  C09D163/00 ,  C09D167/02 ,  C09D171/02

Abstract: The invention relates to compositions of α,α-branched alkane carboxylic acids glycidyl esters with a define isomeric composition where the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75% on total composition.

公开(公告)号：US20150240077A1

公开(公告)日：2015-08-27

申请号：US14427585

申请日：2013-09-03

Applicant: Christophe Steinbrecher ,  Denis Heymans ,  Bedri Erdem ,  Mike O'Shaugnessy ,  Jeff Blaisdell

Inventor： Christophe Steinbrecher ,  Denis Heymans ,  Bedri Erdem ,  Mike O'Shaugnessy ,  Jeff Blaisdell

IPC: C08L75/06

CPC classification number: C08L75/06 ,  C08G18/0823 ,  C08G18/10 ,  C08G18/12 ,  C08G18/42 ,  C08G18/6659 ,  C08G18/3231

Abstract: This invention relates to a Waterborne Polyurethane Dispersions (WPU) derived from the reaction products of tertiary alkyl glycidyl esters based hydroxyl terminal polyester polyols with polyisocyanates and chain extended with poly-functional amines and dispersed in water have shown the surprising inherent ability for self-coalescence. Furthermore the cured films have shown improved hardness and abrasion resistance over these benchmarks with a significant reduction in coalescing solvent needed to accomplish film formation.

Abstract translation: 本发明涉及衍生自叔烷基缩水甘油酯基羟基末端聚酯多元醇与多异氰酸酯和延伸有多官能胺并且分散在水中的链的反应产物的水性聚氨酯分散体（WPU），其显示出令人惊奇的自聚合固有能力 。 此外，固化膜显示出比这些基准提高的硬度和耐磨性，并且显着降低完成成膜所需的聚结溶剂。

公开(公告)号：US20140303387A1

公开(公告)日：2014-10-09

申请号：US14007699

申请日：2012-04-03

Applicant: Denis Heymans

Inventor： Denis Heymans

IPC: C07C67/38 ,  C07C69/56 ,  C07C69/533

CPC classification number: C07C67/38 ,  C07C51/14 ,  C07C67/04 ,  C07C69/533 ,  C07C69/56 ,  C08F220/04 ,  C08K5/101 ,  C07C53/128 ,  C07C69/24

Abstract: The invention relates to a process for the manufacture of α,α-branched carboxylic acids vinyl esters comprising the following steps: isomerising and converting an olefin feed with CO and water under Koch reaction conditions to make an acid with a ratio of Non Blocking isomers (NB) versus Blocking isomers (B) of NB/B above 1.5, wherein a blocking isomer has always a tertiary carbon atom in alpha position of the carboxylic acid and in the beta position of the carboxylic acid, whereas a non-blocking isomer has primary carbon atoms in the beta position of the carboxylic acid converting the resulting acid into a vinyl ester.

Abstract translation: 本发明涉及一种制备α，α-支链羧酸乙烯基酯的方法，包括以下步骤：在Koch反应条件下用CO和水异构化和转化烯烃进料以制备具有非封闭异构体比例的酸（ NB）相对于1.5以上的NB / B的封闭异构体（B），其中阻聚异构体在羧酸的α位置和羧酸的β位总是具有叔碳原子，而非阻塞异构体具有伯 羧酸的β位上的碳原子将所得酸转化成乙烯基酯。

公开(公告)号：US20140248502A1

公开(公告)日：2014-09-04

申请号：US14352238

申请日：2012-10-16

Applicant: Denis Heymans ,  Christophe Steinbrecher ,  Cédrlc Le fevere de ten hove

Inventor： Denis Heymans ,  Christophe Steinbrecher ,  Cédrlc Le fevere de ten hove

IPC: C08F120/06 ,  C09D133/02

CPC classification number: C08F120/06 ,  C08G59/1466 ,  C09D133/02 ,  C09D163/00 ,  Y10T428/31699 ,  Y10T428/31935

Abstract: The invention relates to compositions of hydroxyl functional acrylic resins (acrylic polyols) comprising a mixture of α,α-branched alkane carboxylic glycidyl esters derived from butene oligomers characterized in that the sum of the concentration of the blocked and of the highly branched isomers is maximum 55%, preferably below 40%, and most preferably below 30% weight on total composition.

Abstract translation: 本发明涉及羟基官能丙烯酸树脂（丙烯酸多元醇）的组合物，其包含衍生自丁烯低聚物的α，α-支链烷烃羧基缩水甘油酯的混合物，其特征在于封端和高度支化异构体的浓度之和为最大 55％，优选低于40％，最优选低于30％重量。

公开(公告)号：US20140005300A1

公开(公告)日：2014-01-02

申请号：US13997413

申请日：2011-12-16

Applicant: Christophe Steinbrecher ,  Cédric Le Fevere De Ten Hove ,  Robert Vant Sand ,  Denis Heymans ,  Aleksandra Kotlewska

Inventor： Christophe Steinbrecher ,  Cédric Le Fevere De Ten Hove ,  Robert Vant Sand ,  Denis Heymans ,  Aleksandra Kotlewska

IPC: C09D7/06

CPC classification number: C09D7/47 ,  C07D303/16 ,  C08K5/10 ,  C08K5/1515 ,  C08K2201/014 ,  C08L63/00

Abstract: The invention relates to compositions of α,α-branched alkane carboxylic acids glycidyl esters with a defined isomeric composition where the sum of the concentration of the blocked and of the highly branched isomers is maximum 55% preferably below 40%, and most preferably below 30%.The mixture of neononanoic acid glycidyl esters comprising at least 2,2-dimethyl heptanoic acid glycidyl ester and 2-methyl 2-ethyl hexanoic acid glycidyl ester and 2-methyl 2-ethyl 3-methyl pentanoic acid glycidyl esters.

Abstract translation: 本发明涉及具有确定的异构体组合物的α支链烷烃羧酸缩水甘油酯的组合物，其中封端和高度支化的异构体的浓度之和为最大55％，优选低于40％，最优选低于30％ ％。 包含至少2,2-二甲基庚酸缩水甘油酯和2-甲基2-乙基己酸缩水甘油酯的2-羟基乙酸缩水甘油酯和2-甲基2-乙基3-甲基戊酸缩水甘油酯的混合物。