摘要:
A porous ceramic honeycomb article includes a primary cordierite phase and an intercrystalline glass phase. In an as-fired condition, the porous ceramic honeycomb article exhibits microcrack parameter Nb3≦0.06 and an as-fired E500° C./E25° C. ratio ≦0.99. The article exhibits a coated microcrack parameter Nb3≦0.14 and a coated E500° C./E25° C. ratio ≦1.06 after the porous ceramic honeycomb article has been washcoated and calcined at a temperature of 550° C. After the article is exposed to a thermal treatment at a temperature ≧800° C. following washcoating and calcining, at least a first portion of the porous ceramic honeycomb article has a first treated microcrack parameter Nb3≧0.18, and a first treated mean coefficient of thermal expansion of not more than 12×10−7/° C. over a temperature range of 25° C. to 800° C. Methods of forming the porous ceramic honeycomb article are also disclosed.
摘要:
A porous ceramic honeycomb article includes a primary cordierite phase and an intercrystalline glass phase. In an as-fired condition, the porous ceramic honeycomb article exhibits microcrack parameter Nb3 ≦0.06 and an as-fired E500° C./E25° C. ratio ≦0.99. The article exhibits a coated microcrack parameter Nb3 ≦0.14 and a coated E500° C./E25° C. ratio ≦1.06 after the porous ceramic honeycomb article has been washcoated and calcined at a temperature of 550° C. After the article is exposed to a thermal treatment at a temperature ≧800° C. following washcoating and calcining, at least a first portion of the porous ceramic honeycomb article has a first treated microcrack parameter Nb3 ≧0.18, and a first treated mean coefficient of thermal expansion of not more than 12×10−7/° C. over a temperature range of 25° C. to 800° C. Methods of forming the porous ceramic honeycomb article are also disclosed.
摘要:
Substantially non-microcracked, porous, cordierite ceramic honeycomb bodies are provided. Although exhibiting moderately high thermal expansion (CTE) between 7×10−7 to 16×10−7/° C. (25-800° C.), the honeycomb bodies exhibit relatively high thermal shock parameter (TSP), such as TSR≧525° C. by virtue of a high MOR/E ratio, and/or low Eratio=ERT/E1000° C. and well interconnected porosity, as witnessed by a relatively high pore connectivity factor (PCF). A method of manufacturing the honeycomb ceramic structure is also provided.
摘要:
A porous cordierite ceramic honeycomb article with increased mechanical strength and thermal shock resistance. The porous cordierite ceramic honeycomb article has MA 2660 wherein MA=3645(IA)−106(CTE)+19(d90)+17(% porosity), MT=4711(IT)+116(CTE)−26(d90)−28(% porosity), and a CTE≦9×10−7/° C. in at least one direction. A method of manufacturing is also disclosed wherein the inorganic raw material mixture contains talc, an alumina-forming source, a silica-forming source, and 0-18 wt. % of a kaolin or calcined kaolin containing not more than 8 wt. % of a fine kaolin source having a median particle diameter of less than 7 μm, wherein the fired porous ceramic cordierite honeycomb article has a porosity
摘要:
Disclosed are ceramic honeycomb articles, which are composed predominately of a crystalline phase cordierite composition. The ceramic honeycomb articles possess a microstructure characterized by a unique combination of relatively high total porosity of less than 54%, and relatively narrow pore size distribution having a d10 pore diameter of not less than 8 μm, a d90 pore diameter of not greater than 35 μm, and a value of df=(d50−d10)/d50 of less than 0.50. The articles exhibit high thermal durability and high filtration efficiency coupled with low pressure drop across the filter. Such ceramic articles are particularly well suited for filtration applications, such as diesel exhaust filters or DPFs. Also disclosed are methods for manufacturing the ceramic articles of the present invention.
摘要翻译:公开了主要由结晶相堇青石组合物组成的陶瓷蜂窝体制品。 陶瓷蜂窝体制品具有微结构,其特征在于具有小于54%的相对高的总孔隙率的独特组合,以及具有不小于8μm的孔径的孔径分布, 不大于35μm的细孔直径,并且其中d≥30 )/ d <50 <小于0.50。 该制品表现出高热耐久性和高过滤效率以及过滤器两端的低压降。 这种陶瓷制品特别适用于过滤应用,例如柴油机排气过滤器或DPF。 还公开了用于制造本发明的陶瓷制品的方法。
摘要:
The present invention describes a high porosity (% P≧45%), refractory, ceramic article comprising a cordierite ceramic phase and at least about 0.1 wt. % of a rare earth oxide, such as yttrium oxide or lanthanum oxide. When compared to typical high-porosity cordierite articles, the articles of the present invention may exhibit relatively high strength, relatively low microcracking, relatively high strain tolerance (MOR/E), and/or relatively high thermal shock resistance (TSP).
摘要:
The present invention describes a high porosity (% P≧45%), refractory, ceramic article comprising a cordierite ceramic phase and at least about 0.1 wt.% of a rare earth oxide, such as yttrium oxide or lanthanum oxide. When compared to typical high-porosity cordierite articles, the articles of the present invention may exhibit relatively high strength, relatively low microcracking, relatively high strain tolerance (MOR/E), and/or relatively high thermal shock resistance (TSP).
摘要:
Disclosed are ceramic honeycomb articles, which are composed predominately of a crystalline phase cordierite composition. The ceramic honeycomb articles possess a microstructure characterized by a unique combination of relatively high total porosity of less than 54%, and relatively narrow pore size distribution having a d10 pore diameter of not less than 8 μm, a d90 pore diameter of not greater than 35 μm, and a value of df=(d50−d10)/d50 of less than 0.50. The articles exhibit high thermal durability and high filtration efficiency coupled with low pressure drop across the filter. Such ceramic articles are particularly well suited for filtration applications, such as diesel exhaust filters or DPFs. Also disclosed are methods for manufacturing the ceramic articles of the present invention.
摘要:
Substantially non-microcracked, porous, cordierite ceramic honeycomb bodies are provided. Although exhibiting moderately high thermal expansion (CTE) between 7×10−7 to 16×10−7/° C. (25-800° C.), the honeycomb bodies exhibit relatively high thermal shock parameter (TSP), such as TSR≧525° C. by virtue of a high MOR/E ratio, and/or low Eratio=ERT/E1000° C. and well interconnected porosity, as witnessed by a relatively high pore connectivity factor (PCF). A method of manufacturing the honeycomb ceramic structure is also provided.
摘要:
A low-microcracked porous cordierite honeycomb ceramic particulate filter having a high strength in combination with a very low pressure drop, a very high filtration efficiency, and a high thermal shock resistance. Little or no microcracking, a fine median pore diameter, and a narrow pore size distribution contribute to high strength. A thin channel wall, high wall permeability, and narrow pore size distribution, contribute to low pressure drop. A fine pore diameter and narrow pore size distribution with a minimum of coarse pores contribute to high filtration efficiency. A high strain tolerance, MOR/E, contributes to high thermal shock resistance. Particulate filters disclosed herein can be useful as a hot gas particulate filter, and particularly as an internal combustion engine exhaust gas particulate filter, such as an exhaust gas filter for a gasoline direct injection engine.